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Collect. Czech. Chem. Commun. 1982, 47, 1444-1464
https://doi.org/10.1135/cccc19821444

Extraction of strontium and barium by nitrobenzene solution of dicarbolide in the presence of polyethylene glycols

Petr Vaňura, Emanuel Makrlík, Jiří Rais and Miroslav Kyrš

Nuclear Research Institute, 250 68 Řež

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  • Makrlík Emanuel, Vaňura Petr, Selucký Pavel, Brusko Vasiliy: 3,3′-Bis(diisopropoxyphosphoryl)-1,1′-(heptane-1,7-diyl)diurea as a Very Efficient Extraction Agent for Europium and Americium. J Solution Chem 2018, 47, 715. <https://doi.org/10.1007/s10953-018-0748-6>
  • Makrlík Emanuel, Vaňura Petr, Selucký Pavel, Babain Vasily, Alyapyshev Mikhail, Dar’in Dmitriy: Highly Efficient Solvent Extraction of Americium and Europium by Using Hydrogen Dicarbollylcobaltate and N,N′-Diethyl-N,N′-bis(4-ethylphenyl)-1,10-phenanthroline-2,9-dicarboxamide. J Solution Chem 2017, 46, 1475. <https://doi.org/10.1007/s10953-017-0651-6>
  • Makrlík Emanuel, Vaňura Petr, Selucký Pavel, Babain Vasily, Alyapyshev Mikhail, Dar'in Dmitriy: N , N ′-diethyl- N , N ′-diphenyl-1,10-phenanthroline-2,9-dicarboxamide as an extraordinarily effective extraction agent for trivalent europium and americium. Journal of Molecular Liquids 2017, 237, 490. <https://doi.org/10.1016/j.molliq.2017.04.032>
  • Makrlík Emanuel, Kvíčalová Magdalena, Vaňura Petr: Sodium Ionophore III as Very Effective Receptor for Trivalent Europium and Americium. J Solution Chem 2016, 45, 463. <https://doi.org/10.1007/s10953-016-0447-0>
  • Makrlík Emanuel, Vaňura Petr, Selucký Pavel: Solvent Extraction of Europium and Americium into Nitrobenzene by Using Hydrogen Dicarbollylcobaltate in the Presence of 3,3′-Bis(diphenoxyphosphoryl)-1,1′-(heptane-1,7-diyl)diurea. J Solution Chem 2016, 45, 1773. <https://doi.org/10.1007/s10953-016-0541-3>
  • Makrlík Emanuel, Vaňura Petr, Spíchal Zdeněk: Solvent extraction of trivalent europium and americium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and bis(diphenylphosphino)acetylene dioxide. Journal of Molecular Liquids 2016, 221, 574. <https://doi.org/10.1016/j.molliq.2016.05.028>
  • Makrlík E., Vaňura P., Selucký P.: Magnesium ionophore III as an effective receptor for trivalent europium and americium. J Radioanal Nucl Chem 2014, 302, 393. <https://doi.org/10.1007/s10967-014-3263-2>
  • Makrlík E., Spíchal Z., Vaňura P., Selucký P.: Synergistic extraction of europium and americium into nitrobenzene by using hydrogen dicarbollylcobaltate and bis(diphenylphosphino)methane dioxide. J Radioanal Nucl Chem 2013, 295, 2135. <https://doi.org/10.1007/s10967-012-2227-7>
  • Makrlík E., Vaňura P., Selucký P.: Synergistic extraction of calcium and strontium into nitrobenzene by using hydrogen dicarbollylcobaltate and dodecaethylene glycol. J Radioanal Nucl Chem 2013, 295, 2215. <https://doi.org/10.1007/s10967-012-2273-1>
  • Makrlík E., Vaňura P., Selucký P.: Synergistic extraction of sodium into nitrobenzene by using hydrogen dicarbollylcobaltate and dodecaethylene glycol. J Radioanal Nucl Chem 2013, 297, 115. <https://doi.org/10.1007/s10967-012-2317-6>
  • Makrlík E., Vaňura P., Spíchal Z., Selucký P.: Synergistic extraction of europium and americium into nitrobenzene by using hydrogen dicarbollylcobaltate and 1,3-bis(diphenylphosphino)propane dioxide. J Radioanal Nucl Chem 2013, 298, 243. <https://doi.org/10.1007/s10967-013-2517-8>
  • Paulenova A., Alyapyshev M. Yu, Babain V. A., Herbst R. S., Law J. D.: Extraction of Lanthanoids with Diamides of Dipcolinic Acid from Nitric Acid Solutions. II. Synergistic Effect of Ethyl-Tolyl Derivates and Dicarbollide Cobalt. Solvent Extraction and Ion Exchange 2013, 31, 184. <https://doi.org/10.1080/07366299.2012.735528>
  • Makrlík E., Vaňura P.: Synergistic extraction of some divalent cations into nitrobenzene by using strontium dicarbollylcobaltate and hexaethyl p- tert-butylcalix[6]arene hexaacetate. J Radioanal Nucl Chem 2012, 293, 931. <https://doi.org/10.1007/s10967-012-1783-1>
  • Makrlík E., Vaňura P., Selucký P.: Extraction of cesium into nitrobenzene by using ammonium and thallium dicarbollylcobaltates in the presence of polypropylene glycol PPG 425. J Radioanal Nucl Chem 2012. <https://doi.org/10.1007/s10967-012-2300-2>
  • Makrlík E., Toman P., Vaňura P., Kašička V., Rathore R.: A Combined Experimental and Theoretical Study on the Complexation of Ag+ with a Hexaarylbenzene-Based Receptor. J Solution Chem 2011, 40, 1418. <https://doi.org/10.1007/s10953-011-9727-x>
  • Makrlík E., Vaňura P., Selucký P.: Solvent extraction of calcium and strontium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of polypropylene glycol PPG 425. J Radioanal Nucl Chem 2011, 287, 151. <https://doi.org/10.1007/s10967-010-0660-z>
  • Makrlík E., Vaňura P., Selucký P.: Extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and tetraisopropyl methylene diphosphonate. J Radioanal Nucl Chem 2011, 287, 217. <https://doi.org/10.1007/s10967-010-0668-4>
  • Makrlík E., Vaňura P., Selucký P., Smirnov I. V., Babain V. A.: Solvent extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and diphenyl-N,N-dibutylcarbamoylmethyl phosphine oxide. J Radioanal Nucl Chem 2011, 287, 335. <https://doi.org/10.1007/s10967-010-0680-8>
  • Makrlík E., Vaňura P., Selucký P.: Solvent extraction of calcium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of dibenzo-30-crown-10. J Radioanal Nucl Chem 2011, 287, 411. <https://doi.org/10.1007/s10967-010-0695-1>
  • Makrlík E., Vaňura P., Selucký P.: Solvent extraction of some divalent metal cations into nitrobenzene by using a synergistic mixture of strontium dicarbollylcobaltate and hexaethyl calix[6]arene hexaacetate. J Radioanal Nucl Chem 2011, 287, 899. <https://doi.org/10.1007/s10967-010-0850-8>
  • Makrlík E., Vaňura P., Selucký P.: Solvent extraction of cesium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and polypropylene glycol PPG 425. J Radioanal Nucl Chem 2011, 287, 981. <https://doi.org/10.1007/s10967-010-0855-3>
  • Makrlík E., Vaňura P.: Solvent extraction of some divalent metal cations into nitrobenzene by using a synergistic mixture of strontium dicarbollylcobaltate and nonactin. J Radioanal Nucl Chem 2011, 288, 49. <https://doi.org/10.1007/s10967-010-0869-x>
  • Makrlík E., Vaňura P., Selucký P., Babain V. A., Smirnov I. V.: Solvent extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and N,N,N′,N′-tetraisobutyl-2,6-dipicolinamide. J Radioanal Nucl Chem 2011, 288, 233. <https://doi.org/10.1007/s10967-010-0902-0>
  • Makrlík E., Vaňura P., Selucký P.: Solvent extraction of cesium into nitrobenzene by using sodium, potassium and rubidium dicarbollylcobaltates in the presence of polypropylene glycol PPG 425. J Radioanal Nucl Chem 2011, 288, 429. <https://doi.org/10.1007/s10967-010-0940-7>
  • Makrlík E., Vaňura P., Selucký P., Spíchal Z.: Synergistic extraction of europium and americium into nitrobenzene by using hydrogen dicarbollylcobaltate and 1,2-(diphenylphosphino)ethane dioxide. J Radioanal Nucl Chem 2011, 289, 13. <https://doi.org/10.1007/s10967-011-1046-6>
  • Makrlík E., Vaňura P., Selucký P.: Solvent extraction of cesium into nitrobenzene by using hydrogen dicarbollylcobaltate and dodecaethylene glycol. J  Radioanal Nucl Chem 2011, 290, 307. <https://doi.org/10.1007/s10967-011-1230-8>
  • Dybal Jiří, Makrlík Emanuel, Vaňura Petr: Extraction and DFT study on the complexation of Mg2+ with valinomycin. Monatsh Chem 2010, 141, 15. <https://doi.org/10.1007/s00706-009-0217-4>
  • Makrlík E., Vaňura P., Selucký P.: Solvent Extraction of Calcium and Strontium into Nitrobenzene by Using Hydrogen Dicarbollylcobaltate in the Presence of Dibutyl Diethylcarbamoylmethylene Phosphonate. J Solution Chem 2010, 39, 692. <https://doi.org/10.1007/s10953-010-9525-x>
  • Makrlík E., Vaňura P., Selucký P.: Solvent extraction of microamounts of europium and americium into nitrobenzene by using synergistic mixture of hydrogen dicarbollylcobaltate and 1,2-(diphenylphosphino)ethylene dioxide. J Radioanal Nucl Chem 2010, 283, 45. <https://doi.org/10.1007/s10967-009-0048-0>
  • Makrlík E., Vaňura P., Selucký P., Kašička V.: Extraction of microamounts of calcium and strontium into nitrobenzene using synergistic mixture of hydrogen dicarbollylcobaltate and 2,3-naphtho-15-crown-5. J Radioanal Nucl Chem 2010, 283, 95. <https://doi.org/10.1007/s10967-009-0127-2>
  • Makrlík E., Vaňura P., Sedláková Z.: Extraction of europium and cerium into nitrobenzene using synergistic mixture of hydrogen dicarbollylcobaltate and polyethylene glycol PEG 600. J Radioanal Nucl Chem 2010, 283, 157. <https://doi.org/10.1007/s10967-009-0134-3>
  • Makrlík E., Vaňura P.: Extraction of strontium and barium into nitrobenzene by using synergistic mixture of hydrogen dicarbollylcobaltate and polyethylene glycol PEG 1000. J Radioanal Nucl Chem 2010, 283, 497. <https://doi.org/10.1007/s10967-009-0354-6>
  • Makrlík E., Vaňura P., Selucký P.: Solvent extraction of strontium and barium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of dicyclohexano-24-crown-8. J Radioanal Nucl Chem 2010, 283, 615. <https://doi.org/10.1007/s10967-009-0394-y>
  • Makrlík E., Vaňura P., Selucký P.: Extraction of europium and americium into nitrobenzene by using synergistic mixture of hydrogen dicarbollylcobaltate and tetraisopropyl methylene diphosphonate. J Radioanal Nucl Chem 2010, 283, 727. <https://doi.org/10.1007/s10967-009-0404-0>
  • Makrlík E., Vaňura P.: Extraction of europium and cerium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of polyethylene glycol PEG 1000. J Radioanal Nucl Chem 2010, 283, 773. <https://doi.org/10.1007/s10967-009-0411-1>
  • Makrlík E., Vaňura P., Selucký P.: Solvent extraction of calcium and strontium into nitrobenzene by using synergistic mixture of hydrogen dicarbollylcobaltate and diphenyl-N-butylcarbamoylmethyl phosphine oxide. J Radioanal Nucl Chem 2010, 284, 87. <https://doi.org/10.1007/s10967-009-0433-8>
  • Makrlík E., Vaňura P., Selucký P.: Solvent extraction of strontium and barium into nitrobenzene by using synergistic mixture of hydrogen dicarbollylcobaltate and dibenzo-24-crown-8. J Radioanal Nucl Chem 2010, 284, 137. <https://doi.org/10.1007/s10967-010-0451-6>
  • Makrlík E., Vaňura P., Selucký P.: Extraction of calcium and strontium into phenyltrifluoromethyl sulfone by using hydrogen dicarbollylcobaltate in the presence of polyethylene glycol PEG 400. J Radioanal Nucl Chem 2010, 284, 207. <https://doi.org/10.1007/s10967-010-0473-0>
  • Makrlík E., Vaňura P., Selucký P.: Extraction of calcium and strontium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of 1,2-(diphenylphosphino)ethylene dioxide. J Radioanal Nucl Chem 2010, 285, 383. <https://doi.org/10.1007/s10967-010-0542-4>
  • Makrlík E., Vaňura P., Selucký P.: Solvent extraction of calcium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of dicyclohexano-18-crown-6 and dicyclohexano-24-crown-8. J Radioanal Nucl Chem 2010, 285, 593. <https://doi.org/10.1007/s10967-010-0570-0>
  • Makrlík E., Vaňura P.: Individual extraction constants of some divalent metal cations in the two-phase water–nitrobenzene system. J Radioanal Nucl Chem 2010, 285, 683. <https://doi.org/10.1007/s10967-010-0598-1>
  • Makrlík E., Vaňura P., Selucký P.: Extraction of cesium into phenyltrifluoromethyl sulfone by using hydrogen dicarbollylcobaltate in the presence of polyethylene glycol PEG 400. J Radioanal Nucl Chem 2010, 286, 295. <https://doi.org/10.1007/s10967-010-0655-9>
  • Zalupski P. R., Herbst R. S., Delmau L. H., Martin L. R., Peterman D. R., Nash K. L.: Two-Phase Calorimetry. II. Studies on the Thermodynamics of Cesium and Strontium Extraction by Mixtures of H+CCD−and PEG-400 in FS-13. Solvent Extraction and Ion Exchange 2010, 28, 161. <https://doi.org/10.1080/07366290903408482>
  • Makrlík Emanuel, Budka J., Vaňura P., Selucký P.: Stability constants of some metal cation complexes of tetraphenyl p-tert-butylcalix[4]arene tetraketone in nitrobenzene saturated with water. Monatsh Chem 2009, 140, 157. <https://doi.org/10.1007/s00706-008-0070-x>
  • Makrlík E., Vaňura P., Selucký P.: Stability Constants of Some Univalent Cation Complexes of 2,3-Naphtho-15-crown-5 in Nitrobenzene Saturated with Water. J Solution Chem 2009, 38, 1129. <https://doi.org/10.1007/s10953-009-9434-z>
  • Makrlík E., Vaňura P., Selucký P.: Extraction of microamounts of europium and americium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of diphenyl-N-butylcarbamoylmethyl phosphine oxide. J Radioanal Nucl Chem 2009, 279, 137. <https://doi.org/10.1007/s10967-007-7203-2>
  • Makrlík E., Vaňura P., Selucký P.: Extraction of microamounts of europium and americium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of N,N′-dibutyl-N,N′-dimethyl-2-(2-dodecyloxyethyl)-malonamide. J Radioanal Nucl Chem 2009, 279, 287. <https://doi.org/10.1007/s10967-007-7288-2>
  • Dybal J., Makrlík E., Vaňura P.: Extraction and ab initio calculation studies on the complexation of Ca2+ with valinomycin. J Radioanal Nucl Chem 2009, 279, 553. <https://doi.org/10.1007/s10967-008-7344-y>
  • Makrlík E., Vaňura P., Selucký P., Babain V. A., Smirnov I. V.: Extractive distribution of microamounts of europium and americium in the two phase water — HCl — nitrobenzene — N,N,N′,N′-tetraethyl-2,6-dipicolinamide — hydrogen dicarbollylcobaltate system. J Radioanal Nucl Chem 2009, 279, 743. <https://doi.org/10.1007/s10967-008-7375-4>
  • Makrlík E., Vaňura P., Selucký P.: Solvent extraction of microamounts of cesium into nitrobenzene using ammonium and thallium dicarbollylcobaltates in the presence of 2,3-naphtho-15-crown-5. J Radioanal Nucl Chem 2009, 281, 547. <https://doi.org/10.1007/s10967-009-0020-z>
  • Makrlík E., Vaňura P., Selucký P.: Solvent extraction of microamounts of strontium and barium into nitrobenzene by using synergistic mixture of hydrogen dicarbollylcobaltate and dicyclohexano-18-crown-6. J Radioanal Nucl Chem 2009, 281, 633. <https://doi.org/10.1007/s10967-009-0053-3>
  • Makrlík E., Vaňura P., Sedláková Z.: Solvent extraction of microamounts of strontium and barium into nitrobenzene using hydrogen dicarbollylcobaltate in the presence of polyethylene glycol PEG 600. J Radioanal Nucl Chem 2009, 280, 607. <https://doi.org/10.1007/s10967-009-7484-8>
  • Makrlik E., Vaňura P., Selucký P., Babain V. A., Alyapyshev M. Yu.: Extraction of microamounts of Eu and Am into nitrobenzene using a synergistic mixture of chlorinated hydrogen dicarbollylcobaltate and N,N′-diethyl-N,N′-diphenyl-2,6-dipicolinamide. Radiochemistry 2009, 51, 479. <https://doi.org/10.1134/S1066362209050075>
  • Makrlík E., Vanura P., Selucky P.: Extraction of Microamounts of Calcium and Strontium into Nitrobenzene by Using Hydrogen Dicarbollylcobaltate in the Presence of “Classical” CMPO. Zeitschrift für Physikalische Chemie 2009, 223, 253. <https://doi.org/10.1524/zpch.2009.5360>
  • Dybal J., Makrlík E., Vanura P.: Experimental and DFT Study on the Complexation of Zn2+with Valinomycin. Zeitschrift für Physikalische Chemie 2009, 223, 869. <https://doi.org/10.1524/zpch.2009.5465>
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  • Makrlík E., Vaňura P., Selucký P.: Extraction distributions of microamounts of strontium and barium in the two-phase water-HCl-nitrobenzene-dibenzo-21-crown-7-hydrogen dicarbollylcobaltate system. J Radioanal Nucl Chem 2008, 275, 3. <https://doi.org/10.1007/s10967-006-6975-0>
  • Makrlík E., Vaňura P., Selucký P.: Solvent extraction of microamounts of cesium into nitrobenzene by using potassium and rubidium dicarbollylcobaltates in the presence of benzo-15-crown-5. J Radioanal Nucl Chem 2008, 275, 229. <https://doi.org/10.1007/s10967-007-7005-6>
  • Makrlík E., Vaňura P., Selucký P.: Extraction of microamounts of calcium into nitrobenzene using hydrogen dicarbollylcobaltate in the presence of dibenzo-21-crown-7 and dibenzo-24-crown-8. J Radioanal Nucl Chem 2008, 275, 285. <https://doi.org/10.1007/s10967-007-7040-3>
  • Makrlík E., Vaňura P., Selucký P.: Extraction of microamounts of europium and americium by using hydrogen dicarbollylcobaltate in the presence of dibutyl diethylcarbamoylmethylene phosphonate. J Radioanal Nucl Chem 2008, 275, 309. <https://doi.org/10.1007/s10967-007-7058-6>
  • Makrlík E., Budka J., Vaňura P., Selucký P.: Extraction of Ba2+, Pb2+ and Cd2+ into nitrobenzene by using strontium dicarbollylcobaltate in the presence of tetramethyl p-tert-butylcalix[4]arene tetraketone. J Radioanal Nucl Chem 2008, 277, 487. <https://doi.org/10.1007/s10967-007-7110-6>
  • Makrlík E., Vaňura P., Selucký P.: Extraction of microamounts of calcium, strontium and barium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of dibenzo-18-crown-6. J Radioanal Nucl Chem 2008, 277, 549. <https://doi.org/10.1007/s10967-007-7115-1>
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  • Makrlík E., Vaňura P., Selucký P.: Extraction Distribution of Microamounts of Strontium in the Two-Phase Water–RbCl–15-Crown–5-Nitrobenzene–Rubidium Dicarbollylcobaltate System. Zeitschrift für Physikalische Chemie 2007, 221, 949. <https://doi.org/10.1524/zpch.2007.221.7.949>
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