Collect. Czech. Chem. Commun. 2004, 69, 365-383

New Ligands for Enantioselective Recognition of Chiral Carboxylates Based on 1,1'-Binaphthalene-2,2'-diamine

Ivan Stibora,*, Roman Holakovskýa, Asiya R. Mustafinab and Pavel Lhotáka

a Department of Organic Chemistry, Institute of Chemical Technology, Prague, Technická 5, 166 28 Prague 6, Czech Republic
b A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, 420088 Kazan, Russia


Simple bis(arylureido)binaphthalenes and (arylamido)binaphthalenes have been synthesized in both racemic as well as optically active forms. One of these compounds has been found to complex chiral anions with modest enantioselectivity.

Keywords: Biaryls; Binaphthalenes; Axial chirality; Chiral anion recognition; Complexation; Extractions; Amides.

References: 50 live references.