Collect. Czech. Chem. Commun. 2010, 75, 121-131
Published online 2010-02-10 16:07:47

Structure, properties and comparison of C,N-chelated and amido-stabilized plumbylenes

Josef Bareša, Vítězslav Šoureka, Zdeňka Padělkováa, Philippe Meunierb, Nadine Piriob, Ivana Císařovác, Aleš Růžičkaa,* and Jaroslav Holečeka

a Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, nám. Čs. legií 565, 532 10, Pardubice, Czech Republic
b Institute de Chimie Moleculaire de l’Université de Bourgogne, 9 avenue Alain Savary, BP 47870, F-21078 Dijon Cedex, France
c Department of Inorganic Chemistry, Faculty of Science, Charles University, Hlavova 2030, 128 40 Prague 2, Czech Republic


The molecular structure of {2-[(CH3)2NCH2]C6H4}2Pb (1) in the solid state was determined by X-ray diffraction techniques on a single crystalline material. Bulky amido ligand stabilized complexes [(i-C3H7)2C6H3]NHLi (2) and [(i-C3H7)2C6H3N(Me3Si)]2Pb (3) were synthesized and characterized both in the solid state and solution by 1H, 13C, 15N and 207Pb NMR and XRD techniques. The structure of both C,N-chelated and bulky amido plumbylenes is compared.

Keywords: Lead; Bulky amides; C,N-chelates; Plumbylenes; Organoelement chemistry; X-Ray diffraction.

References: 47 live references.