Collect. Czech. Chem. Commun. 1987, 52, 132-139
https://doi.org/10.1135/cccc19870132

Mechanism of the reaction of 1-methoxy- and 1-chloro-2,4,6-trinitrobenzene with dimethyl malonate anion

Vladimír Macháčeka, Vojeslav Štěrbaa and Antonín Lyčkab

a Department of Organic Chemistry, Institute of Chemical Technology, 532 10 Pardubice
b Research Institute of Organic Syntheses, 532 18 Pardubice-Rybitví

Individual author index pages


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    1987, Vol. 52, Issue 9, pp. 2225–2240 [Abstract]
  • Jaromír Kaválek, Vladimír Macháček, Gabriela Svobodová and Vojeslav Štěrba
    Kinetics of acid-catalyzed cyclization of substituted hydantoinamides to substituted hydantoins
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    1987, Vol. 52, Issue 3, pp. 736–741 [Abstract]
  • Antonín Lyčka, Tibor Liptaj and Josef Jirman
    13C and 15N NMR spectra of 3-methyl-1-phenylpyrazole-4,5-dione 4-(4'-substituted phenyl)hydrazones
    1987, Vol. 52, Issue 3, pp. 727–735 [Abstract]
  • Jaromír Mindl and Vojeslav Štěrba
    Mechanism of base-catalyzed cyclization of ethyl N-(substituted aminocarbonyl)glycinates
    1987, Vol. 52, Issue 1, pp. 156–161 [Abstract]
  • Vladimír Macháček, Gabriela Svobodová and Vojeslav Štěrba
    Kinetics and mechanism of base-catalyzed cyclization of substituted amides and nitriles of hydantoic acid
    1987, Vol. 52, Issue 1, pp. 140–155 [Abstract]
  • Jaromír Kaválek, Josef Jirman and Vojeslav Štěrba
    Reactions of 1,3-diacylthioureas with methoxide ion and with amines
    1987, Vol. 52, Issue 1, pp. 120–131 [Abstract]
  • Antonín Lyčka, Jaroslav Holeček, Karel Handlíř, Josef Pola and Václav Chvalovský
    17O, 13C, and 29Si NMR spectra of some acyloxy- and diacetoxysilanes and acetoxygermanes
    1986, Vol. 51, Issue 11, pp. 2582–2589 [Abstract]
  • Jaroslav Holeček, Antonín Lyčka and Roland Wagener
    The 119Sn and 15N NMR spectral study of the chelate formation in the triphenyltin(IV) oxinate
    1986, Vol. 51, Issue 10, pp. 2116–2126 [Abstract]
  • Vladimír Macháček, Makky M. M. Hassanien, Vojeslav Štěrba and Antonín Lyčka
    Formation of the Meisenheimer spiro adduct of N-(2,4,6-trinitrophenyl)alanine methylamide and its rearrangement to 2-amino-N-methyl-N-(2,4,6-trinitrophenyl)propanamide
    1986, Vol. 51, Issue 9, pp. 1972–1985 [Abstract]
  • Jaromír Kaválek, Josef Panchartek, Tomáš Potěšil and Vojeslav Štěrba
    Kinetics of the reaction of guanyl-O-methylisourea hydrochloride with dimethylformamide dimethylacetal
    1986, Vol. 51, Issue 9, pp. 1964–1971 [Abstract]
  • Jaroslav Holeček, Karel Handlíř, Antonín Lyčka, T. K. Chattopadhyay, B. Majee and A. K. Kumar
    Preparation and infrared and 13C, 17O, and 119Sn NMR spectra of some substituted di- and tri(1-butyl)tin phenoxyacetates and phenylthioacetates
    1986, Vol. 51, Issue 5, pp. 1100–1111 [Abstract]
  • Jaromír Kaválek, Josef Panchartek, Tomáš Potěšil and Vojeslav Štěrba
    Solvolysis kinetics of ethyl 3-ethoxy-3-iminopropanoate
    1986, Vol. 51, Issue 3, pp. 677–683 [Abstract]
  • Jaromír Kaválek, Vladimír Macháček, Gabriela Svobodová and Vojeslav Štěrba
    Base catalyzed cyclization of substituted esters of hydantoic and thiohydantoic acids
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  • Jaromír Kaválek, Josef Jirman and Vojeslav Štěrba
    Kinetics and mechanism of rearrangement and methanolysis of acylphenylthioureas
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  • Vladimír Macháček, Josef Kořínek, Daniela Kreuzigová and Vojeslav Štěrba
    Kinetics of reactions of 1,2,4-triazole-3-diazonium ions with phenol and with hydroxyl ion
    1985, Vol. 50, Issue 3, pp. 658–674 [Abstract]
  • Antonín Lyčka, Milan Nádvorník, Karel Handlíř and Jaroslav Holeček
    13C and 119Sn NMR spectra of some triphenyltin 4-substituted benzoates dissolved in coordinating and non-coordinating solvents
    1984, Vol. 49, Issue 12, pp. 2903–2911 [Abstract]
  • Antonín Lyčka
    13C, 15N, and 19F NMR spectra of 2-phenylhydrazonopropanedinitriles and methyl 2-phenyl hydrazonocyanoacetates
    1984, Vol. 49, Issue 12, pp. 2801–2806 [Abstract]
  • Jan Slouka, Vojtěch Bekárek, Karel Nálepa and Antonín Lyčka
    Synthesis of 1,2,4-triazino[5,6-b]- and imidazo[4,5-b]quinoline derivatives
    1984, Vol. 49, Issue 11, pp. 2628–2634 [Abstract]
  • Jaromír Kaválek, Said El Bahaie and Vojeslav Štěrba
    Kinetics and mechanism of methanolysis of benzoyl derivatives of substituted phenylureas and phenylthioureas
    1984, Vol. 49, Issue 9, pp. 2103–2110 [Abstract]
  • Jaromír Mindl, Vojeslav Štěrba, Vladimír Kadeřábek, Jr. and Jiří Klicnar
    Kinetics and mechanism of hydrolysis of benzhydryl N-arylthiocarbamates and study of their IR spectra
    1984, Vol. 49, Issue 7, pp. 1577–1591 [Abstract]
  • Karel Handlíř, Jaroslav Holeček, Milan Nádvorník, Antonín Lyčka and Milan Hucl
    Study of structure of bis(triphenylstannyl) chromate(VI) by infrared, Mössbauer, and 1H, 13C and 119Sn NMR spectra
    1984, Vol. 49, Issue 6, pp. 1497–1504 [Abstract]
  • Antonín Lyčka and Pavel Vetešník
    13C and 15N NMR spectra of 1-(3- or 4-substituted phenyl)-3-methyl-3-phenyltriazenes
    1984, Vol. 49, Issue 4, pp. 963–969 [Abstract]
  • Vladimír Macháček and Antonín Lyčka
    13C and 15N NMR spectra of 6-substituted bicyclo[3,3,1]7-nonanone nitronates
    1984, Vol. 49, Issue 1, pp. 244–252 [Abstract]
  • Antonín Lyčka and Jaromír Kaválek
    13C, 15N, and 19F NMR spectra of 4-fluoro-(3´ or 4´-substituted) azobenzenes
    1984, Vol. 49, Issue 1, pp. 58–64 [Abstract]
  • Antonín Lyčka
    13C and 15N NMR study of azo-hydrazone tautomerism in azo dyes containing amino or acetamido groups
    1983, Vol. 48, Issue 11, pp. 3104–3111 [Abstract]
  • Jaromír Kaválek, Vladimír Macháček and Vojeslav Štěrba
    Reactions of ethyl 2-alkyl-3-oxobutanoate with thiourea and methylthiourea
    1983, Vol. 48, Issue 7, pp. 1872–1877 [Abstract]
  • Vladimír Macháček, Jaroslav Andrle and Vojeslav Štěrba
    Kinetics of reaction of 1-chloro-2,4,6-trinitrobenzene with enolate ions of 2,4-pentanedione and methyl 3-oxobutanoate
    1983, Vol. 48, Issue 6, pp. 1608–1617 [Abstract]
  • Jaromír Kaválek, Vojeslav Štěrba and Said El Bahaie
    Dissociation constants of m- and p-substituted phenylthioureas and ureas in water and in methanol
    1983, Vol. 48, Issue 5, pp. 1430–1434 [Abstract]
  • Jaromír Mindl and Vojeslav Štěrba
    Kinetics and mechanism of hydrolysis of aryl N-methoxycarbamates and their derivatives
    1983, Vol. 48, Issue 3, pp. 900–905 [Abstract]
  • Jaromír Kaválek, Tomáš Potěšil and Vojeslav Štěrba
    Cyclization kinetics and mechanism of N-benzoyl-N'-(1,2-dimethyl-3-oxo-1-butenyl)thiourea
    1983, Vol. 48, Issue 2, pp. 578–585 [Abstract]
  • Jaromír Kaválek, Jaroslav Novák and Vojeslav Štěrba
    Kinetics of hydrolysis and rearrangements of S-acylthiouronium salts
    1982, Vol. 47, Issue 10, pp. 2702–2710 [Abstract]
  • Jan Slouka, Vojtěch Bekárek and Antonín Lyčka
    Cyclization reactions of some o-acylphenylhydrazones
    1982, Vol. 47, Issue 6, pp. 1746–1756 [Abstract]
  • Bohumír Koutek, Milena Píšová, Josef Krupička, Antonín Lyčka, Dobroslav Šnobl and Milan Souček
    Benzoannelated quinone methides
    1982, Vol. 47, Issue 6, pp. 1645–1653 [Abstract]
  • Antonín Lyčka
    Carbon-13 and nitrogen-15 NMR spectra of cis- and trans-azobenzene, 4-monosubstituted and 4,4'-disubstituted trans-azobenzenes
    1982, Vol. 47, Issue 4, pp. 1112–1120 [Abstract]
  • Antonín Lyčka, Dobroslav Šnobl, Karel Handlíř, Jaroslav Holeček and Milan Nádvorník
    29Si and 13C NMR spectra of some alkyldiphenylchlorosilanes, alkyldiphenylsilanoles and bis(alkyldiphenylsilyl)chromates
    1982, Vol. 47, Issue 2, pp. 603–612 [Abstract]
  • Jaromír Kaválek, Jiří Hruška and Vojeslav Štěrba
    Kinetics of cyclization of 1-phenyl-3-(1,2-dimethyl-3-oxo-1-butenyl)urea and ethyl 2-methyl-3-N-(N'-phenylureido)-2-butenoate
    1982, Vol. 47, Issue 2, pp. 518–522 [Abstract]
  • Vladimír Macháček, Vojeslav Štěrba and Helena Zahradníčková
    Solvolysis kinetics and mechanism of 3-methyl-1,3-thiazolidine-2,4-dione
    1981, Vol. 46, Issue 12, pp. 3097–3103 [Abstract]
  • Bohumír Koutek, Lubomír Musil, Jiří Velek, Antonín Lyčka, Dobroslav Šnobl, Miroslava Synáčková and Milan Souček
    Perturbation of the fuchsone chromophore by 3,5-methyl substitution. Sterically crowded exocyclic double bond
    1981, Vol. 46, Issue 10, pp. 2540–2556 [Abstract]
  • Jaromír Toman, Vojeslav Štěrba and Jiří Klicnar
    Ketimine-enamine tautomerism of 2-ethoxycarbonylmethylene-4-methyl-3-oxo-1,2,3,4-tetrahydroquinoxaline: A kinetic study
    1981, Vol. 46, Issue 9, pp. 2104–2109 [Abstract]
  • Antonín Lyčka, Dobroslav Šnobl, Bohumír Koutek, Libuše Pavlíčková and Milan Souček
    13C NMR study of 7,7-disubstituted quinone methides
    1981, Vol. 46, Issue 9, pp. 2083–2090 [Abstract]
  • Antonín Lyčka, Dobroslav Šnobl, Bohumír Koutek, Libuše Pavlíčková and Milan Souček
    13C NMR study of substituted quinone methides. 2- and 2,6-substituted fuchsones
    1981, Vol. 46, Issue 8, pp. 1775–1787 [Abstract]
  • Antonín Lyčka, Dobroslav Šnobl, Karel Handlíř, Jaroslav Holeček and Milan Nádvorník
    13C, 29Si, 115Sn, 117Sn and 119Sn NMR spectra of some triphenyl derivatives of elements of IVB group
    1981, Vol. 46, Issue 6, pp. 1383–1388 [Abstract]
  • Antonín Lyčka and Dobroslav Šnobl
    Coupling constants nitrogen-15-nitrogen-15 and nitrogen-15-hydrogen in phenylhydrazones forming hydrogen bond
    1981, Vol. 46, Issue 4, pp. 892–897 [Abstract]
  • Vladimír Macháček, Said El Bahaie and Vojeslav Štěrba
    Study of cyclization of 2-acetyl-3-methylamino-N-benzoyl-2-butenethioamide
    1981, Vol. 46, Issue 1, pp. 256–261 [Abstract]
  • Jaromír Kaválek, Milan Kotyk, Said El Bahaie and Vojeslav Štěrba
    Reactions of N-benzoyl isothiocyanate with anthranilic acid and methyl anthranilate
    1981, Vol. 46, Issue 1, pp. 246–255 [Abstract]
  • Antonín Lyčka
    13C and 15N NMR studies of 2,3,4-pentanetrione 3-phenylhydrazone, dimethyl 2-phenylhydrazonopropanedioate and ethyl 2-phenylhydrazono-3-oxobutanoate
    1980, Vol. 45, Issue 12, pp. 3354–3359 [Abstract]
  • Antonín Lyčka
    Carbon-13 and nitrogen-14 NMR spectra of 1-(substituted phenyl)pyridinium salts
    1980, Vol. 45, Issue 10, pp. 2766–2771 [Abstract]
  • Jaroslav Horyna, Antonín Lyčka and Dobroslav Šnobl
    13C-NMR spectra of benzenesulphonyl derivatives
    1980, Vol. 45, Issue 5, pp. 1575–1580 [Abstract]
  • Jaromír Kaválek, Said El-Bahaie, Vladimír Macháček and Vojeslav Štěrba
    Study of reaction of thiourea with ethyl 3-oxobutanoate
    1980, Vol. 45, Issue 3, pp. 732–739 [Abstract]
  • Jaromír Kaválek, Said El-Bahaie and Vojeslav Štěrba
    Reactions of thiourea with chloro- and bromoacetic acids
    1980, Vol. 45, Issue 1, pp. 263–268 [Abstract]
  • Jaromír Kaválek, Karel Janák and Vojeslav Štěrba
    Kinetics of reaction of 5-phenyl-1,3,4-thiadiazol-2-diazonium ion with water
    1979, Vol. 44, Issue 10, pp. 3102–3110 [Abstract]
  • Vladimír Macháček, Sylvie Marečková and Vojeslav Štěrba
    Study of reaction of substituted nitrophenyl acetates and benzoates with nucleophiles
    1979, Vol. 44, Issue 6, pp. 1779–1789 [Abstract]
  • Jaromír Kaválek, Ahmad Ashfaq and Vojeslav Štěrba
    Reactions of 1-substituted 2,4,6-trinitrobenzenes with nucleophiles
    1979, Vol. 44, Issue 5, pp. 1453–1459 [Abstract]
  • Vladimír Macháček, Said A. El-bahai and Vojeslav Štěrba
    Kinetics of cyclization of S-ethoxycarbonylmethylisothiouronium chloride to 2-imino-4-thiazolidone
    1979, Vol. 44, Issue 3, pp. 912–917 [Abstract]
  • Antonín Lyčka and Dobroslav Šnobl
    Effect of lanthanide shift reagents on 1H NMR spectra of aminopyridines
    1979, Vol. 44, Issue 3, pp. 908–911 [Abstract]
  • Jaromír Kaválek, Said El-Bahei and Vojeslav Štěrba
    Hydrolysis kinetics of 4-amino-3-pentene-2-one and its N-substituted derivatives
    1978, Vol. 43, Issue 10, pp. 2732–2739 [Abstract]
  • Jaromír Toman, Jiří Klicnar and Vladimír Macháček
    Synthesis of 2-methyl-3-oxo-3,4-dihydroquinoxaline derivatives
    1978, Vol. 43, Issue 8, pp. 2179–2189 [Abstract]
  • Vladimír Macháček, Jaromír Toman and Jiří Klicnar
    Ketimine-enamine tautomerism of 2-methylene-3-oxo-1,2,3,4-tetrahydroquinoxaline derivatives
    1978, Vol. 43, Issue 6, pp. 1634–1638 [Abstract]
  • Jaromír Kaválek, Miroslav Pastrnek and Vojeslav Štěrba
    Reactions of 2,4,6-trinitrochlorobenzene with dimethyl malonate anion in methanol and methanol-dimethyl sulphoxide mixture
    1978, Vol. 43, Issue 5, pp. 1401–1409 [Abstract]