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Collect. Czech. Chem. Commun. 1999, 64, 986-992
https://doi.org/10.1135/cccc19990986

NMR Assignments of [6-R-nido-5,6-C2B8H10]- Anions (where R = H, Me, and n-C6H13). An Irreversible 5 → 6 Alkyl Migration via a B9 Vertex-Swing Mechanism

Zbyněk Janoušeka,*, Piotr Kaszynskib, John D. Kennedyc and Bohumil Štíbra

a Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, 250 68 Řež near Prague, Czech Republic
b Department of Chemistry, Vanderbilt University, Nashville, TN 37235, U.S.A.
c The School of Chemistry, University of Leeds, Leeds LS2 9JT, U.K.

Crossref Cited-by Linking

  • Štíbr Bohumil: Alpha shift correlation (ASC) method. Sensitivity of 11 B NMR shifts to halogen substitution in the ten-vertex nido and arachno series of boron clusters. Linear behavior of NMR effects. Inorganica Chimica Acta 2018, 471, 615. <https://doi.org/10.1016/j.ica.2017.11.040>
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  • Bakardjiev Mario, Štíbr Bohumil, Tok Oleg L., Holub Josef: Unusual Closure of the Ten-Vertex Nido Cage via Alkylation: Regiospecific Synthesis of 3-Alkyl Derivatives of closo-1,2-C2B8H10. Inorg. Chem. 2018, 57, 1368. <https://doi.org/10.1021/acs.inorgchem.7b02783>
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  • Lazareva A. I., Pisareva I. V., Balagurova E. V., Smolyakov A. F., Dolgushin F. M., Godovikov I. A., Chizhevsky I. T.: Synthesis and molecular structure of a manganese tricarbonyl complex based on 5,6-nido-C2B8H12 carborane. Russ Chem Bull 2017, 66, 2142. <https://doi.org/10.1007/s11172-017-1994-2>
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  • Pisareva I. V., Balagurova E. V., Dolgushin F. M., Godovikov I. A., Chizhevsky I. T.: Anionic commo-rhodacarborane clusters: [tmndH][commo-1,1′-Rh(2,4-C2B8H10)2] as a structurally new derivative of middle-cage [5,6-nido-C2B8H12] carborane. Russ Chem Bull 2014, 63, 777. <https://doi.org/10.1007/s11172-014-0509-7>
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  • Dolgushin F. M., Balagurova E. V., Pisareva I. V., Godovikov I. A., Barakovskaya I. G., Chizhevsky I. T.: First cupracarborane commo-clusters based on the medium-cage nido-5,6-C2B8H12-carborane and molecular structure of [Ph3PEt][commo-9,9′-Cu(nido-7,8-C2B8H11)2]. Russ Chem Bull 2013, 62, 1919. <https://doi.org/10.1007/s11172-013-0276-x>
  • Štíbr Bohumil: Carbon insertion into borane clusters via nucleophilic addition reactions of borane and carborane anions. Journal of Organometallic Chemistry 2013, 747, 16. <https://doi.org/10.1016/j.jorganchem.2013.04.010>
  • Kononova E.G., Klemenkova Z.S., Balagurova E.V., Pisareva I.V.: A new look at the structure and reactivity of 10-vertex nido-dicarbaboranes. Journal of Molecular Structure 2010, 970, 36. <https://doi.org/10.1016/j.molstruc.2010.01.067>
  • Holub Josef, Štíbr Bohumil, Štěpnička Petr, Císařová Ivana: Synthesis and electrochemistry of some ferrocenyl substituted dicarba- and tricarbaborane compounds. Dalton Trans. 2010, 39, 2057. <https://doi.org/10.1039/b919767b>
  • Bakardjiev Mario, Holub Josef, Štíbr Bohumil, Císařová Ivana: Synthesis of C-substituted t-BuNH-8,9-R,R′-nido-7,8,9-C3B8H9 (R,R′ = H,H; MeH; Me,Me; Ph,H and Ph,Ph) tricarbollide compounds and their tautomeric conversions. Effect of substituents on tautomeric equilibria between neutral and zwitterionic forms. Dalton Trans. 2010, 39, 4186. <https://doi.org/10.1039/b924754h>
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  • Bown Mark, Grüner Bohumı́r, Štı́br Bohumil, Fontaine Xavier L.R., Thornton-Pett Mark, Kennedy John D.: Eleven-vertex polyhedral metalladicarbaborane chemistry. Reactions of neutral nido-5,6-C2B8H12 and the [nido-6,9-C2B8H10]2− anion to give formally closo isomeric 1-(arene) and 1-(cyclopentadiene)-1,2,4- and 1,2,3-metalladicarbaundecaboranes, and some substituent chemistry. Chiral separations, and crystal and molecular structures of [5-Br-1-(η6-C6Me6)-1,2,4-RuC2B8H9] and [2-Me-1-(η5-C5Me5)-1,2,3-RhC2B8H9]. Journal of Organometallic Chemistry 2000, 614-615, 269. <https://doi.org/10.1016/S0022-328X(00)00615-X>
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