Collect. Czech. Chem. Commun. 1993, 58, 1534-1547
https://doi.org/10.1135/cccc19931534

Unique Dialkylsulfonio-Methylation of the 7,8-C2B9H12(-) Ion to the 9-R2S-CH2-7,8-C2B9H11 Zwitterions by Formaldehyde and Dialkyl Sulfides. General Synthesis of the Compounds 10-R2E-7,8-C2B9H11 (E = O, S)

Jaromír Plešek, Tomáš Jelínek, František Mareš and Stanislav Heřmánek

Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, 250 68 Řež near Prague, Czech Republic

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Other CCCC articles of these authors

  • Drahomír Hnyk*, Josef Holub, Tomáš Jelínek, Jan Macháček and Michael G. S. Londesborough*
    Revisiting B20H16 by means of a joint computational/experimental NMR approach
    2010, Vol. 75, Issue 11, pp. 1115–1123 [Abstract]
  • Martin Lepšík, Martin Srnec, Drahomír Hnyk, Bohumír Grüner, Jaromír Plešek, Zdeněk Havlas and Lubomír Rulíšek*
    exo-Substituent effects in halogenated icosahedral (B12H122–) and octahedral (B6H62–) closo-borane skeletons: chemical reactivity studied by experimental and quantum chemical methods
    2009, Vol. 74, Issue 1, pp. 1–27 [Abstract]
  • Tomáš Jelínek, Mark Thornton-Pett and John D. Kennedy*
    Monocarbaborane Anion Chemistry. Syntheses and Structures Within the closo Nine-Vertex System
    2002, Vol. 67, Issue 7, pp. 1035–1050 [Abstract]
  • Josef Holub, Tomáš Jelínek and Zbyněk Janoušek*
    New Multigram-Scale Preparation of 1,10-Dicarba-closo-decaborane
    2002, Vol. 67, Issue 7, pp. 949–952 [Abstract]
  • Jaromír Plešek*, Ivana Císařová and Jaroslav Bačkovský
    Cobalt Bis(1,2-dicarbollide) Ion with a Disulfur Bridge Between B(8) and B(8'). X-Ray Structure, Absolute Configuration of One Enantiomer, and Implications
    2002, Vol. 67, Issue 5, pp. 569–576 [Abstract]
  • Jaromír Plešek*, Jaroslav Bačkovský, Jiří Fusek and Zbyněk Plzák
    Cyanoethylation and (Methoxycarbonyl)ethylation of Icosahedral ortho-Carborane Derivatives at Carbon Vertices via Michael Additions
    2001, Vol. 66, Issue 10, pp. 1499–1507 [Abstract]
  • Bohumil Štíbr, Josef Holub, Tomáš Jelínek, Bohumír Grüner, Jiří Fusek, Zbyněk Plzák, Francesc Teixidor, Clara Viñas and John D. Kennedy
    A Return to the Plesek Reaction and Some Useful Variations. Carbon-Substituted Methyl and Phenyl Derivatives of 5,6-Dicarba-nido-decaborane(12), nido-5,6-C2B8H12
    1997, Vol. 62, Issue 8, pp. 1229–1238 [Abstract]
  • Andreas Franken, Jaromír Plešek, Jiří Fusek and Markus Semrau
    Cobaltacarboranes with Intramolecular Monophosphorus Bridges 8,8'-μ-Me2P(1,2-C2B9H10)2-3-Co, 6,6'-μ-Me2P(1,7-C2B9H10)2-2-Co and the Respective Non-Bridged Trimethylphosphine Derivatives (8-Me3P-1,2-C2B9H10)-3-Co-(1,2-C2B9H11) and (6-Me3P-1,7-C2B9H10)-2-Co-(1,7-C2B9H11)
    1997, Vol. 62, Issue 7, pp. 1070–1079 [Abstract]
  • Jaromír Plešek, Bohumír Grüner and Josef Holub
    Synthesis and Properties of Cobaltacarboranes with Substituted Monoatomic Bridges Between Ligands of the 6,6'-μ-RnE(1,7-C2B9H10)2-2-Co Type
    1997, Vol. 62, Issue 6, pp. 884–893 [Abstract]
  • Andreas Franken, Jaromír Plešek and Christiane Nachtigal
    Unusual Rearrangement of Naphthalene in the Synthesis of a Novel B8-B8-Bridged Derivative in the [(1,2-C2B9H11)2-3-Co]- Series. X-Ray Structure and 11B NMR Spectra of [8,8'-μ-(CH2-C9H6)-(1,2-C2B9H10)2-3-Co]- (CH3)4N+
    1997, Vol. 62, Issue 5, pp. 746–751 [Abstract]
  • Jaromír Plešek, Andreas Franken and Roland Fröhlich
    The Structure of [6,6'-μ-S(1,7-C2B9H10)2-2-Co]-[PPh4]+
    1997, Vol. 62, Issue 1, pp. 57–61 [Abstract]
  • Jaromír Plešek, Stanislav Heřmánek, Andreas Franken, Ivana Císařová and Christiane Nachtigal
    Dimethyl Sulfate Induced Nucleophilic Substitution of the [Bis(1,2-dicarbollido)-3-cobalt(1-)]ate Ion. Syntheses, Properties and Structures of Its 8,8'-μ-Sulfato, 8-Phenyland 8-Dioxane Derivatives
    1997, Vol. 62, Issue 1, pp. 47–56 [Abstract]
  • Jiří Vohlídal, Jaromír Plešek, Jan Sedláček, Ivana Císařová, Pavel Matějka and Stanislav Heřmánek
    Cobaltacarboranylacetylene 8,8'-(μ-CHC-CH2S)-(1,2-C2B9H10)2-3-Co(III): Synthesis, Characterization and Polymerization of New Substituted Acetylene
    1996, Vol. 61, Issue 6, pp. 877–887 [Abstract]
  • Jaromír Plešek and Stanislav Heřmánek
    The (η-1,7'-2,2')4,8'-8,4'-(Bis-μ-o-phenylene)bisdicarbollidocobalt(1-)ate Ion [3-Co-4,8'-8,4'(o-C6H4)2(1,2-C2B9H9)2](-). The First Doubly Bridged Metallacarborane Complex. Synthesis, Properties and Structure
    1995, Vol. 60, Issue 8, pp. 1297–1302 [Abstract]
  • Tomáš Jelínek, Bohumil Štíbr and John D. Kennedy
    Nine-Vertex Polyhedral Monoazaborane Chemistry: Synthesis and NMR Characterization of exo-6-Ligand-arachno-4-azanonaboranes(11), 6-L-4-NB8H11
    1994, Vol. 59, Issue 10, pp. 2244–2252 [Abstract]
  • Tomáš Jelínek, Josef Holub, Bohumil Štíbr, Xavier L. R. Fontaine and John D. Kennedy
    Nine- and Eight-Vertex Polyhedral Dicarbaborane Chemistry: New arachno and hypho Dicarbaboranes from arachno-4,5-C2B7H13: Isolation and Characterization of the [arachno-4,5-C2B7H12]- and [hypho-7,8-C2B6H13]- Anions, and of the Neutral Ligand Derivatives exo-6-(MeNC)-arachno-4,5-C2B7H11 and exo-5-L-hypho-4,9-C2B7H13 (L = NMe3 and NEt3)
    1994, Vol. 59, Issue 7, pp. 1584–1595 [Abstract]
  • Jaromír Plešek, Farzaneh Hosseinpour Rajabi, Veena Vangani and Jiří Fusek
    Constitution and Properties of the 8,8'-μ-(H2NO)=(1,2-C2B9H10)2-3-Co Bridged Cobaltaborane
    1994, Vol. 59, Issue 6, pp. 1326–1336 [Abstract]
  • Jaromír Plešek, Bohumír Grüner, Stanislav Heřmánek, Jiří Fusek and Hana Votavová
    Constitution and HPLC Resolution of Enantiomers of the [8,4'-μ-R2N-commo-(1,2-C2B9H10)2-3-Co] Complexthe Third Isomer of Nitrogen-Bridged Bis
    1994, Vol. 59, Issue 2, pp. 374–380 [Abstract]
  • Jaromír Plešek, Bohumír Grüner, Jiří Fusek and Hana Votavová
    Asymmetric Cobaltacarboranes [6,6'-μ-R-S(1,7-C2B9H10)2-2-Co] with a Monosulfur Bridge between Ligands and HPLC Resolution of the Enantiomers
    1993, Vol. 58, Issue 12, pp. 2936–2943 [Abstract]
  • John D. Kennedy, Bohumil Štíbr, Tomáš Jelínek, Xavier L. R. Fontaine and Mark Thornton-Pett
    Eleven-Vertex Polyhedral Dicarbaplatinaborane Chemistry. Aspects of the Chemistry of Some closo-Structured {1,2,3-PtC2B8} Species and Some Related Compounds
    1993, Vol. 58, Issue 9, pp. 2090–2120 [Abstract]
  • Jaromír Plešek, Bohumír Grüner and Petr Maloň
    Synthesis and Properties of (±)- and (+)-4-MeS-3-C2H5-1,2,3-C2CoB9H10
    1993, Vol. 58, Issue 5, pp. 1087–1092 [Abstract]
  • Bohumil Štíbr, John D. Kennedy, Mark Thornton-Pett, Eva Drdáková, Tomáš Jelínek and Jaromír Plešek
    Polyhedral Iridamonocarbaborane Chemistry. The Isolation and Characterisation of the Nine-Vertex closo-Type Species [(CO)(PPh3)2IrCB7H8] and the Partially Open Structures of Formally closo Nine-Vertex Clusters
    1992, Vol. 57, Issue 7, pp. 1439–1450 [Abstract]
  • Karl Nestor, Bohumil Štíbr, John D. Kennedy, Mark Thornton-Pett and Tomáš Jelínek
    Ten-Vertex Monocarbaborane Chemistry. A Convenient New Preparation of the [closo-1-CB9H10]- Anion and the Crystal and Molecular Structure of [(η5-C5Me5)2Ir2Cl3]+ [closo-1-CB9H10]-
    1992, Vol. 57, Issue 6, pp. 1262–1268 [Abstract]
  • Jaromír Plešek, Bohumil Štíbr, Xavier L. R. Fontaine, John D. Kennedy, Stanislav Heřmánek and Tomáš Jelínek
    Selective dismantling of closo-1,2-C2B10H12 to lower-cage dicarbaborane systems
    1991, Vol. 56, Issue 8, pp. 1618–1635 [Abstract]
  • Bohumil Štíbr, Karel Baše, Tomáš Jelínek, Xavier L. R. Fontaine, John D. Kennedy and Mark Thornton-Pett
    Polyhedral platinadicarbaborane chemistry. The molecular structure and some NMR properties of [9,9-(PPh3)2-arachno-9,5,6-PtC2B7H11]
    1991, Vol. 56, Issue 3, pp. 646–656 [Abstract]
  • Otomar Kříž, Zbyněk Plzák and Jaromír Plešek
    Triethylamine borane - a stable, efficient and safe reductant for transforming carboxylic acids to primary alcohols
    1990, Vol. 55, Issue 12, pp. 2956–2962 [Abstract]
  • Stanislav Heřmánek, Tomáš Jelínek, Jaromír Plešek, Bohumil Štíbr and Jiří Fusek
    Revision of nido-2,6-C2B7H11 to the arachno-4,5-C2B7H13 structure. Determination of the structure from NMR spectra and chemical origin
    1988, Vol. 53, Issue 11, pp. 2742–2752 [Abstract]
  • Bohumil Štíbr, Jaromír Plešek, Tomáš Jelínek, Stanislav Heřmánek, Konstantin A. Solntsev and Nicolai T. Kuznetsov
    Symmetrical isomers of arachno-5,5'-X-(6,9-C2B8H13)2 (X = O and OSO2O) compounds
    1987, Vol. 52, Issue 4, pp. 957–959 [Abstract]
  • Bohumil Štíbr, Zbyněk Janoušek, Jaromír Plešek, Tomáš Jelínek and Stanislav Heřmánek
    Arachno-6,9-C2B8H14 dicarbaborane and its 1- and 5-monohalogenated derivatives
    1987, Vol. 52, Issue 1, pp. 103–112 [Abstract]
  • Tomáš Jelínek, Jaromír Plešek, Stanislav Heřmánek and Bohumil Štíbr
    Chemistry of compounds with the 1-carba-closo-dodecaborane(12) framework
    1986, Vol. 51, Issue 4, pp. 819–829 [Abstract]
  • Jaromír Plešek, Tomáš Jelínek, Stanislav Heřmánek and Bohumil Štíbr
    Synthesis and reactions of 1,2-dicarba-closo-dodecarborane-1-yl tetrahydroborate(1-)
    1986, Vol. 51, Issue 1, pp. 81–89 [Abstract]
  • Tomáš Jelínek, Jaromír Plešek, Stanislav Heřmánek and Bohumil Štíbr
    Preparation of 7-substituted 7-carba-nido-undecaboranes(12)
    1985, Vol. 50, Issue 6, pp. 1376–1382 [Abstract]
  • Jaromír Plešek, Karel Baše, František Mareš, František Hanousek, Bohumil Štíbr and Stanislav Heřmánek
    Potential uses of metallocarborane sandwich anions for analysis, characterization and isolation of various cations and organic bases
    1984, Vol. 49, Issue 12, pp. 2776–2789 [Abstract]
  • Bohumil Štíbr, Zbyněk Janoušek, Karel Baše, Stanislav Heřmánek, Jaromír Plešek and Inessa A. Zakharova
    Synthesis and structure of μ-6,9-metalla-bis(ligand)-6,9-dicarba-nido-decarboranes(10) from the [6,9-C2B8H10]2- anion
    1984, Vol. 49, Issue 8, pp. 1891–1894 [Abstract]
  • Bohumil Štíbr, Zbyněk Janoušek, Karel Baše, Jaromír Plešek, Konstantin A. Solntsev, Lev A. Butman, Igor I. Kuznetsov and Nikolai T. Kuznetsov
    Synthesis of ten-vertex closo-metallacarbaboranes from 4-CB8H14
    1984, Vol. 49, Issue 7, pp. 1660–1664 [Abstract]
  • Jaromír Plešek, Tomáš Jelínek, Eva Drdáková, Stanislav Heřmánek and Bohumil Štíbr
    A convenient preparation of 1-CB11H12- and its C-amino derivatives
    1984, Vol. 49, Issue 7, pp. 1559–1562 [Abstract]
  • Jaromír Plešek, Bohumil Štíbr and Stanislav Heřmánek
    A [8,8'-μ-I-3-Co(1,2-C2B9H10)2] metallacarborane complex with a iodonium bridge. Evidence for a bromonium analogue
    1984, Vol. 49, Issue 6, pp. 1492–1496 [Abstract]
  • Zbyněk Janoušek, Jaromír Plešek, Bohumil Štíbr and Stanislav Heřmánek
    Synthesis and structure of iso-C4B18H22
    1983, Vol. 48, Issue 1, pp. 228–231 [Abstract]
  • Otomar Kříž, František Mareš and Bohuslav Čásenský
    Preparation and 1H NMR study of soluble alkoxy, alkyl and arylamido derivatives of sodium tetraamidoaluminate
    1982, Vol. 47, Issue 2, pp. 384–391 [Abstract]
  • Zbyněk Janoušek, Jaromír Plešek, Stanislav Heřmánek, Karel Baše, Lee J. Todd and W. F. Wright
    Synthesis and characteristics of sulfur interligand bridge-derivatives and of some S-substituted compounds in the (C2B9H11)2Co- series. Conformations of (C2B9H11)2Mx- metallocarboranes
    1981, Vol. 46, Issue 11, pp. 2818–2833 [Abstract]
  • Jiří Dolanský, Stanislav Heřmánek and Rudolf Zahradník
    Electronic structure and 11B-NMR spectra of nine-vertex heteroboranes: 4-CB8H14, 4-NB8H13, 4-SB8H12 and 4,6-C2B7H13
    1981, Vol. 46, Issue 10, pp. 2479–2493 [Abstract]
  • Jaromír Plešek, Zbyněk Plzák, Jiří Stuchlík and Stanislav Heřmánek
    Synthesis of B-alkyl derivatives of o-carborane by alkylation under electrophilic conditions; Scope and limitation
    1981, Vol. 46, Issue 8, pp. 1748–1763 [Abstract]
  • Jaromír Plešek and Stanislav Heřmánek
    Syntheses and properties of substituted icosahedral carborane thiols
    1981, Vol. 46, Issue 3, pp. 687–692 [Abstract]
  • Jaromír Plešek, Zbyněk Janoušek and Stanislav Heřmánek
    Synthesis and properties of some icosahedral carborane B,B'-dithiols
    1980, Vol. 45, Issue 6, pp. 1775–1779 [Abstract]
  • Jaromír Plešek and Stanislav Heřmánek
    Synthesis and properties of 1-HSCH2-1,2-C2B10H11
    1979, Vol. 44, Issue 9, pp. 2769–2771 [Abstract]
  • Jaromír Plešek and Stanislav Heřmánek
    Experimental evaluation of charge distribution on particular skeletal atoms in icosahedral carboranes by means of HS-derivatives
    1979, Vol. 44, Issue 1, pp. 24–33 [Abstract]
  • Jaromír Plešek, Zbyněk Janoušek and Stanislav Heřmánek
    Four new (CH3)2S·C2B9H11 isomers
    1978, Vol. 43, Issue 11, pp. 2862–2868 [Abstract]
  • Jaromír Plešek, Zbyněk Janoušek and Stanislav Heřmánek
    Chemistry of 9-mercapto-1,7-dicarba-closo-dodecaborane
    1978, Vol. 43, Issue 5, pp. 1332–1338 [Abstract]
  • Jaromír Plešek and Stanislav Heřmánek
    Introduction of an HS-group into electron donor positions in icosahedral heteroboranes. A new method for the preparation of metallocarborane sandwich compounds with o-phenylene bridges
    1978, Vol. 43, Issue 5, pp. 1325–1331 [Abstract]