Collect. Czech. Chem. Commun.
2007, 72, 569-578
https://doi.org/10.1135/cccc20070569
Protonation of the Sulfonamido Ligands in Their Fe(CO)2Cp Complexes
Maria Makowskaa, Janusz Zakrzewskia,* and Agnieszka Rybarczyk-Pirekb
a Department of Organic Chemistry, University of Łódź, Narutowicza 68, 90-136 Łódź, Poland
b Department of Crystallography, University of Łódź, Pomorska 149/153, 90-136 Łódź, Poland
Abstract
[Fe(CO)2Cp(4-RC6H4SO2NH)] complexes (R = Me, NO2) undergo reversible protonation at the nitrogen atom bonded to the iron centre. The molecular structure of the methyl complex was determined by single crystal X-ray diffraction.
Keywords: Cyclopentadienyl ligands; Iron carbonyl complexes; Sulfonamides; Protonation; X-Ray diffraction; Basicity.
References: 19 live references.
