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Collect. Czech. Chem. Commun. 1997, 62, 884-893

Synthesis and Properties of Cobaltacarboranes with Substituted Monoatomic Bridges Between Ligands of the 6,6'-μ-RnE(1,7-C2B9H10)2-2-Co Type

Jaromír Plešek, Bohumír Grüner and Josef Holub

Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, 250 68 Řež near Prague, Czech Republic

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  • Sardo Carla, Janczak Sławomir, Leśnikowski Zbigniew J.: Unusual resistance of cobalt bis dicarbollide phosphate and phosphorothioate bridged esters towards alkaline hydrolysis: The “metallacarborane effect”. Journal of Organometallic Chemistry 2019, 896, 70. <>
  • Timofeev Sergey V., Sivaev Igor B., Prikaznova Elena A., Bregadze Vladimir I.: Transition metal complexes with charge-compensated dicarbollide ligands. Journal of Organometallic Chemistry 2014, 751, 221. <>
  • Grüner Bohumír, Kvíčalová Magdaléna, Plešek Jaromír, Šícha Václav, Císařová Ivana, Lučaníková Mária, Selucký Pavel: Cobalt bis(dicarbollide) ions functionalized by CMPO-like groups attached to boron by short bonds; efficient extraction agents for separation of trivalent f-block elements from highly acidic nuclear waste. Journal of Organometallic Chemistry 2009, 694, 1678. <>
  • Horáková Hana, Vespalec Radim: Chiral separability of hydrophobic boron cluster anions with native cyclodextrins in water–methanol background electrolytes. Electrophoresis 2007, 28, 3639. <>
  • Plešek Jaromír, Císařová Ivana, Bačkovský Jaroslav: Cobalt Bis(1,2-dicarbollide) Ion with a Disulfur Bridge Between B(8) and B(8'). X-Ray Structure, Absolute Configuration of One Enantiomer, and Implications. Collect. Czech. Chem. Commun. 2002, 67, 569. <>
  • Bown Mark, Grüner Bohumı́r, Štı́br Bohumil, Fontaine Xavier L.R., Thornton-Pett Mark, Kennedy John D.: Eleven-vertex polyhedral metalladicarbaborane chemistry. Reactions of neutral nido-5,6-C2B8H12 and the [nido-6,9-C2B8H10]2− anion to give formally closo isomeric 1-(arene) and 1-(cyclopentadiene)-1,2,4- and 1,2,3-metalladicarbaundecaboranes, and some substituent chemistry. Chiral separations, and crystal and molecular structures of [5-Br-1-(η6-C6Me6)-1,2,4-RuC2B8H9] and [2-Me-1-(η5-C5Me5)-1,2,3-RhC2B8H9]. Journal of Organometallic Chemistry 2000, 614-615, 269. <>
  • Sivaev Igor B, Semioshkin Andrei A, Brellochs Bernd, Sjöberg Stefan, Bregadze Vladimir I: Synthesis of oxonium derivatives of the dodecahydro-closo-dodecaborate anion [B12H12]2−. Tetramethylene oxonium derivative of [B12H12]2− as a convenient precursor for the synthesis of functional compounds for boron neutron capture therapy. Polyhedron 2000, 19, 627. <>
  • Grüner Bohumir, Cisařová Ivana, Franken Andreas, Plešek Jaromı́r: Resolution of the [6,6′-μ-(CH3)2P-(1,7-(C2B9H10)2)-2-Co] bridged cobaltacarborane to enantiomers pure by chiral HPLC, circular dichroism spectra and absolute configurations by X-ray diffraction. Tetrahedron: Asymmetry 1998, 9, 79. <>
  • A. Beckett M.: Chapter 3. Boron. Annu. Rep. Prog. Chem., Sect. A 1998, 94, 19. <>