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Collect. Czech. Chem. Commun. 1997, 62, 1446-1456
https://doi.org/10.1135/cccc19971446

Crystal Structures of Titanium(III) Bis(acetylide) Tweezer Complexes with Alkali Metal Cations

Jörg Hillera, Vojtech Vargab, Ulf Thewalta and Karel Machb

a Sektion für Röntgen- und Elektronenbeugung, Universität Ulm, 89069 Ulm, Germany
b J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic,182 23 Prague 8, Czech Republic

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  • Pinkas Jiří, Lukešová Lenka, Gyepes Róbert, Císařová Ivana, Kubišta Jiří, Horáček Michal, Mach Karel: Reduction-Induced Exclusive Activation of the ansa-1,2-Bis(dimethylsilylene)ethane Chain in ansa-Permethyltitanocene Compounds. Organometallics 2010, 29, 5199. <https://doi.org/10.1021/om1003623>
  • Finze Maik: Carba-closo-dodecaborates with One or Two Alkynyl Substituents Bonded to Boron. Inorg. Chem. 2008, 47, 11857. <https://doi.org/10.1021/ic801610b>
  • Morris J. Jacob, Noll Bruce C., Honeyman Gordon W., O'Hara Charles T., Kennedy Alan R., Mulvey Robert E., Henderson Kenneth W.: Organometallic Polymers Assembled from Cation–π Interactions: Use of Ferrocene as a Ditopic Linker Within the Homologous Series [{(Me3Si)2NM}2⋅(Cp2Fe)]∞ (M=Na, K, Rb, Cs; Cp=cyclopentadienyl). Chemistry A European J 2007, 13, 4418. <https://doi.org/10.1002/chem.200700219>
  • Horáček Michal, Císařová Ivana, Kubišta Jiří, Spannenberg Anke, Dallmann Kai, Rosenthal Uwe, Mach Karel: Titanocene – 1,4,6-tris(trimethylsilyl)hex-3-ene-1,5-diyne-3-yl complexes – crystal structures and their retro reaction. Journal of Organometallic Chemistry 2004, 689, 4592. <https://doi.org/10.1016/j.jorganchem.2004.08.035>
  • Mach Karel, Gyepes Róbert, Horáček Michal, Petrusová Lidmila, Kubišta Jiří: Linear Dimerization of Terminal Alkynes by Bis(tetramethylphenylcyclopentadienyl)titanium-Magnesium Hydride and Acetylide Complexes. Collect. Czech. Chem. Commun. 2003, 68, 1877. <https://doi.org/10.1135/cccc20031877>
  • Schiefer Marcus, Hatop Hagen, Roesky Herbert W., Schmidt Hans-Georg, Noltemeyer Mathias: Organoaluminates with Three Terminal Phenylethynyl Groups and Their Interactions with Alkali Metal Cations. Organometallics 2002, 21, 1300. <https://doi.org/10.1021/om010690v>
  • Fernández Francisco J., Alfonso Montserrat, Schmalle Helmut W., Berke Heinz: Utilization of Redox and Acid/Base Chemistry for the Deprotection of a Mn(dmpe)2(C⋮CSiMe3)2 Complex. Organometallics 2001, 20, 3122. <https://doi.org/10.1021/om010172k>
  • Kirchbauer Frank G., Pellny Paul-Michael, Sun Hongsui, Burlakov Vladimir V., Arndt Perdita, Baumann Wolfgang, Spannenberg Anke, Rosenthal Uwe: Synthesis and Reactions with Carbon Dioxide of Mono(σ-alkynyl) Titanocene(III) Complexes Cp*2Ti(C⋮CR) (R = Me, t-Bu) and the Corresponding “Ate” Complexes [Cp*2Ti(C⋮CR)2Li(THF)n] (R = SiMe3, t-Bu, Ph). Organometallics 2001, 20, 5289. <https://doi.org/10.1021/om010404f>
  • Gyepes Róbert, Císařová Ivana, Horáček Michal, Čejka Jiří, Petrusová Lidmila, Mach Karel: Crystal Structures of Unusual Titanocene By-products from Attempted Dimerization of Terminal Alkynes. Collect. Czech. Chem. Commun. 2000, 65, 1248. <https://doi.org/10.1135/cccc20001248>