Collect. Czech. Chem. Commun. 2008, 73, 956-966

Effect of Zeolite ZSM-5 Particle Size in the Synthesis of 1,4-Diazabicyclo[2.2.2]octane

Jiří Trejbal*, Josef Pašek and Miroslav Petrisko

Department of Organic Technology, Institute of Chemical Technology, Prague, Technická 5, 166 28 Prague 6, Czech Republic


The effect of the particle size of zeolite ZSM-5 in the synthesis of 1,4-diazabicyclo[2.2.2]octane from ethylenediamine was studied. The activity of the catalyst and its selectivity for 1,4-diazabicyclo[2.2.2]octane increase with decreasing particle size of zeolite ZSM-5.

Keywords: Zeolites; Particle size; 1,4-Diazabicyclo[2.2.2]octane.

References: 33 live references.