Collect. Czech. Chem. Commun. 2005, 70, 430-440
https://doi.org/10.1135/cccc20050430

Macropolyhedral Boron-Containing Cluster Chemistry. A Metallathiaborane from S2B17H17: Isolation and Characterisation of [(PMe2Ph)2PtS2B16H16]; A neo-arachno Ten-Vertex Cluster Shape, and the Constitution of the [arachno-B10H15]- Anion

Michael J. Carra,b, Michael G. S. Londesborougha, Jonathan Bouldb, Ivana Císařovác, Bohumil Štíbra and John D. Kennedyb,*

a Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, 250 68 Řež near Prague, Czech Republic
b The School of Chemistry of the University of Leeds, Leeds, UK LS2 9JT, England
c Faculty of Science, Charles University, Hlavova 2030, 128 42 Prague 2, Czech Republic

Individual author index pages


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    1997, Vol. 62, Issue 8, pp. 1289–1298 [Abstract]
  • Jonathan Bould, Paul Brint, John D. Kennedy, Mark Thornton-Pett, Lawrence Barton and Nigam P. Rath
    Metallaborane Reaction Chemistry. Part 3. Reaction of Carbon Monoxide with [6-H-6-(PPh3)-6P,5C-μ-(2-Ph2PC6H4)-nido-6-IrB9H12] and the Isolation and Characterisation of Two arachno-6-Monoiridadecaboranes [6-(CO)-6-H-6,9-(PPh3)2-6P,5C-μ-(2-Ph2PC6H4)-arachno-6-IrB9H11] and sym-[6-(CO)-6-H-6,6-(PMe2Ph)2-9-(PPh3)-arachno-6-IrB9H11]
    1997, Vol. 62, Issue 8, pp. 1239–1253 [Abstract]
  • Bohumil Štíbr, Josef Holub, Tomáš Jelínek, Bohumír Grüner, Jiří Fusek, Zbyněk Plzák, Francesc Teixidor, Clara Viñas and John D. Kennedy
    A Return to the Plesek Reaction and Some Useful Variations. Carbon-Substituted Methyl and Phenyl Derivatives of 5,6-Dicarba-nido-decaborane(12), nido-5,6-C2B8H12
    1997, Vol. 62, Issue 8, pp. 1229–1238 [Abstract]
  • Jaromír Plešek, Stanislav Heřmánek, Andreas Franken, Ivana Císařová and Christiane Nachtigal
    Dimethyl Sulfate Induced Nucleophilic Substitution of the [Bis(1,2-dicarbollido)-3-cobalt(1-)]ate Ion. Syntheses, Properties and Structures of Its 8,8'-μ-Sulfato, 8-Phenyland 8-Dioxane Derivatives
    1997, Vol. 62, Issue 1, pp. 47–56 [Abstract]
  • Peter MacKinnon, Xavier L. R. Fontaine, John D. Kennedy and Paul A. Salter
    Polyhedral Azaborane Chemistry: NMR Parameters for the Unique Eight-Boron Polyhedral Species [(C2H5NH2)B8H11NHC2H5]
    1996, Vol. 61, Issue 12, pp. 1773–1782 [Abstract]
  • Petr Štěpnička and Ivana Císařová
    Crystal Structure of Dibromo(η4-1,5-cyclooctadiene)palladium(II)
    1996, Vol. 61, Issue 9, pp. 1335–1341 [Abstract]
  • Pavel Vojtíšek and Ivana Císařová
    Complexes of Tris(N-piperidinomethyl)phosphine Oxide with Zinc and Cadmium
    1996, Vol. 61, Issue 9, pp. 1321–1334 [Abstract]
  • Michal Horáček, Róbert Gyepes, Ivana Císařová, Miroslav Polášek, Vojtech Varga and Karel Mach
    Syntheses and Crystal Structures of Bis[(trimethylsilyl)tetramethylcyclopentadienyl]titanium Dichloride and Monochloride
    1996, Vol. 61, Issue 9, pp. 1307–1320 [Abstract]
  • Zdeněk Mička, Lucie Prokopová, Ivana Císařová and David Havlíček
    Crystal Structure, Thermoanalytical Properties and Infrared Spectra of Double Magnesium Selenates
    1996, Vol. 61, Issue 9, pp. 1295–1306 [Abstract]
  • Jiří Vohlídal, Jaromír Plešek, Jan Sedláček, Ivana Císařová, Pavel Matějka and Stanislav Heřmánek
    Cobaltacarboranylacetylene 8,8'-(μ-CHC-CH2S)-(1,2-C2B9H10)2-3-Co(III): Synthesis, Characterization and Polymerization of New Substituted Acetylene
    1996, Vol. 61, Issue 6, pp. 877–887 [Abstract]
  • Václav Všetečka, Ivana Císařová and Jaroslav Podlaha
    Conformation of Methylsulfonyl Group: A Comparison of the Data for 2-Chlorophenyl Methyl Sulfone in Solution and in Crystal
    1996, Vol. 61, Issue 5, pp. 733–741 [Abstract]
  • Jaroslav Podlaha, Ivana Císařová, Martin Bělohradský and Jiří Závada
    Crystal and Molecular Structure of cis-2,2',3',2"-Tetraacetoxy-1,1':4',1"-ternaphthyl
    1996, Vol. 61, Issue 5, pp. 726–732 [Abstract]
  • Roman Řeřicha, Ivana Císařová and Jaroslav Podlaha
    Crystal and Molecular Structure of Lithium Benzohydroxamate-Benzohydroxamic Acid (1 : 1) Adduct
    1996, Vol. 61, Issue 1, pp. 139–146 [Abstract]
  • Bohumil Štíbr, Josef Holub, Francesc Teixidor and Clara Viñas
    The First Examples of Metallatricarbollides. Isomeric Twelve-Vertex Cyclopentadienyl Ferratricarbadodecaboranes [(η5-C5H5)-closo-FeC3B8H11]
    1995, Vol. 60, Issue 12, pp. 2023–2027 [Abstract]
  • Ivana Císařová, Jana Podlahová and Jaroslav Podlaha
    Crystal Structure of the Adduct Hexahydroxotelluric Acid-Disodium Ethylenediaminetetraacetate-Water (1/1/2)
    1995, Vol. 60, Issue 5, pp. 820–828 [Abstract]
  • Tomáš Jelínek, Bohumil Štíbr and John D. Kennedy
    Nine-Vertex Polyhedral Monoazaborane Chemistry: Synthesis and NMR Characterization of exo-6-Ligand-arachno-4-azanonaboranes(11), 6-L-4-NB8H11
    1994, Vol. 59, Issue 10, pp. 2244–2252 [Abstract]
  • Tomáš Jelínek, Josef Holub, Bohumil Štíbr, Xavier L. R. Fontaine and John D. Kennedy
    Nine- and Eight-Vertex Polyhedral Dicarbaborane Chemistry: New arachno and hypho Dicarbaboranes from arachno-4,5-C2B7H13: Isolation and Characterization of the [arachno-4,5-C2B7H12]- and [hypho-7,8-C2B6H13]- Anions, and of the Neutral Ligand Derivatives exo-6-(MeNC)-arachno-4,5-C2B7H11 and exo-5-L-hypho-4,9-C2B7H13 (L = NMe3 and NEt3)
    1994, Vol. 59, Issue 7, pp. 1584–1595 [Abstract]
  • Josef Holub, John D. Kennedy and Bohumil Štíbr
    Nine-Vertex Polyhedral Monothiaborane Chemistry. The First nido Thianonaborane: Isolation and Characterization by NMR of the [nido-9-SB8H9]- Anion, and its Conversion to Compounds of the 6-L-arachno-4-SB8H10 Series (where L = SMe2 and Pyridine)
    1994, Vol. 59, Issue 2, pp. 367–373 [Abstract]
  • Jane H. Jones, Bohumil Štíbr, John D. Kennedy and Mark Thornton-Pett
    Ten-Vertex Polyhedral Monocarbaborane Chemistry. The Novel High-Yield Formation of the Ten-Vertex closo Compound [6-(PMe2Ph)-closo-1-CB9H9] from the Thermolysis of [8,8-(PMe2Ph)2-nido-8,7-PtCB9H11]
    1993, Vol. 58, Issue 12, pp. 2924–2935 [Abstract]
  • John D. Kennedy, Bohumil Štíbr, Tomáš Jelínek, Xavier L. R. Fontaine and Mark Thornton-Pett
    Eleven-Vertex Polyhedral Dicarbaplatinaborane Chemistry. Aspects of the Chemistry of Some closo-Structured {1,2,3-PtC2B8} Species and Some Related Compounds
    1993, Vol. 58, Issue 9, pp. 2090–2120 [Abstract]
  • Karl Nestor, Michael Murphy, Bohumil Štíbr, Trevor R. Spalding, Xavier L. R. Fontaine, Mark Thornton-Pett and John D. Kennedy
    Ten-Vertex Polyhedral Rhodadicarbaborane Chemistry. Molecular Structure, NMR Properties, and Cluster Dynamic Behaviour of [2,2,2-(PPh3)2H-closo-2,1,6-RhC2B7H9]
    1993, Vol. 58, Issue 7, pp. 1555–1568 [Abstract]
  • Dalimil Dvořák, David Šaman, Zdeněk Arnold, Ivana Císařová and Václav Petříček
    Cycloaddition Reactions of Arylmethylenemalonaldehydes with Olefins
    1992, Vol. 57, Issue 11, pp. 2337–2358 [Abstract]
  • Bohumil Štíbr, John D. Kennedy, Mark Thornton-Pett, Eva Drdáková, Tomáš Jelínek and Jaromír Plešek
    Polyhedral Iridamonocarbaborane Chemistry. The Isolation and Characterisation of the Nine-Vertex closo-Type Species [(CO)(PPh3)2IrCB7H8] and the Partially Open Structures of Formally closo Nine-Vertex Clusters
    1992, Vol. 57, Issue 7, pp. 1439–1450 [Abstract]
  • Karl Nestor, Bohumil Štíbr, John D. Kennedy, Mark Thornton-Pett and Tomáš Jelínek
    Ten-Vertex Monocarbaborane Chemistry. A Convenient New Preparation of the [closo-1-CB9H10]- Anion and the Crystal and Molecular Structure of [(η5-C5Me5)2Ir2Cl3]+ [closo-1-CB9H10]-
    1992, Vol. 57, Issue 6, pp. 1262–1268 [Abstract]
  • Jaromír Plešek, Bohumil Štíbr, Xavier L. R. Fontaine, John D. Kennedy, Stanislav Heřmánek and Tomáš Jelínek
    Selective dismantling of closo-1,2-C2B10H12 to lower-cage dicarbaborane systems
    1991, Vol. 56, Issue 8, pp. 1618–1635 [Abstract]
  • Karl Nestor, Xavier L. R. Fontaine, John D. Kennedy, Bohumil Štíbr, Karel Baše and Mark Thornton-Pett
    Polyhedral organoiridaazaborane chemistry. The preparation of the eleven-vertex nido compound [9-Cl-8-(η5-C5Me5)-nido-8,7-IrNHB9H10] and its characterization by single-crystal X-ray diffraction analysis and nuclear magnetic resonance spectroscopy
    1991, Vol. 56, Issue 8, pp. 1607–1617 [Abstract]
  • Bohumil Štíbr, Karel Baše, Tomáš Jelínek, Xavier L. R. Fontaine, John D. Kennedy and Mark Thornton-Pett
    Polyhedral platinadicarbaborane chemistry. The molecular structure and some NMR properties of [9,9-(PPh3)2-arachno-9,5,6-PtC2B7H11]
    1991, Vol. 56, Issue 3, pp. 646–656 [Abstract]
  • Ladislav Lešetický, Stanislav Smrček, Vladimír Sváta, Jana Podlahová, Jaroslav Podlaha and Ivana Císařová
    The synthesis and X-ray structure of 3,7-diiododibenzosuberone. Synthesis of 3,7-diiodoamitriptyline
    1990, Vol. 55, Issue 11, pp. 2677–2684 [Abstract]
  • Stanislav Heřmánek, Tomáš Jelínek, Jaromír Plešek, Bohumil Štíbr and Jiří Fusek
    Revision of nido-2,6-C2B7H11 to the arachno-4,5-C2B7H13 structure. Determination of the structure from NMR spectra and chemical origin
    1988, Vol. 53, Issue 11, pp. 2742–2752 [Abstract]
  • Jiří Brynda, Bohumil Kratochvíl and Ivana Císařová
    The determination of crystal structure of chromium(II) phosphite dihydrate, CrHPO3 2 H2O
    1987, Vol. 52, Issue 7, pp. 1742–1747 [Abstract]
  • Bohumil Štíbr, Jaromír Plešek, Tomáš Jelínek, Stanislav Heřmánek, Konstantin A. Solntsev and Nicolai T. Kuznetsov
    Symmetrical isomers of arachno-5,5'-X-(6,9-C2B8H13)2 (X = O and OSO2O) compounds
    1987, Vol. 52, Issue 4, pp. 957–959 [Abstract]
  • Bohumil Štíbr, Zbyněk Janoušek, Jaromír Plešek, Tomáš Jelínek and Stanislav Heřmánek
    Arachno-6,9-C2B8H14 dicarbaborane and its 1- and 5-monohalogenated derivatives
    1987, Vol. 52, Issue 1, pp. 103–112 [Abstract]
  • Tomáš Jelínek, Jaromír Plešek, Stanislav Heřmánek and Bohumil Štíbr
    Chemistry of compounds with the 1-carba-closo-dodecaborane(12) framework
    1986, Vol. 51, Issue 4, pp. 819–829 [Abstract]
  • Jaromír Plešek, Tomáš Jelínek, Stanislav Heřmánek and Bohumil Štíbr
    Synthesis and reactions of 1,2-dicarba-closo-dodecarborane-1-yl tetrahydroborate(1-)
    1986, Vol. 51, Issue 1, pp. 81–89 [Abstract]
  • Tomáš Jelínek, Jaromír Plešek, Stanislav Heřmánek and Bohumil Štíbr
    Preparation of 7-substituted 7-carba-nido-undecaboranes(12)
    1985, Vol. 50, Issue 6, pp. 1376–1382 [Abstract]
  • Jaromír Plešek, Karel Baše, František Mareš, František Hanousek, Bohumil Štíbr and Stanislav Heřmánek
    Potential uses of metallocarborane sandwich anions for analysis, characterization and isolation of various cations and organic bases
    1984, Vol. 49, Issue 12, pp. 2776–2789 [Abstract]
  • Bohumil Štíbr, Zbyněk Janoušek, Karel Baše, Stanislav Heřmánek, Jaromír Plešek and Inessa A. Zakharova
    Synthesis and structure of μ-6,9-metalla-bis(ligand)-6,9-dicarba-nido-decarboranes(10) from the [6,9-C2B8H10]2- anion
    1984, Vol. 49, Issue 8, pp. 1891–1894 [Abstract]
  • Bohumil Štíbr, Zbyněk Janoušek, Karel Baše, Jaromír Plešek, Konstantin A. Solntsev, Lev A. Butman, Igor I. Kuznetsov and Nikolai T. Kuznetsov
    Synthesis of ten-vertex closo-metallacarbaboranes from 4-CB8H14
    1984, Vol. 49, Issue 7, pp. 1660–1664 [Abstract]
  • Jaromír Plešek, Tomáš Jelínek, Eva Drdáková, Stanislav Heřmánek and Bohumil Štíbr
    A convenient preparation of 1-CB11H12- and its C-amino derivatives
    1984, Vol. 49, Issue 7, pp. 1559–1562 [Abstract]
  • Jaromír Plešek, Bohumil Štíbr and Stanislav Heřmánek
    A [8,8'-μ-I-3-Co(1,2-C2B9H10)2] metallacarborane complex with a iodonium bridge. Evidence for a bromonium analogue
    1984, Vol. 49, Issue 6, pp. 1492–1496 [Abstract]
  • Zbyněk Janoušek, Jaromír Plešek, Bohumil Štíbr and Stanislav Heřmánek
    Synthesis and structure of iso-C4B18H22
    1983, Vol. 48, Issue 1, pp. 228–231 [Abstract]
  • Karel Baše, Bohumil Štíbr, Jiří Dolanský and Josef Duben
    Preparation, properties and structure of some intermediate nido- and arachno-monocarbaboranes
    1981, Vol. 46, Issue 10, pp. 2345–2353 [Abstract]