Collect. Czech. Chem. Commun. 1986, 51, 493-497

Contribution to the study of the kinetics of redox reactions proceeding via electrode processes: Reactions with two-electron transfer

Jaroslav Macenauer

Department of Physical Chemistry, University of Chemical Technology, 532 10 Pardubice


The author studied the kinetics of redox reactions of the type n2Ox1 + n1Red2n1Ox2 + n2Red1 proceeding via electrodes, for the case of two-electron redox systems. The dependence of the reaction time on experimental parameters (resistance, concentration, and volume of reactants) was studied on two model reactions, and the theory was verified.