Collect. Czech. Chem. Commun. 1987, 52, 736-741
https://doi.org/10.1135/cccc19870736

15N NMR study of amino-imino tautomerism in derivatives of 1,4-bis(substituted amino)-9,10-anthraquinones and 1,4-bis(substituted amino)-2,3-dihydro-9,10-anthraquinones

Antonín Lyčka, Libuše Havlíčková, Alois Koloničný and Josef Jirman

Research Institute of Organic Syntheses, 532 18 Pardubice-Rybitví

Abstract

The 15N chemical shifts and 1J(15N, H) coupling constants of 1,4-bis(substituted amino)-9,10-anthraquinones and 1,4-bis(substituted amino)-2,3-dihydro-9,10-anthraquinones indicate that these derivatives exist as true aminoderivatives except for 1,4-bis(phenylamino)-2,3-dihydro-9,10-anthraquinone which forms a tautomeric mixture of the amino and imino forms in deuteriochloroform and hexadeuteriodimethyl sulphoxide.