Collect. Czech. Chem. Commun. 1980, 45, 2400-2409
https://doi.org/10.1135/cccc19802400

Dipole moments induced in larger molecules. 1- And 4-substituted diamantanes

Otto Exnera, Václav Jehličkab, Luděk Vodičkac and Pavel Jakoubekc

a Institute of Organic Chemistry and Biochemistry, Czechoslovak Academy of Sciences, 166 10 Prague 6
b Department of Physical Chemistry, Prague Institute of Chemical Technology, 166 28 Prague 6
c Laboratory of Synthetic Fuels, Prague Institute of Chemical Technology, 166 28 Prague 6

Individual author index pages


Other CCCC articles of these authors

  • Stanislav Böhm and Otto Exner*
    Revision of the Dual-Substituent-Parameter Treatment; Reaction Series with a Donor Reaction Centre
    2007, Vol. 72, Issue 8, pp. 1158–1176 [Abstract]
  • Otto Exner* and Stanislav Böhm
    Analysis of the Ortho Effect: Basicity of 2-Substituted Benzonitriles
    2006, Vol. 71, Issue 8, pp. 1239–1255 [Abstract]
  • Stanislav Böhm and Otto Exner*
    Estimation of Resonance Energy from Forced Nonplanar Conformations of Conjugated Molecules
    2005, Vol. 70, Issue 10, pp. 1577–1588 [Abstract]
  • Stanislav Böhm and Otto Exner*
    Interaction of Polar Groups with a Bulky Hydrocarbon Residue: Polarizability and Steric Effects
    2005, Vol. 70, Issue 3, pp. 370–382 [Abstract]
  • Stanislav Böhm and Otto Exner*
    Attenuation of the Substituent Effects Along the Aliphatic Chain
    2004, Vol. 69, Issue 5, pp. 984–995 [Abstract]
  • Pavel Fiedler and Otto Exner*
    Conformation of Aromatic Carbonyl Derivatives: An Infrared Study
    2004, Vol. 69, Issue 4, pp. 797–810 [Abstract]
  • Otto Exner and Stanislav Böhm*
    Resonance Energy in Benzene Derivatives with a Variable Functional Group
    2001, Vol. 66, Issue 11, pp. 1623–1637 [Abstract]
  • Drahomír Hnyk*, Václav Všetečka, Ladislav Drož and Otto Exner
    Charge Distribution Within 1,2-Dicarba-closo-dodecaborane: Dipole Moments of Its Phenyl Derivatives
    2001, Vol. 66, Issue 9, pp. 1375–1379 [Abstract]
  • Ivana Císařová, Jaroslav Podlaha, Stanislav Böhm and Otto Exner*
    Steric Effects and Steric Inhibition of Resonance in Benzene Derivatives: 2,3-Dimethylbenzoic Acid
    2000, Vol. 65, Issue 2, pp. 216–226 [Abstract]
  • Pavel Fiedler, Jiří Kulhánek, Michèle Decouzon, Jean-François Gal, Pierre-Charles Maria and Otto Exner*
    Steric Effects and Steric Inhibition of Resonance in Isopropylbenzoic Acids in the Gas Phase and in Solution
    1999, Vol. 64, Issue 9, pp. 1433–1447 [Abstract]
  • Karel Waisser*, Karel Palát, Jr. and Otto Exner*
    Substituent Effects on Conformational Equilibria: Substituted Thiobenzanilides
    1999, Vol. 64, Issue 8, pp. 1295–1306 [Abstract]
  • Otto Exner, Martin Hradil and Jiří Mollin
    Dissociation of Hydroxamic Acids: Solvent Effects
    1993, Vol. 58, Issue 5, pp. 1109–1121 [Abstract]
  • Bernard Tinant, Jean-Paul Declercq and Otto Exner
    Deformation of the Adamantane Skeleton by Substitution: Crystal Structure of 1-Methylsulfonyladamantane
    1993, Vol. 58, Issue 2, pp. 373–377 [Abstract]
  • Václav Všetečka, Janusz Oszczapowicz and Otto Exner
    Configuration and Conformation of N,N'-Diarylamidines: A Dipole Moment Study
    1993, Vol. 58, Issue 1, pp. 105–112 [Abstract]
  • Otto Exner and Miloš Buděšínský
    Carbon-13 Substituent-Induced Chemical Shifts: Monosubstituted Benzene Derivatives
    1992, Vol. 57, Issue 3, pp. 497–507 [Abstract]
  • Otto Exner and Miloš Buděšínský*
    Correlation of substituent – inducted chemical shifts of aromatic protons: Substituted benzonitriles and methyl benzoates
    1991, Vol. 56, Issue 11, pp. 2234–2250 [Abstract]
  • Otto Exner and Ivan Mach
    Polarization and apparent dipole moments of some symmetrical molecules
    1991, Vol. 56, Issue 2, pp. 406–410 [Abstract]
  • Miloš Buděšínský, Dan Johnels, Ulf Edlund and Otto Exner
    Carbon-13 substituent-induced chemical shifts in benzene derivatives: Substituted anilines
    1991, Vol. 56, Issue 2, pp. 368–385 [Abstract]
  • Josef Janků, Sergei D. Isaev, Leonid V. Cybulskii, Luděk Vodička and Alexander G. Yurchenko
    Reactions of isomeric oxo-2(3)-oxahomodiamantanes. Dehydration of tetracyclic diols with concentrated phosphoric acid
    1990, Vol. 55, Issue 10, pp. 2475–2480 [Abstract]
  • Zdeněk Kafka and Luděk Vodička
    Isomerization of heptacyclic hydrocarbons to triamantane
    1990, Vol. 55, Issue 8, pp. 2043–2045 [Abstract]
  • Otto Exner
    Studies of association in solution from permitivity measurements: Statistical problems
    1990, Vol. 55, Issue 6, pp. 1435–1456 [Abstract]
  • Jan Ondráček, Josef Janků, Jiří Novotný, Luděk Vodička, László Csordás and Bohumil Kratochvíl
    The Bayer-Villiger oxidation of diamantanone and the structure of 11-oxo-10-oxapentacyclo[7,4,1,14,13,02,7,06,12]-pentadecane
    1989, Vol. 54, Issue 12, pp. 3260–3266 [Abstract]
  • Bernard Tinant, Janine Dupont-Fenfau, Jean-Paul Declercq, Jaroslav Podlaha and Otto Exner
    Configuration on the C=N double bond of monosubstituted amidines and amidoximes
    1989, Vol. 54, Issue 12, pp. 3245–3252 [Abstract]
  • Drahomír Hnyk, Radek Fajgar, Václav Všetečka and Otto Exner
    Dipole moments and conformation of some olefinic and ortho-substituted aromatic methoxy derivatives
    1989, Vol. 54, Issue 5, pp. 1291–1298 [Abstract]
  • Sergei D. Isaev, Nataliya F. Karpenko, Aleksandr G. Yurchenko, Luděk Vodička, Valentin I. Kadentsev and Pavel Zachař
    Compounds of aziadamantane type: Mass spectrometric study
    1989, Vol. 54, Issue 3, pp. 691–698 [Abstract]
  • Otto Exner, Václav Jehlička and Bernard Tinant
    Conformations of molecules bearing two carbonyl groups on adjacent atoms
    1988, Vol. 53, Issue 6, pp. 1260–1267 [Abstract]
  • Otto Exner and Václav Jehlička
    Conjugation within the oximino group: A semiquantitative estimation
    1988, Vol. 53, Issue 5, pp. 1018–1032 [Abstract]
  • Bernard Tinant, Jean-Paul Declercq, Maurice Van Meerssche and Otto Exner
    Structure of 5-nitro-2-methylbenzoic acid: ortho Effect of the methyl group
    1988, Vol. 53, Issue 2, pp. 301–307 [Abstract]
  • Jiří Burkhard, Josef Janků and Luděk Vodička
    Reaction of 1-acetyladamantane with thionyl chloride
    1988, Vol. 53, Issue 1, pp. 110–113 [Abstract]
  • Milan Hájek, Alena Horská, Petr Trška, Luděk Vodička, Douglas J. Raber, Brent L. Podlogar and Joop A. Peters
    Halogen substituted adamantanones. Structural studies with lanthanide shift reagents
    1988, Vol. 53, Issue 1, pp. 97–109 [Abstract]
  • Josef Janků, Jiří Burkhard and Luděk Vodička
    Reaction of adamantanone, diamantanone, and their derivatives with thionyl chloride
    1987, Vol. 52, Issue 8, pp. 2028–2034 [Abstract]
  • Otto Exner and Pavel Fiedler
    Conformation and electronic structure of aromatic chloroformates
    1987, Vol. 52, Issue 4, pp. 970–979 [Abstract]
  • Josef Janků, Jiří Burkhard and Luděk Vodička
    Reaction of 5-oxo-4-oxahomoadamantane with thionyl chloride
    1987, Vol. 52, Issue 3, pp. 752–755 [Abstract]
  • Zdeněk Kafka and Luděk Vodička
    Oxidation of triamantane
    1986, Vol. 51, Issue 12, pp. 2798–2801 [Abstract]
  • Otto Exner and Nedelko Motekov
    Dipole moments and conformation of some aromatic benzamidoximes
    1986, Vol. 51, Issue 7, pp. 1444–1449 [Abstract]
  • Luděk Vodička, Jiří Burkhard and Josef Janků
    Reaction of hydroxydiamantanes with chloroethylenes in sulfuric acid
    1986, Vol. 51, Issue 5, pp. 1086–1093 [Abstract]
  • Zdeněk Kafka and Luděk Vodička
    The Diels-Alder reaction of butadiene with hexacyclic olefins in the synthesis of triamantane
    1986, Vol. 51, Issue 5, pp. 1083–1085 [Abstract]
  • Luděk Vodička, Jiří Burkhard and Josef Janků
    Preparation of diamantanedicarboxylic acids with carboxyl groups on one secondary and one tertiary carbon atom
    1986, Vol. 51, Issue 4, pp. 867–871 [Abstract]
  • Otto Exner and Václav Jehlička
    Dipole moments and conformation of α-disulphones. The gauche effect
    1985, Vol. 50, Issue 10, pp. 2245–2251 [Abstract]
  • Štefan Marchalín, Václav Jehlička, Stanislav Böhm, Petr Trška and Josef Kuthan
    Molecular structure of para-substituted 3-aryl-2-arylmethylene-3-oxopropanenitriles in solution phase
    1985, Vol. 50, Issue 9, pp. 1935–1947 [Abstract]
  • Zdeněk Kafka and Luděk Vodička
    Isomerization of binor S
    1985, Vol. 50, Issue 5, pp. 1212–1215 [Abstract]
  • Juraj Koudelka, David Šaman and Otto Exner
    Secondary steric effects in 2,4,6-trialkylated acetophenones and nitrobenzenes: Dipole moments and 13C NMR spectra
    1985, Vol. 50, Issue 1, pp. 208–214 [Abstract]
  • Otto Exner and Juraj Koudelka
    Principle of additivity of dipole moments: Halogen derivatives of adamantane
    1985, Vol. 50, Issue 1, pp. 200–207 [Abstract]
  • Juraj Koudelka and Otto Exner
    Principle of additivity of dipole moments: 1,3- and 1,3,5-derivatives of benzene
    1985, Vol. 50, Issue 1, pp. 188–199 [Abstract]
  • Zdeněk Friedl, Pavel Fiedler, Ján Biroš, Věra Uchytilová, Igor Tvaroška, Stanislav Böhm and Otto Exner
    Electrostatic effects on conformational equilibria: Solvation enthalpies and the reaction field theory
    1984, Vol. 49, Issue 9, pp. 2050–2069 [Abstract]
  • Luděk Vodička, Sergei D. Isaev, Jiří Burkhard and Josef Janků
    Synthesis and reactions of hydroxydiamantanones
    1984, Vol. 49, Issue 8, pp. 1900–1906 [Abstract]
  • Jan Tříska, Luděk Vodička, Eugenijus P. Butkus and Milan Hájek
    Beckmann rearrangement of adamantanone oxime as a route to ditopic and tritopic secondarily substituted adamantane derivatives
    1984, Vol. 49, Issue 8, pp. 1774–1779 [Abstract]
  • Karel Kalfus, Zdeněk Friedl and Otto Exner
    Electrostatic effects on ionization equilibria: Solvent dependence
    1984, Vol. 49, Issue 1, pp. 179–189 [Abstract]
  • Otto Exner and Tomáš Juška
    X-ray photoelectron spectroscopic study of sulphonamides: Charge distribution and tautomerism
    1984, Vol. 49, Issue 1, pp. 51–57 [Abstract]
  • Otto Exner, Zdeněk Friedl and Pavel Fiedler
    Electrostatic effects on conformational equilibria: Alkyl 2-cyanobenzoates and 3-cyanopropenoates
    1983, Vol. 48, Issue 11, pp. 3086–3096 [Abstract]
  • Evangelia A. Varella, Nicholas E. Alexandrou and Otto Exner
    A mass spectral study of O-aroylbenzohydroximoyl chlorides
    1983, Vol. 48, Issue 9, pp. 2518–2524 [Abstract]
  • Libuše Pavlíčková, Bohumír Koutek, Václav Jehlička and Milan Souček
    Solvatochromic study of internal charge transfer in 7,7-disubstituted quinone methides
    1983, Vol. 48, Issue 8, pp. 2376–2385 [Abstract]
  • Luděk Vodička, Josef Janků and Jiří Burkhard
    Synthesis of diamantanedicarboxylic acids with the carboxy groups bonded at tertiary carbon atoms
    1983, Vol. 48, Issue 4, pp. 1162–1172 [Abstract]
  • Zdeněk Kafka, Luděk Vodička and Milan Hájek
    Oxidation of triamantane by sulphuric acid
    1983, Vol. 48, Issue 4, pp. 1074–1076 [Abstract]
  • Otto Exner and Václav Jehlička
    Conformation around several equivalent bonds. Polymethoxy derivatives of benzene
    1983, Vol. 48, Issue 4, pp. 1030–1041 [Abstract]
  • Barbu A. Demian, Otto Exner and Aurora Sallo
    Kinetics and mechanism of the azo coupling reaction of 1-aminonaphthalene-4-sulfonic acid
    1983, Vol. 48, Issue 3, pp. 748–754 [Abstract]
  • Otto Exner, Juraj Koudelka and Soňa Vašíčková
    Dipole moment of the intramolecular hydrogen bond. 2-Nitrophenol and its derivatives
    1983, Vol. 48, Issue 3, pp. 735–747 [Abstract]
  • Evangelia A. Varella, Evangelos D. Micromastoras, Nicholas E. Alexandrou and Otto Exner
    Sythesis and mass spectra of aroylbenzamidoximes
    1983, Vol. 48, Issue 2, pp. 596–607 [Abstract]
  • Otto Exner, Dario Iarossi and Piero Vivarelli
    Dipole moments induced in larger molecules. Triphenylmethyl derivatives
    1982, Vol. 47, Issue 6, pp. 1733–1737 [Abstract]
  • Otto Exner and Karel Waisser
    Dipole moment and electron distribution of the thioamide group
    1982, Vol. 47, Issue 3, pp. 828–837 [Abstract]
  • Otto Exner and Nedelko Motekov
    Configuration and conformation of amidoximes. N,N-Dialkyl derivatives
    1982, Vol. 47, Issue 3, pp. 814–827 [Abstract]
  • Zdeněk Kafka, Luděk Vodička and Vlastimil Galík
    Isomerization of binor S
    1982, Vol. 47, Issue 1, pp. 286–289 [Abstract]
  • Jaromír Kaválek, Pavel Fiedler, Zlata Papoušková and Otto Exner
    The confirmation of trisubstituted ureas and thioureas in solution
    1982, Vol. 47, Issue 1, pp. 35–44 [Abstract]
  • Otto Exner and Ayfer Bapçum
    Dipole moments induced in larger molecule. Long-chain aliphatic esters
    1982, Vol. 47, Issue 1, pp. 29–34 [Abstract]
  • Otto Exner
    A re-examination of the Eötvös equation
    1981, Vol. 46, Issue 8, pp. 1930–1940 [Abstract]
  • Otto Exner
    A comparison of methods for determining dipole moments in solution
    1981, Vol. 46, Issue 4, pp. 1002–1010 [Abstract]
  • Otto Exner and Václav Jehlička
    The conformation of aryl carbonates. A dipole moment study
    1981, Vol. 46, Issue 4, pp. 856–860 [Abstract]
  • Aleksandr I. Artemenko, Inga V. Tikunova, Evgenii K. Anufriev, Václav Jehlička and Otto Exner
    Dipole moments of hydroxamic acids and N,O-diacylhydroxylamines
    1981, Vol. 46, Issue 3, pp. 729–739 [Abstract]
  • Božo Plesničar and Otto Exner
    Dipole moments and conformation of peroxy esters
    1981, Vol. 46, Issue 2, pp. 490–497 [Abstract]
  • Luděk Vodička, Jan Tříska and Milan Hájek
    Synthesis, separation, and identification of 4-bromoadamantan-2-one stereoisomers
    1980, Vol. 45, Issue 10, pp. 2670–2674 [Abstract]
  • Vladimír Hanuš, Milan Hrazdira and Otto Exner
    Pyrazolidine derivatives from the condensation reaction of hydrazobenzene with aliphatic aldehydes
    1980, Vol. 45, Issue 9, pp. 2417–2424 [Abstract]
  • Otto Exner and Zlata Papoušková
    Dipole moment and electron distribution of the amide group
    1980, Vol. 45, Issue 9, pp. 2410–2416 [Abstract]
  • Zdeněk Friedl, Pavel Fiedler and Otto Exner
    Electrostatic effects on conformational equilibria. Solvent dependence
    1980, Vol. 45, Issue 5, pp. 1351–1360 [Abstract]
  • Otto Exner and Pavel Fiedler
    A refined empirical model of the sigma-inductive effect
    1980, Vol. 45, Issue 4, pp. 1251–1268 [Abstract]
  • Vladimír Král, Zdeněk Arnold, Václav Jehlička and Otto Exner
    Quantum chemical study of sulfonium ylides: Structure, charge distribution and dipole moments
    1980, Vol. 45, Issue 4, pp. 1236–1250 [Abstract]
  • Otto Exner
    Substituent effects in electronic spectroscopy: Correlations with Platt spectroscopic moments
    1980, Vol. 45, Issue 3, pp. 843–853 [Abstract]
  • Luděk Vodička, Jiří Burkhard and Josef Janků
    Preparation of higher adamantane homologues by reaction of adamantan-1-ol with heptenes in sulfuric acid
    1980, Vol. 45, Issue 3, pp. 835–842 [Abstract]
  • Otto Exner and Jan B. F. N. Engberts
    The gauche effect on conformation. α-Substituted sulfones and N-substituted sulfonamides
    1979, Vol. 44, Issue 11, pp. 3378–3384 [Abstract]
  • Luděk Vodička and Josef Hlavatý
    Synthesis and separation of stereoisomers of 1,4- and 2,4-dihydroxyadamantanes
    1979, Vol. 44, Issue 11, pp. 3296–3300 [Abstract]
  • Dušan Ilavský, Václav Jehlička and Josef Kuthan
    Structure of reaction product of 3-aminocrotononitrile with esters of alkoxymethylenecyanoacetic acid
    1979, Vol. 44, Issue 11, pp. 3288–3295 [Abstract]
  • Zdeněk Friedl, Jaroslav Hapala and Otto Exner
    Electrostatic effects on ionization equilibria. 3-Substituted bicyclo[2,2,2]octane-1-carboxylic acids
    1979, Vol. 44, Issue 10, pp. 2928–2945 [Abstract]
  • Otto Exner, Jorga Smolíková, Václav Jehlička and Ahmad S. Shawali
    Hydrogen bonding, configuration and conformation of substituted α-oxo oximes and hydrazones
    1979, Vol. 44, Issue 8, pp. 2494–2506 [Abstract]
  • Jan Schraml, Harald Jancke, Günter Engelhardt, Luděk Vodička and Josef Hlavatý
    13C NMR spectra of hydroxy adamantanes additivity in 13C NMR spectra of dihydroxyadamantanes
    1979, Vol. 44, Issue 7, pp. 2230–2237 [Abstract]
  • Břetislav Princ and Otto Exner
    Structure reexamination of aliphatic nitrones and their dimers
    1979, Vol. 44, Issue 7, pp. 2221–2229 [Abstract]
  • Jan Tříska, Luděk Vodička and Josef Hlavatý
    Beckmann rearrangement of 2-oximinoadamantane in hydrobromic acid
    1979, Vol. 44, Issue 5, pp. 1448–1452 [Abstract]
  • Milan Hájek, Gustav Šebor, Ivo Lang, Zenon Starčuk, Otto Weisser and Luděk Vodička
    Characterization of heavy crude oil fractions by means of the 13C NMR technique
    1979, Vol. 44, Issue 4, pp. 1160–1166 [Abstract]
  • Jiří Mollin, Pavel Fiedler, Václav Jehlička and Otto Exner
    The conformation of substituted hydroxyureas and hydroxythioureas in solution
    1979, Vol. 44, Issue 3, pp. 895–907 [Abstract]
  • Jiří Karhan, Milan Hájek, Zbyněk Ksandr and Luděk Vodička
    Application of the relaxation reagent Gd(FOD)3 (1,1,1,2,2,3,3-heptafluoro-7,7-dimethyl-4,6-octanedionate)gadolinium(III) in 1H NMR spectroscopy of adamantoid compounds
    1979, Vol. 44, Issue 2, pp. 533–541 [Abstract]
  • Otto Exner and Zdeněk Friedl
    Electrostatic effects on ionization equilibria. Carboxylic acids and amines derived from 1-indanone
    1978, Vol. 43, Issue 12, pp. 3227–3240 [Abstract]
  • Jan Schraml, Jaroslav Včelák, Václav Chvalovský, Günter Engelhardt, Harald Jancke, Luděk Vodička and Josef Hlavatý
    29Si and 13C-NMR spectra and steric effects in mono- and bis(trimethylsiloxy)adamantanes
    1978, Vol. 43, Issue 12, pp. 3179–3191 [Abstract]
  • Otto Exner and Božo Plesničar
    Hydrogen bonding and conformation of substituted peroxybenzoic acids as reflected in dipole moment values
    1978, Vol. 43, Issue 11, pp. 3079–3086 [Abstract]
  • Otto Exner and Pavel Vetešník
    Substituent efect in electronic spectroscopy: meta- and para-substituted benzonitriles
    1978, Vol. 43, Issue 10, pp. 2763–2778 [Abstract]
  • Božo Plesničar, Jorga Smolíková, Václav Jehlička and Otto Exner
    Dipole moment of the intramolecular hydrogen bond. Substituted α-hydroxyacetophenones
    1978, Vol. 43, Issue 10, pp. 2754–2762 [Abstract]
  • Otto Exner and Nedelko Motekov
    Configuration and conformation of amidoximes. Aromatic derivatives with a free amino group
    1978, Vol. 43, Issue 10, pp. 2740–2753 [Abstract]
  • Zdeněk Friedl and Otto Exner
    Electrostatic effects on conformational equilibria 3-substituted benzonitriles
    1978, Vol. 43, Issue 10, pp. 2591–2599 [Abstract]
  • Luděk Vodička, Josef Janků and Jiří Burkhard
    Bromination of adamantane in the presence of nitric acid
    1978, Vol. 43, Issue 5, pp. 1410–1412 [Abstract]
  • Zdeněk Kafka, Vlastimil Galík and Luděk Vodička
    Study of reactivity of some 1,3,5-triazaadamantane derivatives
    1978, Vol. 43, Issue 1, pp. 151–155 [Abstract]