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Collect. Czech. Chem. Commun. 2007, 72, 1631-1638

Polyhedral Dipalladaborane Chemistry. The Molecular Structure and Cluster Electron Count of [7,8-(PPh3)2-7,8-(μ-PPh2)-9,11-(OEt)2-nido-7,8-Pd2B9H8]

Jonathan Boulda, Simon J. Teatb and John D. Kennedya,*

a School of Chemistry, University of Leeds, Leeds, UK LS2 9JT, U.K.
b CCLRC Daresbury Laboratory, Daresbury, Warrington, UK WA4 4AD, U.K.

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  • Bould Jonathan, Tok Oleg, Passarelli Vincenzo, Londesborough Michael G. S., Macías Ramón: Ligand Lability Driven by Metal-to-Borane Pseudorotation: A Mechanism for Ligand Exchange. Inorg. Chem. 2020, 59, 17958. <>
  • Londesborough Michael G. S., Macías Ramón, Kennedy John D., Clegg William, Bould Jonathan: Macropolyhedral Nickelaboranes from the Metal-Assisted Fusion of KB9H14. Inorg. Chem. 2019, 58, 13258. <>
  • Bould Jonathan, Passarelli Vincenzo, Oro Luis A., Macías Ramón: Reversible Small‐Molecule Interactions with Coordinatively Unsaturated Metal Centers Held in Metallathiaborane Clusters. Eur. J. Inorg. Chem. 2017, 2017, 4599. <>
  • Mateo Ana C., Calvo Beatriz, Macías Ramón, Artigas María José, Lahoz Fernando J., Oro Luis A.: [1,1-(η2-dppe)-3-(NC5H5)-closo-1,2-RhSB9H8]: conformational lability and reactivity with H2 upon protonation. Dalton Trans. 2015, 44, 9004. <>
  • Bould Jonathan, Macías Ramón: Do agostic interactions play a role in the stabilization of the nido structure of [(PPh3)2RhSB9H10]?. Journal of Organometallic Chemistry 2014, 761, 120. <>
  • Nie Yong, Miao Jin-Ling, Hu Chun-Hua, Chen Hai-Yan, Cheung Man Sing, Lin Zhen-Yang, Enders Markus, Siebert Walter: Synthesis and characterization of 11-vertex platinaborane compounds having nido-PtB10H12 and nido-Pt2B9H10 skeletons. Polyedron 2012, 31, 607. <>
  • Bould Jonathan, Oro Luis A., Macías Ramón, Kennedy John D., Londesborough Michael G.S.: A DFT and crystallographic reinvestigation of the [L2RuC2B7H9] and [L3RuC2B7H9] ‘hypercloso’ and closo systems. J Polyhedron 2011, 30, 2140. <>