Collect. Czech. Chem. Commun. 1981, 46, 2818-2833

Synthesis and characteristics of sulfur interligand bridge-derivatives and of some S-substituted compounds in the (C2B9H11)2Co- series. Conformations of (C2B9H11)2Mx- metallocarboranes

Zbyněk Janoušeka, Jaromír Plešeka, Stanislav Heřmáneka, Karel Bašea, Lee J. Toddb and W. F. Wrightb

a Institute of Inorganic Chemistry, Czechoslovak Academy of Sciences, 250 68 Řež
b Indiana University, Bloomington, Indiana 474 01, U.S.A.

Individual author index pages

Other CCCC articles of these authors

  • Ivan Šnajdr, Zbyněk Janoušek and Martin Kotora
    Synthesis of novel C-(o-carboranyl)-2-deoxy-D-ribose conjugates
    Symposium Series 2011, Vol. 12, pp. 465–466 [Abstract]
    Published online 2015-08-20 10:24:38
  • Radim Dostál*, Michael G. S. Londesborough*, Magdalena Kvíčalová, Jan Macháček, Ivana Císařová and Zbyněk Janoušek
    Incremental iodination of the eight-vertex closo monocarborane anion [closo-1-CB7H8]: Preparation and characterization of [closo-1-CB7H5-6,7,8-I3] and [closo-1-CB7H2-2,3,4,6,7,8-I6], and the synthesis of the first eight-vertex C-methylated carborane anion [1-CH3-closo-1-CB7H4-6,7,8-I3]
    2010, Vol. 75, Issue 9, pp. 931–947 [Abstract]
  • Bryan Ringstrand*, Devon Bateman, Richard K. Shoemaker and Zbyněk Janoušek*
    Improved synthesis of [closo-1-CB9H10] anion and new C-substituted derivatives
    2009, Vol. 74, Issue 3, pp. 419–431 [Abstract]
  • Martin Lepšík, Martin Srnec, Drahomír Hnyk, Bohumír Grüner, Jaromír Plešek, Zdeněk Havlas and Lubomír Rulíšek*
    exo-Substituent effects in halogenated icosahedral (B12H122–) and octahedral (B6H62–) closo-borane skeletons: chemical reactivity studied by experimental and quantum chemical methods
    2009, Vol. 74, Issue 1, pp. 1–27 [Abstract]
  • Zbyněk Janoušek, Cameron L. Hilton, Peter J. Schreiber and Josef Michl*
    C-Halogenation of the closo-[CB11H12]- Anion
    2002, Vol. 67, Issue 7, pp. 1025–1034 [Abstract]
  • Josef Holub, Tomáš Jelínek and Zbyněk Janoušek*
    New Multigram-Scale Preparation of 1,10-Dicarba-closo-decaborane
    2002, Vol. 67, Issue 7, pp. 949–952 [Abstract]
  • Jaromír Plešek*, Ivana Císařová and Jaroslav Bačkovský
    Cobalt Bis(1,2-dicarbollide) Ion with a Disulfur Bridge Between B(8) and B(8'). X-Ray Structure, Absolute Configuration of One Enantiomer, and Implications
    2002, Vol. 67, Issue 5, pp. 569–576 [Abstract]
  • Jaromír Plešek*, Jaroslav Bačkovský, Jiří Fusek and Zbyněk Plzák
    Cyanoethylation and (Methoxycarbonyl)ethylation of Icosahedral ortho-Carborane Derivatives at Carbon Vertices via Michael Additions
    2001, Vol. 66, Issue 10, pp. 1499–1507 [Abstract]
  • Zbyněk Janoušek*, Piotr Kaszynski, John D. Kennedy and Bohumil Štíbr
    NMR Assignments of [6-R-nido-5,6-C2B8H10]- Anions (where R = H, Me, and n-C6H13). An Irreversible 5 → 6 Alkyl Migration via a B9 Vertex-Swing Mechanism
    1999, Vol. 64, Issue 6, pp. 986–992 [Abstract]
  • Bohumil Štíbr*, Zbyněk Janoušek, Matthew Trammell, Bohumír Grüner and Zbyněk Plzák
    Oxidation of the [nido-6,9-C2B8H10]2- Anion - An Alternative Source of the 1,6- and 1,10-Dicarba-closo-decaboranes(10)
    1999, Vol. 64, Issue 6, pp. 971–976 [Abstract]
  • Andreas Franken, Jaromír Plešek, Jiří Fusek and Markus Semrau
    Cobaltacarboranes with Intramolecular Monophosphorus Bridges 8,8'-μ-Me2P(1,2-C2B9H10)2-3-Co, 6,6'-μ-Me2P(1,7-C2B9H10)2-2-Co and the Respective Non-Bridged Trimethylphosphine Derivatives (8-Me3P-1,2-C2B9H10)-3-Co-(1,2-C2B9H11) and (6-Me3P-1,7-C2B9H10)-2-Co-(1,7-C2B9H11)
    1997, Vol. 62, Issue 7, pp. 1070–1079 [Abstract]
  • Jaromír Plešek, Bohumír Grüner and Josef Holub
    Synthesis and Properties of Cobaltacarboranes with Substituted Monoatomic Bridges Between Ligands of the 6,6'-μ-RnE(1,7-C2B9H10)2-2-Co Type
    1997, Vol. 62, Issue 6, pp. 884–893 [Abstract]
  • Andreas Franken, Jaromír Plešek and Christiane Nachtigal
    Unusual Rearrangement of Naphthalene in the Synthesis of a Novel B8-B8-Bridged Derivative in the [(1,2-C2B9H11)2-3-Co]- Series. X-Ray Structure and 11B NMR Spectra of [8,8'-μ-(CH2-C9H6)-(1,2-C2B9H10)2-3-Co]- (CH3)4N+
    1997, Vol. 62, Issue 5, pp. 746–751 [Abstract]
  • Jaromír Plešek, Andreas Franken and Roland Fröhlich
    The Structure of [6,6'-μ-S(1,7-C2B9H10)2-2-Co]-[PPh4]+
    1997, Vol. 62, Issue 1, pp. 57–61 [Abstract]
  • Jaromír Plešek, Stanislav Heřmánek, Andreas Franken, Ivana Císařová and Christiane Nachtigal
    Dimethyl Sulfate Induced Nucleophilic Substitution of the [Bis(1,2-dicarbollido)-3-cobalt(1-)]ate Ion. Syntheses, Properties and Structures of Its 8,8'-μ-Sulfato, 8-Phenyland 8-Dioxane Derivatives
    1997, Vol. 62, Issue 1, pp. 47–56 [Abstract]
  • Jiří Vohlídal, Jaromír Plešek, Jan Sedláček, Ivana Císařová, Pavel Matějka and Stanislav Heřmánek
    Cobaltacarboranylacetylene 8,8'-(μ-CHC-CH2S)-(1,2-C2B9H10)2-3-Co(III): Synthesis, Characterization and Polymerization of New Substituted Acetylene
    1996, Vol. 61, Issue 6, pp. 877–887 [Abstract]
  • Jaromír Plešek and Stanislav Heřmánek
    The (η-1,7'-2,2')4,8'-8,4'-(Bis-μ-o-phenylene)bisdicarbollidocobalt(1-)ate Ion [3-Co-4,8'-8,4'(o-C6H4)2(1,2-C2B9H9)2](-). The First Doubly Bridged Metallacarborane Complex. Synthesis, Properties and Structure
    1995, Vol. 60, Issue 8, pp. 1297–1302 [Abstract]
  • Jaromír Plešek, Farzaneh Hosseinpour Rajabi, Veena Vangani and Jiří Fusek
    Constitution and Properties of the 8,8'-μ-(H2NO)=(1,2-C2B9H10)2-3-Co Bridged Cobaltaborane
    1994, Vol. 59, Issue 6, pp. 1326–1336 [Abstract]
  • Jaromír Plešek, Bohumír Grüner, Stanislav Heřmánek, Jiří Fusek and Hana Votavová
    Constitution and HPLC Resolution of Enantiomers of the [8,4'-μ-R2N-commo-(1,2-C2B9H10)2-3-Co] Complexthe Third Isomer of Nitrogen-Bridged Bis
    1994, Vol. 59, Issue 2, pp. 374–380 [Abstract]
  • Jaromír Plešek, Bohumír Grüner, Jiří Fusek and Hana Votavová
    Asymmetric Cobaltacarboranes [6,6'-μ-R-S(1,7-C2B9H10)2-2-Co] with a Monosulfur Bridge between Ligands and HPLC Resolution of the Enantiomers
    1993, Vol. 58, Issue 12, pp. 2936–2943 [Abstract]
  • Jaromír Plešek, Tomáš Jelínek, František Mareš and Stanislav Heřmánek
    Unique Dialkylsulfonio-Methylation of the 7,8-C2B9H12(-) Ion to the 9-R2S-CH2-7,8-C2B9H11 Zwitterions by Formaldehyde and Dialkyl Sulfides. General Synthesis of the Compounds 10-R2E-7,8-C2B9H11 (E = O, S)
    1993, Vol. 58, Issue 7, pp. 1534–1547 [Abstract]
  • Jaromír Plešek, Bohumír Grüner and Petr Maloň
    Synthesis and Properties of (±)- and (+)-4-MeS-3-C2H5-1,2,3-C2CoB9H10
    1993, Vol. 58, Issue 5, pp. 1087–1092 [Abstract]
  • Bohumil Štíbr, John D. Kennedy, Mark Thornton-Pett, Eva Drdáková, Tomáš Jelínek and Jaromír Plešek
    Polyhedral Iridamonocarbaborane Chemistry. The Isolation and Characterisation of the Nine-Vertex closo-Type Species [(CO)(PPh3)2IrCB7H8] and the Partially Open Structures of Formally closo Nine-Vertex Clusters
    1992, Vol. 57, Issue 7, pp. 1439–1450 [Abstract]
  • František Adámek, Milan Hájek and Zbyněk Janoušek
    Relative Reactivities of 1,1,1-Trichloroethane and 1,1,1-Trichlorotrifluoroethane in Competitive Addition Reactions
    1992, Vol. 57, Issue 6, pp. 1291–1298 [Abstract]
  • Jaromír Plešek, Bohumil Štíbr, Xavier L. R. Fontaine, John D. Kennedy, Stanislav Heřmánek and Tomáš Jelínek
    Selective dismantling of closo-1,2-C2B10H12 to lower-cage dicarbaborane systems
    1991, Vol. 56, Issue 8, pp. 1618–1635 [Abstract]
  • Karl Nestor, Xavier L. R. Fontaine, John D. Kennedy, Bohumil Štíbr, Karel Baše and Mark Thornton-Pett
    Polyhedral organoiridaazaborane chemistry. The preparation of the eleven-vertex nido compound [9-Cl-8-(η5-C5Me5)-nido-8,7-IrNHB9H10] and its characterization by single-crystal X-ray diffraction analysis and nuclear magnetic resonance spectroscopy
    1991, Vol. 56, Issue 8, pp. 1607–1617 [Abstract]
  • Bohumil Štíbr, Karel Baše, Tomáš Jelínek, Xavier L. R. Fontaine, John D. Kennedy and Mark Thornton-Pett
    Polyhedral platinadicarbaborane chemistry. The molecular structure and some NMR properties of [9,9-(PPh3)2-arachno-9,5,6-PtC2B7H11]
    1991, Vol. 56, Issue 3, pp. 646–656 [Abstract]
  • Otomar Kříž, Zbyněk Plzák and Jaromír Plešek
    Triethylamine borane - a stable, efficient and safe reductant for transforming carboxylic acids to primary alcohols
    1990, Vol. 55, Issue 12, pp. 2956–2962 [Abstract]
  • Stanislav Heřmánek, Tomáš Jelínek, Jaromír Plešek, Bohumil Štíbr and Jiří Fusek
    Revision of nido-2,6-C2B7H11 to the arachno-4,5-C2B7H13 structure. Determination of the structure from NMR spectra and chemical origin
    1988, Vol. 53, Issue 11, pp. 2742–2752 [Abstract]
  • Bohumil Štíbr, Jaromír Plešek, Tomáš Jelínek, Stanislav Heřmánek, Konstantin A. Solntsev and Nicolai T. Kuznetsov
    Symmetrical isomers of arachno-5,5'-X-(6,9-C2B8H13)2 (X = O and OSO2O) compounds
    1987, Vol. 52, Issue 4, pp. 957–959 [Abstract]
  • Bohumil Štíbr, Zbyněk Janoušek, Jaromír Plešek, Tomáš Jelínek and Stanislav Heřmánek
    Arachno-6,9-C2B8H14 dicarbaborane and its 1- and 5-monohalogenated derivatives
    1987, Vol. 52, Issue 1, pp. 103–112 [Abstract]
  • Tomáš Jelínek, Jaromír Plešek, Stanislav Heřmánek and Bohumil Štíbr
    Chemistry of compounds with the 1-carba-closo-dodecaborane(12) framework
    1986, Vol. 51, Issue 4, pp. 819–829 [Abstract]
  • Jaromír Plešek, Tomáš Jelínek, Stanislav Heřmánek and Bohumil Štíbr
    Synthesis and reactions of 1,2-dicarba-closo-dodecarborane-1-yl tetrahydroborate(1-)
    1986, Vol. 51, Issue 1, pp. 81–89 [Abstract]
  • Tomáš Jelínek, Jaromír Plešek, Stanislav Heřmánek and Bohumil Štíbr
    Preparation of 7-substituted 7-carba-nido-undecaboranes(12)
    1985, Vol. 50, Issue 6, pp. 1376–1382 [Abstract]
  • Jaromír Plešek, Karel Baše, František Mareš, František Hanousek, Bohumil Štíbr and Stanislav Heřmánek
    Potential uses of metallocarborane sandwich anions for analysis, characterization and isolation of various cations and organic bases
    1984, Vol. 49, Issue 12, pp. 2776–2789 [Abstract]
  • Bohumil Štíbr, Zbyněk Janoušek, Karel Baše, Stanislav Heřmánek, Jaromír Plešek and Inessa A. Zakharova
    Synthesis and structure of μ-6,9-metalla-bis(ligand)-6,9-dicarba-nido-decarboranes(10) from the [6,9-C2B8H10]2- anion
    1984, Vol. 49, Issue 8, pp. 1891–1894 [Abstract]
  • Bohumil Štíbr, Zbyněk Janoušek, Karel Baše, Jaromír Plešek, Konstantin A. Solntsev, Lev A. Butman, Igor I. Kuznetsov and Nikolai T. Kuznetsov
    Synthesis of ten-vertex closo-metallacarbaboranes from 4-CB8H14
    1984, Vol. 49, Issue 7, pp. 1660–1664 [Abstract]
  • Jaromír Plešek, Tomáš Jelínek, Eva Drdáková, Stanislav Heřmánek and Bohumil Štíbr
    A convenient preparation of 1-CB11H12- and its C-amino derivatives
    1984, Vol. 49, Issue 7, pp. 1559–1562 [Abstract]
  • Jaromír Plešek, Bohumil Štíbr and Stanislav Heřmánek
    A [8,8'-μ-I-3-Co(1,2-C2B9H10)2] metallacarborane complex with a iodonium bridge. Evidence for a bromonium analogue
    1984, Vol. 49, Issue 6, pp. 1492–1496 [Abstract]
  • Karel Baše
    Degradation-insertion reactions of decaborane(14) with inorganic salts
    1983, Vol. 48, Issue 9, pp. 2593–2603 [Abstract]
  • Zbyněk Janoušek, Jaromír Plešek, Bohumil Štíbr and Stanislav Heřmánek
    Synthesis and structure of iso-C4B18H22
    1983, Vol. 48, Issue 1, pp. 228–231 [Abstract]
  • Jiří Dolanský, Stanislav Heřmánek and Rudolf Zahradník
    Electronic structure and 11B-NMR spectra of nine-vertex heteroboranes: 4-CB8H14, 4-NB8H13, 4-SB8H12 and 4,6-C2B7H13
    1981, Vol. 46, Issue 10, pp. 2479–2493 [Abstract]
  • Karel Baše, Bohumil Štíbr, Jiří Dolanský and Josef Duben
    Preparation, properties and structure of some intermediate nido- and arachno-monocarbaboranes
    1981, Vol. 46, Issue 10, pp. 2345–2353 [Abstract]
  • Jaromír Plešek, Zbyněk Plzák, Jiří Stuchlík and Stanislav Heřmánek
    Synthesis of B-alkyl derivatives of o-carborane by alkylation under electrophilic conditions; Scope and limitation
    1981, Vol. 46, Issue 8, pp. 1748–1763 [Abstract]
  • Jaromír Plešek and Stanislav Heřmánek
    Syntheses and properties of substituted icosahedral carborane thiols
    1981, Vol. 46, Issue 3, pp. 687–692 [Abstract]
  • Jaromír Plešek, Zbyněk Janoušek and Stanislav Heřmánek
    Synthesis and properties of some icosahedral carborane B,B'-dithiols
    1980, Vol. 45, Issue 6, pp. 1775–1779 [Abstract]
  • Jaromír Plešek and Stanislav Heřmánek
    Synthesis and properties of 1-HSCH2-1,2-C2B10H11
    1979, Vol. 44, Issue 9, pp. 2769–2771 [Abstract]
  • Jaromír Plešek and Stanislav Heřmánek
    Experimental evaluation of charge distribution on particular skeletal atoms in icosahedral carboranes by means of HS-derivatives
    1979, Vol. 44, Issue 1, pp. 24–33 [Abstract]
  • Jaromír Plešek, Zbyněk Janoušek and Stanislav Heřmánek
    Four new (CH3)2S·C2B9H11 isomers
    1978, Vol. 43, Issue 11, pp. 2862–2868 [Abstract]
  • Jaromír Plešek, Zbyněk Janoušek and Stanislav Heřmánek
    Chemistry of 9-mercapto-1,7-dicarba-closo-dodecaborane
    1978, Vol. 43, Issue 5, pp. 1332–1338 [Abstract]
  • Jaromír Plešek and Stanislav Heřmánek
    Introduction of an HS-group into electron donor positions in icosahedral heteroboranes. A new method for the preparation of metallocarborane sandwich compounds with o-phenylene bridges
    1978, Vol. 43, Issue 5, pp. 1325–1331 [Abstract]
  • J. Plešek, S. Heřmánek, K. Baše, Lee J. Todd and W. F. Wright
    Zwitterionic compounds of the 8,8'-X(C2B9H10)2Co series with monoatomic O, S, Se, Te, N bridges between carborane ligands
    1976, Vol. 41, Issue 12, pp. 3509–3515 [Abstract]