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Collect. Czech. Chem. Commun. 2004, 69, 2174-2182
https://doi.org/10.1135/cccc20042174

Kinetics and Mechanism of the Aminolysis of S-Aryl O-Ethyl Dithiocarbonates in Acetonitrile

Hyuck Keun Oha, Ji Young Oha, Dae Dong Sungb and Ikchoon Leeb,c,*

a Department of Chemistry, Chonbuk National University, Chonju 560-756, Korea
b Department of Chemistry, Dong-A University, Busan 604-714, Korea
c Department of Chemistry, Inha University, Inchon 402-751, Korea

Crossref Cited-by Linking

  • Santos José G., Gazitúa Marcela: The reactions of O‐(4‐nitrophenyl) S‐aryl dithiocarbonates with anilines: Effects on the relative nucleofugality. J of Physical Organic Chem 2019, 32. <https://doi.org/10.1002/poc.3818>
  • Montecinos Rodrigo, Gazitúa Marcela, Santos José G.: The effect of the electrophilic group on the hierarchy of nucleofuges in the aminolysis reactions of thiol- and dithiocarbonates with secondary alicyclic amines: A kinetic and theoretical study. New J. Chem. 2019, 43, 6372. <https://doi.org/10.1039/C9NJ00385A>
  • Castro Enrique A., Gazitúa Marcela, Santos José G.: Reactions of O‐aryl S‐aryl dithiocarbonates with secondary alicyclic amines in aqueous ethanol. Kinetics and mechanism. J of Physical Organic Chem 2011, 24, 466. <https://doi.org/10.1002/poc.1787>
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  • Castro Enrique A., Aliaga Margarita, Campodónico Paola R., Cepeda Marjorie, Contreras Renato, Santos José G.: Experimental and Theoretical Studies on the Nucleofugality Patterns in the Aminolysis and Phenolysis of S-Aryl O-Aryl Thiocarbonates. J. Org. Chem. 2009, 74, 9173. <https://doi.org/10.1021/jo902005y>
  • Castro Enrique A., Aliaga Margarita, Santos José G.: Aminolysis and pyridinolysis of O‐aryl S‐(4‐nitrophenyl) thiocarbonates in aqueous ethanol. Kinetics and mechanism. J of Physical Organic Chem 2008, 21, 271. <https://doi.org/10.1002/poc.1312>
  • Sung Dae Dong, Jang Hee Man, Jung Dae Il, Lee Ikchoon: Kinetics and mechanism of the anilinolysis of S‐aryl N‐arylthiocarbamates in acetonitrile. J of Physical Organic Chem 2008, 21, 1014. <https://doi.org/10.1002/poc.1418>
  • Um Ik-Hwan, Yoon Sora, Park Hye-Ran, Han Hyun-Joo: Aminolysis of 4-nitrophenyl phenyl carbonate and thionocarbonate: effects of amine nature and modification of electrophilic center from CO to CS on reactivity and mechanism. Org. Biomol. Chem. 2008, 6, 1618. <https://doi.org/10.1039/b801422a>
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