Collect. Czech. Chem. Commun. 2002, 67, 813-821

Two Forgotten Ten-Vertex arachno Triheteroboranes: arachno-5,6,9-C2SB7H11 and arachno-5,6,9-C3B7H13, Their Molecular Structure Determination by ab initio/NMR Approach and Synthesis of the Thiacarbaborane

Drahomír Hnyk* and Josef Holub

Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, 250 68 Řež, Czech Republic

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Other CCCC articles of these authors

  • Dmitry S. Perekalin, Evgeniya A. Trifonova, Ivan V. Glukhov, Josef Holub and Alexander R. Kudinov*
    Cyclopentadienyl ruthenium complexes with tricarbollide ligands
    2010, Vol. 75, Issue 11, pp. 1139–1148 [Abstract]
  • Drahomír Hnyk*, Josef Holub, Tomáš Jelínek, Jan Macháček and Michael G. S. Londesborough*
    Revisiting B20H16 by means of a joint computational/experimental NMR approach
    2010, Vol. 75, Issue 11, pp. 1115–1123 [Abstract]
  • Dmitry A. Loginov, Mikhail M. Vinogradov, Zoya A. Starikova, Pavel V. Petrovskii, Josef Holub and Alexander R. Kudinov*
    The first metallacarborane triple-decker complexes with a bridging pentaphospholyl ligand
    2010, Vol. 75, Issue 9, pp. 981–993 [Abstract]
  • Ladislav Drož, Mark A. Fox, Drahomír Hnyk*, Paul J. Low, J. A. Hugh MacBride and Václav Všetečka
    Experimental and computed dipole moments in donor–bridge–acceptor systems with p-phenylene and p-carboranediyl bridges
    2009, Vol. 74, Issue 1, pp. 131–146 [Abstract]
  • Martin Lepšík, Martin Srnec, Drahomír Hnyk, Bohumír Grüner, Jaromír Plešek, Zdeněk Havlas and Lubomír Rulíšek*
    exo-Substituent effects in halogenated icosahedral (B12H122–) and octahedral (B6H62–) closo-borane skeletons: chemical reactivity studied by experimental and quantum chemical methods
    2009, Vol. 74, Issue 1, pp. 1–27 [Abstract]
  • Josef Holub, Mario Bakardjiev and Bohumil Štíbr*
    Electrophilic Halogenation of nido-5,6-C2B8H12
    2006, Vol. 71, Issue 11-12, pp. 1549–1556 [Abstract]
  • Josef Holub, Mario Bakardjiev and Bohumil Štíbr*
    The Synthesis of 10-Halo-Substituted Derivatives of nido-7,8,9-PC2B8H11 and [nido-7,8,9-PC2B8H10]- and New Linear Correlations Between NMR Parameters
    2005, Vol. 70, Issue 11, pp. 1861–1872 [Abstract]
  • Josef Holub, Tomáš Jelínek and Zbyněk Janoušek*
    New Multigram-Scale Preparation of 1,10-Dicarba-closo-decaborane
    2002, Vol. 67, Issue 7, pp. 949–952 [Abstract]
  • Josef Holub, Mario Bakardjiev and Bohumil Štíbr*
    Some Halogenation Reactions of nido-7,8,9,11-P2C2B7H9
    2002, Vol. 67, Issue 6, pp. 783–790 [Abstract]
  • Drahomír Hnyk*, Václav Všetečka, Ladislav Drož and Otto Exner
    Charge Distribution Within 1,2-Dicarba-closo-dodecaborane: Dipole Moments of Its Phenyl Derivatives
    2001, Vol. 66, Issue 9, pp. 1375–1379 [Abstract]
  • Drahomír Hnyk*, Matthias Hofmann and Paul von Ragué Schleyer
    4,6-Dicarba-8-thia-arachno-nonaborane(10) Revisited. Theoretical Refinement of Its Structure
    1999, Vol. 64, Issue 6, pp. 993–1000 [Abstract]
  • Bohumil Štíbr, Josef Holub, Tomáš Jelínek, Bohumír Grüner, Jiří Fusek, Zbyněk Plzák, Francesc Teixidor, Clara Viñas and John D. Kennedy
    A Return to the Plesek Reaction and Some Useful Variations. Carbon-Substituted Methyl and Phenyl Derivatives of 5,6-Dicarba-nido-decaborane(12), nido-5,6-C2B8H12
    1997, Vol. 62, Issue 8, pp. 1229–1238 [Abstract]
  • Jaromír Plešek, Bohumír Grüner and Josef Holub
    Synthesis and Properties of Cobaltacarboranes with Substituted Monoatomic Bridges Between Ligands of the 6,6'-μ-RnE(1,7-C2B9H10)2-2-Co Type
    1997, Vol. 62, Issue 6, pp. 884–893 [Abstract]
  • Bohumil Štíbr, Josef Holub, Francesc Teixidor and Clara Viñas
    The First Examples of Metallatricarbollides. Isomeric Twelve-Vertex Cyclopentadienyl Ferratricarbadodecaboranes [(η5-C5H5)-closo-FeC3B8H11]
    1995, Vol. 60, Issue 12, pp. 2023–2027 [Abstract]
  • Tomáš Jelínek, Josef Holub, Bohumil Štíbr, Xavier L. R. Fontaine and John D. Kennedy
    Nine- and Eight-Vertex Polyhedral Dicarbaborane Chemistry: New arachno and hypho Dicarbaboranes from arachno-4,5-C2B7H13: Isolation and Characterization of the [arachno-4,5-C2B7H12]- and [hypho-7,8-C2B6H13]- Anions, and of the Neutral Ligand Derivatives exo-6-(MeNC)-arachno-4,5-C2B7H11 and exo-5-L-hypho-4,9-C2B7H13 (L = NMe3 and NEt3)
    1994, Vol. 59, Issue 7, pp. 1584–1595 [Abstract]
  • Josef Holub, John D. Kennedy and Bohumil Štíbr
    Nine-Vertex Polyhedral Monothiaborane Chemistry. The First nido Thianonaborane: Isolation and Characterization by NMR of the [nido-9-SB8H9]- Anion, and its Conversion to Compounds of the 6-L-arachno-4-SB8H10 Series (where L = SMe2 and Pyridine)
    1994, Vol. 59, Issue 2, pp. 367–373 [Abstract]
  • Drahomír Hnyk
    Principal component analysis of substituent constants
    1990, Vol. 55, Issue 1, pp. 55–62 [Abstract]
  • Drahomír Hnyk, Radek Fajgar, Václav Všetečka and Otto Exner
    Dipole moments and conformation of some olefinic and ortho-substituted aromatic methoxy derivatives
    1989, Vol. 54, Issue 5, pp. 1291–1298 [Abstract]
  • Drahomír Hnyk, Miloš Procházka and Libor Juška
    Empirical parameters of (E-Z) isomerization
    1985, Vol. 50, Issue 12, pp. 2884–2892 [Abstract]