Collect. Czech. Chem. Commun. 1974, 39, 1447-1461
https://doi.org/10.1135/cccc19741447

Cyclisation and solvolysis of stereoisomeric 4-tert-butyl-2-aminomethylcyclohexanol derivatives

M. Pánková and M. Tichý

Individual author index pages


Other CCCC articles of these authors

  • M. Tichý, P. Maloň, I. Frič and K. Bláha
    Synthesis and chiroptical properties of six-membered lactams substituted with tert-butyl group
    1977, Vol. 42, Issue 12, pp. 3591–3604 [Abstract]
  • M. Pánková and J. Závada
    Alkyl structure-reactivity relationships in anti-elimination of open-chain tosylates: On steric hindrance to approach of associated and dissociated tert-butoxide base
    1977, Vol. 42, Issue 12, pp. 3439–3448 [Abstract]
  • J. Závada and M. Pánková
    Alkyl structure-selectivity relationships E2 reactions of open-chain tosylates: Steric effects in the anti-pathway induced by dissociated and associated tert-butoxide base
    1977, Vol. 42, Issue 12, pp. 3421–3438 [Abstract]
  • P. Maloň, I. Frič, M. Tichý and K. Bláha
    Chiroptical properties of (-)-4-methyl-4-azatricyclo[4,4,0,03,8]decan-5-one - A lactam with a non-planar tertiary cis-amide group
    1977, Vol. 42, Issue 10, pp. 3104–3110 [Abstract]
  • M. Pánková and J. Závada
    The effect of hydrogen bonding on orientation in anti-E2 reactions
    1977, Vol. 42, Issue 7, pp. 2161–2166 [Abstract]
  • M. Pánková and J. Závada
    Geometrical and positional orientation in anti-E2 reactions: The effect of base association in a wider scale of transition states
    1977, Vol. 42, Issue 6, pp. 1981–1991 [Abstract]
  • I. Frič, P. Maloň, M. Tichý and K. Bláha
    Chiroptical properties of 4-azatricyclo[4,4,0,03,8]decan-5-one - A lactam with a non-planar cis-amide group
    1977, Vol. 42, Issue 2, pp. 678–686 [Abstract]
  • J. P. Girard, J. C. Rossi, R. Escale, S. Vašíčková and M. Tichý
    Conformational study of cyclic 2-amino and 2-dimethylamino alcohols with six-membered ring by 1H-NMR spectroscopy
    1977, Vol. 42, Issue 1, pp. 90–104 [Abstract]
  • J. Závada, M. Pánková and M. Svoboda
    syn-anti Duality in E2 reactions: The effects of leaving group and base association in the competing pathways
    1976, Vol. 41, Issue 12, pp. 3778–3798 [Abstract]
  • S. Vašíčková, A. Vítek, M. Tichý, J. P. Girard and J. C. Rossi
    Infrared study of chair-boat equilibria and deformations in derivatives of trans-bicyclo[4,3,0]nonane: A comparison with trans-decalin system
    1976, Vol. 41, Issue 12, pp. 3600–3606 [Abstract]
  • J. Hapala and M. Tichý
    Comparison of β-deuterium effects in solvolysis of perhydro-as-indacenyl and various 2-alkylcyclohexyl p-toluenesulphonates
    1976, Vol. 41, Issue 10, pp. 2928–2941 [Abstract]
  • M. Tichý, E. Hamšíková and K. Bláha
    Synthesis of 4-azatricyclo[4,4,0,03,8]decan-5-one - A lactam with a non-planar cis-amide group and related compounds
    1976, Vol. 41, Issue 7, pp. 1935–1943 [Abstract]
  • J. Závada, M. Pánková and Z. Arnold
    Silver perchlorate promoted reactions: Arylmethylation of aromatics by bromomethylarenes
    1976, Vol. 41, Issue 6, pp. 1777–1790 [Abstract]
  • J. Smolíková, M. Tichý and K. Bláha
    Infrared spectroscopy of 4-azatricyclo[4,4,0,03,8]decan-5-one - A lactam with a non-planar cis-amide group
    1976, Vol. 41, Issue 2, pp. 413–429 [Abstract]
  • M. Tichý, L. Kniežo and J. Hapala
    Solvolysis of 4-twistyl and 10-protoadamantyl tosylates. The relationship between these systems
    1975, Vol. 40, Issue 12, pp. 3862–3878 [Abstract]
  • M. Tichý and M. Pánková
    Diequatorial chair transition state in cyclisation of a diequatorial benzamido methanesulphonate
    1975, Vol. 40, Issue 3, pp. 647–657 [Abstract]
  • M. Pánková and M. Tichý
    Cyclisation of N-benzoyl-O-methanesulphonyl derivatives of conformationally biased diequatorial 2-aminocyclohexanols
    1975, Vol. 40, Issue 3, pp. 634–646 [Abstract]
  • M. Tichý
    Absolute configuration and chiroptical properties of tricyclo[4.4.0.03,8]decane (twistane) and some of its derivatives
    1974, Vol. 39, Issue 9, pp. 2673–2684 [Abstract]
  • M. Tichý
    Interaction of methemoglobin with some derivatives of benzene
    1974, Vol. 39, Issue 4, pp. 935–942 [Abstract]
  • M. Tichý, L. Kniežo and S. Vašíčková
    Intramolecular hydrogen bonding in some vicinal derivatives of tricyclo[4,4,0,03,8]decane (twistane)
    1974, Vol. 39, Issue 2, pp. 555–565 [Abstract]
  • M. Pánková, J. Krupička and J. Závada
    Rates of the Menschutkin reaction in alkyldimethylamines: The effect of alkyl structure and solvent
    1974, Vol. 39, Issue 1, pp. 167–170 [Abstract]
  • M. Tichý
    Stereochemical studies. LXXV. Conformational equilibria in substituted 2-aminocyclohexanols and 2-hydroxycyclohexanecarboxylic acids in hydroxylic medium
    1973, Vol. 38, Issue 12, pp. 3631–3636 [Abstract]
  • J. Závada, M. Pánková and M. Svoboda
    Stereochemical studies. LXXIV. The alkyl structure-reactivity relationship in Cope elimination of alkyldimethylamine oxides
    1973, Vol. 38, Issue 7, pp. 2102–2120 [Abstract]
  • S. Vašíčková, A. Vítek and M. Tichý
    Stereochemical studies. LXXIII. Conformational equilibria in 3-hydroxypiperidine and in some of its methyl derivatives
    1973, Vol. 38, Issue 6, pp. 1791–1803 [Abstract]
  • M. Tichý and L. Kniežo
    Stereochemical studies. LXXII. 4,5-Disubstituted twistanes: Vicinal intercations OH/CH3 and OH/CO2CH3 in compounds with the torsion angle Θ ~ 30º
    1973, Vol. 38, Issue 5, pp. 1537–1550 [Abstract]
  • Z. Arnold, J. Kahovcová, M. Pánková, M. Svoboda, M. Tichý and F. Šorm
    Natural and synthetic materials with the insect hormone activity. XIV. Synthesis of substituted phenyl geranyl ethers and related compounds
    1973, Vol. 38, Issue 1, pp. 261–269 [Abstract]
  • R. Řeřicha, A. Vítek, S. Vašíčková, M. Pánková and J. Závada
    The infrared spectra of 1-decenes deuterated on the double bond. A comparison with the vinyl halides-dx
    1972, Vol. 37, Issue 11, pp. 3749–3761 [Abstract]
  • M. Pánková, A. Vítek, S. Vašíčková, R. Řeřicha and J. Závada
    Stereochemical studies. LXIX. Contribution of syn- and anti-elimination to the monosubstituted olefin formation from 1-decyltrimethylammonium base
    1972, Vol. 37, Issue 10, pp. 3456–3466 [Abstract]
  • M. Tichý and J. Sicher
    Stereochemical studies. LXV. Synthetic studies in the tricyclo[4,4,0,03,8]decane and tricyclo[4,3,1,03,7]decane series: The synthesis of twistene
    1972, Vol. 37, Issue 9, pp. 3106–3116 [Abstract]
  • J. Závada, M. Pánková and J. Sicher
    Stereochemical studies. LXIII. The contribution of syn- and anti-elimination to olefin formation in branched open-chain systems: The effect of alkyl structure on steric course of bimolecular elimination
    1972, Vol. 37, Issue 7, pp. 2414–2435 [Abstract]
  • M. Tichý, R. Zahradník, J. A. Völlmin and W. Simon
    Physical properties and chemical reactivity of alternant hydrocarbons and related compounds. XXI. Acid-base equilibria of polynuclear phenols and amines
    1972, Vol. 37, Issue 3, pp. 962–969 [Abstract]
  • J. Sicher, M. Svoboda, M. Pánková and J. Závada
    Stereochemical studies. LXII. The Hofmann-Saytzeff and the syn-anti elimination dichotomy: A relationship between the two phenomena
    1971, Vol. 36, Issue 11, pp. 3633–3649 [Abstract]
  • J. Sicher, J. Závada and M. Pánková
    Stereochemical studies. LXI. The contribution of syn- and anti-elimination to olefin formation in open-chain systems: 5-Decyl and 5-nonyl trimethylammonium bases and tosylates
    1971, Vol. 36, Issue 9, pp. 3140–3164 [Abstract]
  • J. Sicher, M. Pánková, J. Závada, L. Kniežo and A. Orahovats
    Stereochemical studies. LX. Steric course of bimolecular elimination in bicyclo[2.2.2]octyl onium bases and tosylates
    1971, Vol. 36, Issue 9, pp. 3128–3139 [Abstract]
  • M. Tichý, S. Vašíčková, A. Vítek and J. Sicher
    Stereochemical studies. LIX. Flattened chair and twist-boat conformations in cis-2-dimethylaminocyclohexanols
    1971, Vol. 36, Issue 4, pp. 1436–1447 [Abstract]
  • M. Tichý and J. Sicher
    Stereochemical studies. LVIII. Synthesis of trans-anti-trans-perhydro-as-indacene, a system containing a frozen cyclohexane chair
    1971, Vol. 36, Issue 4, pp. 1426–1435 [Abstract]
  • M. Tichý, S. Vašíčková, S. V. Arakelian and J. Sicher
    Stereochemical studies. LVII. Conformational equilibria in trans-2-amino- and trans-2-dimethylaminocyclohexanols: Evaluation of the gauche interactions between OH and NR2
    1970, Vol. 35, Issue 5, pp. 1522–1535 [Abstract]
  • A. Orahovats, M. Tichý and J. Sicher
    Stereochemical studies. LVI. Evaluation of vicinal eclipsing interactions between some groups on a bicyclo[2,2,2]octane system
    1970, Vol. 35, Issue 3, pp. 838–843 [Abstract]
  • M. Tichý, A. Orahovats and J. Sicher
    Stereochemical studies. LV. Evaluation of some 1,3-syn-axial interactions in six-membered ring systems
    1970, Vol. 35, Issue 2, pp. 459–468 [Abstract]
  • J. Sicher, M. Tichý, J. Závada and J. Krupička
    Stereochemical studies. LII. Rates of the Menschutkin reaction in cyclohexyldimethylamines. Some unusual rate effects in a simple reaction
    1968, Vol. 33, Issue 5, pp. 1438–1450 [Abstract]
  • M. Tichý and J. Sicher
    Stereochemical studies. XLV. Epimerisation equilibria in conformationally biased 2-methylcyclohexanecarboxylates and cyanides
    1968, Vol. 33, Issue 1, pp. 68–75 [Abstract]
  • M. Tichý and R. Zahradník
    Tables of quantum chemical data. XIV. Energy characteristics of some hydrocarbons with exocyclic methylene group
    1967, Vol. 32, Issue 12, pp. 4485–4491 [Abstract]
  • J. Sicher and M. Tichý
    Stereochemical studies. XLIII. Epimerisation equilibria in conformationally biased and fixed 2-methylcyclohexanols: Evaluation of CH3-OH gauche interactions
    1967, Vol. 32, Issue 10, pp. 3687–3700 [Abstract]
  • M. Tichý, F. Šipoš and J. Sicher
    Stereochemical studies. XXXVIII. Conformational energies for the axial-equatorial change in different cyclohexyl systems
    1966, Vol. 31, Issue 7, pp. 2889–2898 [Abstract]
  • J. Sicher, M. Tichý and F. Šipoš
    Stereochemical studies. XXXVII. Dissociation constants of some 2-methylcyclohexanecarboxylic acids. Conformational equilibria and the preferred rotational conformations of the carboxyl group on the cyclohexane ring
    1966, Vol. 31, Issue 5, pp. 2238–2256 [Abstract]
  • M. Pánková and J. Sicher
    Stereochemical studies. XXIX. Steric effects in an intramolecular displacement reaction in open-chain systems
    1965, Vol. 30, Issue 2, pp. 388–412 [Abstract]
  • J. Sicher, M. Tichý, F. Šipoš, M. Svoboda and Jiří Jonáš
    Stereochemical studies. XXVIII. Evaluation of the contribution of hydroxyl to the dissociation constants of 2-hydroxycarboxylic acids and 2-aminoalcohols as a function of conformation
    1964, Vol. 29, Issue 7, pp. 1561–1576 [Abstract]
  • M. Tichý, J. Šipoš and J. Sicher
    Stereochemical studies. XXIV. A study of ring deformations in 2-aminocyclohexanol derivatives by spectroscopic intramolecular hydrogen bond determination
    1962, Vol. 27, Issue 12, pp. 2907–2924 [Abstract]
  • F. Šipoš, J. Krupička, M. Tichý and J. Sicher
    Stereochemical studies. XXIII. The 4-t-butyl-2-methylcyclohexanols - Synthesis and rates of chromic acid oxidation
    1962, Vol. 27, Issue 9, pp. 2079–2089 [Abstract]
  • J. Sicher, M. Tichý, F. Šipoš and M. Pánková
    Stereochemical studies. XX. Conformational studies on the 2-amino-4-t-butylcyclohexanols; An approach to quantitative conformational analysis of neighbouring group participation and solvolysis in 1,2-difunctional cyclohexane derivatives
    1961, Vol. 26, Issue 9, pp. 2418–2434 [Abstract]
  • J. Sicher, F. Šipoš and M. Tichý
    Stereochemical studies. XIX. Conformational studies on the 2-amino-4-t-butylcyclohexanols; Synthesis of the four stereoisomers
    1961, Vol. 26, Issue 3, pp. 847–866 [Abstract]
  • M. Tichý, Jiří Jonáš and J. Sicher
    Stereochemical studies. XVII. Dissociation constants of cyclohexanecarboxylic acids and cyclohexylamines and conformational equilibria
    1959, Vol. 24, Issue 10, pp. 3434–3441 [Abstract]
  • J. Sicher, M. Pánková, Jiří Jonáš and M. Svoboda
    Stereochemical studies. XVI. Stereospecific processes in open-chain 3-aminoalcohols. Synthesis of erythro- and threo-4-aminopentan-2-ol
    1959, Vol. 24, Issue 8, pp. 2727–2740 [Abstract]
  • J. Sicher and M. Tichý
    Stereochemical studies. XII. The absolute configuration of conhydrine and ψ-conhydrine
    1958, Vol. 23, Issue 11, pp. 2081–2093 [Abstract]
  • M. Svoboda, M. Tichý and J. Sicher
    Stereochemical studies. XI. Synthesis of cis- and trans-2-aminocyclotetradecanol and 2-aminocyclopentadecanol
    1958, Vol. 23, Issue 10, pp. 1958–1964 [Abstract]
  • M. Svoboda, J. Sicher, J. Farkaš and M. Pánková
    Stereochemical studies. IV. Reaction of Δ2-oxazolines with thioacetic acid. Syntheses of some diacyl-1,2-aminothiols
    1955, Vol. 20, Issue 6, pp. 1426–1438 [Abstract]
  • J. Sicher and M. Pánková
    Stereochemical studies. III. Steric course of the reaction of N-acyl derivatives of 1,2-aminoalcohols with thionyl chloride
    1955, Vol. 20, Issue 6, pp. 1409–1425 [Abstract]