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Collect. Czech. Chem. Commun. 2011, 76, 75-94
https://doi.org/10.1135/cccc2010133
Published online 2011-01-06 09:12:25

Titanocene and ansa-titanocene complexes bearing 2,6-bis(isopropyl)phenoxide ligand(s). Syntheses, characterization and use in catalytic dehydrocoupling polymerization of phenylsilane

Michal Horáčeka, Jan Mernab, Róbert Gyepesc, Jan Sýkorad, Jiří Kubištaa and Jiří Pinkasa,*

a J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, v.v.i., Dolejškova 2155/3, 182 23 Prague 8, Czech Republic
b Institute of Chemical Technology, Prague, Department of Polymers, Technická 5, 166 28 Prague 6, Czech Republic
c Charles University, Department of Inorganic Chemistry, Hlavova 2030, 128 43 Prague 2, Czech Republic
d Institute of Chemical Process Fundamentals, Academy of Sciences of the Czech Republic, v.v.i., Rozvojová 135, 165 02 Prague 6, Czech Republic

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  • Varga Vojtech, Horáček Michal, Bastl Zdeněk, Merna Jan, Císařová Ivana, Sýkora Jan, Pinkas Jiří: Zirconocene silanolate complexes and their heterogeneous siliceous analogues as catalysts for phenylsilane dehydropolymerization. Catal Today 2012, 179, 130. <https://doi.org/10.1016/j.cattod.2011.07.006>
  • Pinkas Jiří, Císařová Ivana, Karban Jindřich, Schraml Jan, Sýkora Jan: Identification of branched oligosilanes in the phenylsilane dehydrocoupling reaction. Journal of Organometallic Chemistry 2012, 710, 20. <https://doi.org/10.1016/j.jorganchem.2012.03.004>