Collect. Czech. Chem. Commun. 2008, 73, 967-982
https://doi.org/10.1135/cccc20080967

Reactions of Doubly Tucked-In Permethyltitanocene with tert-Butanol and Propargyl Alcohol. The Crystal Structures of Unusual Hydrolytic Byproducts

Jiří Pinkasa, Róbert Gyepesb, Ivana Císařováb, Petr Štěpničkab, Michal Horáčeka, Jiří Kubištaa, Vojtech Vargac and Karel Macha,*

a J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, v.v.i., Dolejškova 3, 182 23 Prague 8, Czech Republic
b Department of Inorganic Chemistry, Faculty of Science, Charles University, Hlavova 2030, 128 40 Prague 2, Czech Republic
c Research Institute of Inorganic Chemistry, a.s., Revoluční 84, 400 01 Ústí nad Labem, Czech Republic

Individual author index pages


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    1998, Vol. 63, Issue 1, pp. 64–74 [Abstract]
  • Petr Štěpnička, Ivana Císařová, Jan Sedláček, Jiří Vohlídal and Miroslav Polášek
    Synthesis of Triferrocenylbenzenes by Tantalum(V)-Catalyzed Cyclotrimerization of Ethynylferrocene. The Crystal Structure of 1,3,5-Triferrocenylbenzene
    1997, Vol. 62, Issue 10, pp. 1577–1584 [Abstract]
  • Jörg Hiller, Ulf Thewalt, Jaroslav Podlaha, Vladimír Hanuš and Karel Mach
    Synthesis and Crystal Structures of Dimeric Titanium(II) Bis(trimethylsilyl)acetylene Complexes [(C5H5-nMen)Ti(η2-Me3SiC≡CSiMe3)(μ-Cl)]2(n = 3-5)
    1997, Vol. 62, Issue 10, pp. 1551–1561 [Abstract]
  • Jörg Hiller, Vojtech Varga, Ulf Thewalt and Karel Mach
    Crystal Structures of Titanium(III) Bis(acetylide) Tweezer Complexes with Alkali Metal Cations
    1997, Vol. 62, Issue 9, pp. 1446–1456 [Abstract]
  • Jaroslav Podlaha, Petr Štěpnička, Róbert Gyepes, Vladimír Mareček, Alexander Lhotský, Miroslav Polášek, Jiří Kubišta and Martin Nejezchleba
    Hydrophobic Ferrocene Derivatives as Potential Standards in Electrochemistry
    1997, Vol. 62, Issue 2, pp. 185–198 [Abstract]
  • Jaromír Plešek, Stanislav Heřmánek, Andreas Franken, Ivana Císařová and Christiane Nachtigal
    Dimethyl Sulfate Induced Nucleophilic Substitution of the [Bis(1,2-dicarbollido)-3-cobalt(1-)]ate Ion. Syntheses, Properties and Structures of Its 8,8'-μ-Sulfato, 8-Phenyland 8-Dioxane Derivatives
    1997, Vol. 62, Issue 1, pp. 47–56 [Abstract]
  • Jan-Willem F. Kaagman, Marco Rep, Michal Horáček, Petr Sedmera, Jiří Čejka, Vojtech Varga and Karel Mach
    Titanium-Catalyzed [4+2] and [6+2] Cycloadditions of 1,4-Bis(trimethylsilyl)buta-1,3-diyne
    1996, Vol. 61, Issue 12, pp. 1722–1728 [Abstract]
  • Petr Štěpnička and Ivana Císařová
    Crystal Structure of Dibromo(η4-1,5-cyclooctadiene)palladium(II)
    1996, Vol. 61, Issue 9, pp. 1335–1341 [Abstract]
  • Pavel Vojtíšek and Ivana Císařová
    Complexes of Tris(N-piperidinomethyl)phosphine Oxide with Zinc and Cadmium
    1996, Vol. 61, Issue 9, pp. 1321–1334 [Abstract]
  • Michal Horáček, Róbert Gyepes, Ivana Císařová, Miroslav Polášek, Vojtech Varga and Karel Mach
    Syntheses and Crystal Structures of Bis[(trimethylsilyl)tetramethylcyclopentadienyl]titanium Dichloride and Monochloride
    1996, Vol. 61, Issue 9, pp. 1307–1320 [Abstract]
  • Zdeněk Mička, Lucie Prokopová, Ivana Císařová and David Havlíček
    Crystal Structure, Thermoanalytical Properties and Infrared Spectra of Double Magnesium Selenates
    1996, Vol. 61, Issue 9, pp. 1295–1306 [Abstract]
  • Karel Mach, Vojtech Varga, Günter Schmid, Jörg Hiller and Ulf Thewalt
    The Dimeric Structure of Bis(1,3-Dimethylcyclopentadienyl)titanium(III) Chloride
    1996, Vol. 61, Issue 9, pp. 1285–1294 [Abstract]
  • Jiří Vohlídal, Jaromír Plešek, Jan Sedláček, Ivana Císařová, Pavel Matějka and Stanislav Heřmánek
    Cobaltacarboranylacetylene 8,8'-(μ-CHC-CH2S)-(1,2-C2B9H10)2-3-Co(III): Synthesis, Characterization and Polymerization of New Substituted Acetylene
    1996, Vol. 61, Issue 6, pp. 877–887 [Abstract]
  • Václav Všetečka, Ivana Císařová and Jaroslav Podlaha
    Conformation of Methylsulfonyl Group: A Comparison of the Data for 2-Chlorophenyl Methyl Sulfone in Solution and in Crystal
    1996, Vol. 61, Issue 5, pp. 733–741 [Abstract]
  • Jaroslav Podlaha, Ivana Císařová, Martin Bělohradský and Jiří Závada
    Crystal and Molecular Structure of cis-2,2',3',2"-Tetraacetoxy-1,1':4',1"-ternaphthyl
    1996, Vol. 61, Issue 5, pp. 726–732 [Abstract]
  • Roman Řeřicha, Ivana Císařová and Jaroslav Podlaha
    Crystal and Molecular Structure of Lithium Benzohydroxamate-Benzohydroxamic Acid (1 : 1) Adduct
    1996, Vol. 61, Issue 1, pp. 139–146 [Abstract]
  • Ivana Císařová, Jana Podlahová and Jaroslav Podlaha
    Crystal Structure of the Adduct Hexahydroxotelluric Acid-Disodium Ethylenediaminetetraacetate-Water (1/1/2)
    1995, Vol. 60, Issue 5, pp. 820–828 [Abstract]
  • Dalimil Dvořák, David Šaman, Zdeněk Arnold, Ivana Císařová and Václav Petříček
    Cycloaddition Reactions of Arylmethylenemalonaldehydes with Olefins
    1992, Vol. 57, Issue 11, pp. 2337–2358 [Abstract]
  • Ladislav Lešetický, Stanislav Smrček, Vladimír Sváta, Jana Podlahová, Jaroslav Podlaha and Ivana Císařová
    The synthesis and X-ray structure of 3,7-diiododibenzosuberone. Synthesis of 3,7-diiodoamitriptyline
    1990, Vol. 55, Issue 11, pp. 2677–2684 [Abstract]
  • Jindřich Poláček, Helena Antropiusová, Lidmila Petrusová and Karel Mach
    Effect of triphenylphosphine on the cyclotrimerization of butadiene catalyzed by the TiCl4-EtAlCl2 system
    1990, Vol. 55, Issue 7, pp. 1756–1762 [Abstract]
  • Karel Mach, Helena Antropiusová, Vladimír Hanuš and Petr Sedmera
    Titanium-catalyzed Diels-Alder addition of bis(trimethylsilyl)acetylene to 1,3-cyclohexadiene
    1989, Vol. 54, Issue 11, pp. 3088–3091 [Abstract]
  • Jindřich Poláček, Lidmila Petrusová, Helena Antropiusová and Karel Mach
    The influence of alkali metal halides on the butadiene cyclotrimerization catalyzed by (benzene)titanium(II) complexes
    1989, Vol. 54, Issue 7, pp. 1839–1845 [Abstract]
  • Jiří Brynda, Bohumil Kratochvíl and Ivana Císařová
    The determination of crystal structure of chromium(II) phosphite dihydrate, CrHPO3 2 H2O
    1987, Vol. 52, Issue 7, pp. 1742–1747 [Abstract]
  • Jindřich Poláček, Helena Antropiusová, Lidmila Petrusová and Karel Mach
    Deactivation of arenetitanium(II) bromoalane complexes in the cyclotrimerization of butadiene
    1986, Vol. 51, Issue 12, pp. 2751–2759 [Abstract]
  • Karel Mach, Jana Nováková, Vladimír Hanuš and Zdeněk Dolejšek
    Mass spectrometric and electron spin resonance study of allylic peroxyl radicals in the gas-phase reaction between allylic radicals and dioxygen
    1986, Vol. 51, Issue 12, pp. 2675–2684 [Abstract]
  • Jindřich Poláček, Karel Mach and Lidmila Petrusová
    Effect of mercury chlorides on the activity of complex titanium-based catalysts for the cyclotrimerization of butadiene
    1985, Vol. 50, Issue 9, pp. 2041–2047 [Abstract]
  • Karel Mach, Jana Nováková and Zdeněk Dolejšek
    Trapping of allylic radicals from the gas phase pyrolysis in the adamantane matrix - Isotropic ESR spectra at 77 K
    1984, Vol. 49, Issue 6, pp. 1325–1333 [Abstract]
  • Karel Mach, Lidmila Petrusová, Helena Antropiusová, Vladimír Hanuš, František Tureček and Petr Sedmera
    Intermolecular hydrogen transfer in unsaturated hydrocarbons induced by dimeric titanocene
    1983, Vol. 48, Issue 10, pp. 2924–2936 [Abstract]
  • Karel Mach and Karel Vacek
    Photolytic and thermal annealing of radical anions in gamma-irradiated ammonium salts of carboxylic acids
    1983, Vol. 48, Issue 1, pp. 203–214 [Abstract]
  • František Tureček, Vladimír Hanuš, Petr Sedmera, Helena Antropiusová and Karel Mach
    Cycloheptatriene dimers: New precursors of diamantane
    1981, Vol. 46, Issue 6, pp. 1474–1485 [Abstract]
  • Karel Mach, Igor Janovský and Karel Vacek
    Photolytic and thermal annealing of radical anions gamma-irradiated monocarboxylic acids
    1979, Vol. 44, Issue 12, pp. 3632–3643 [Abstract]
  • Bohumír Matyska, Ludmila Petrusová, Karel Mach and Miroslav Švestka
    Cationic polymerization of isoprene: Initiation by complexes of titanium chloride with halogenoacetic acids
    1979, Vol. 44, Issue 4, pp. 1262–1272 [Abstract]
  • Alexei D. Pershin, Imre Kende, Vlado Cholvad and Karel Mach
    Chemically induced dynamic nuclear polarization in the thermolysis of sulfides with azobisisobutyronitrile
    1978, Vol. 43, Issue 5, pp. 1349–1355 [Abstract]