Collect. Czech. Chem. Commun.
2007, 72, 527-540
https://doi.org/10.1135/cccc20070527
Synthesis and Characterization of Ni(II) and Pd(II) Complexes Bearing Achiral and Chiral Bidentate Aminophosphine Ligands
David Benito-Garagorria, Kurt Mereiterb and Karl Kirchnera,*
a Institute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9, A-1060 Vienna, Austria
b Institute of Chemical Technologies and Analytics, Vienna University of Technology, Getreidemarkt 9, A-1060 Vienna, Austria
Abstract
The synthesis of a range of achiral and chiral bidentate aminophosphine ligands and their complexes with nickel(II) and palladium(II) has been investigated. The ligands and the complexes have been characterized by NMR spectroscopy, and X-ray structures of representative compounds have been determined. In addition, DFT calculations have been performed to investigate different geometries of the nickel(II) complexes in the solid state and in solution.
Keywords: Aminophosphines; Nickel; Palladium; Allyl complexes; DFT calculations.
References: 68 live references.
