Collect. Czech. Chem. Commun. 1985, 50, 2598-2606

A study of reaction of aromatic polynitro compounds with tributylstannyl hydride

Vladimír Macháčeka, Antonín Lyčkab and Milan Nádvorníkc

a Department of Organic Chemistry
b Department of General and Inorganic Chemistry, Institute of Chemical Technology, 532 10 Pardubice
c Research Institute of Organic Syntheses, 532 18 Pardubice


1H, 13C, 15N, and 119Sn NMR spectra have been used to study composition and structure of reaction products from 1,3,5-trinitrobenzene, methyl 2,4,6-trinitrobenzoate, 1-dimethylamino-2,4,6-trinitrobenzene, 1-methoxy-2,4,6-trinitrobenzene, 1-chloro-2,4,6-trinitrobenzene, 2,4,6-trinitrotoluene, 3,5-dinitrobenzonitrile and methyl 3,5-dinitrobenzoate with tributylstannyl hydride in the presence of tetramethylammonium bromide.