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Collect. Czech. Chem. Commun. 2003, 68, 644-662
https://doi.org/10.1135/cccc20030644

A Proposed Mechanism of [closo-CB11H12]- Formation by Dichlorocarbene Insertion Into [nido-B11H14]-. A Computational Study by Density Functional Theory

Pawel Rempala and Josef Michl*

Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO 80309-0215, U.S.A.

Crossref Cited-by Linking

  • Pecyna Jacek, Rončević Igor, Michl Josef: Insertion of Carbenes into Deprotonated nido-Undecaborane, B11H13(2-). Molecules 2019, 24, 3779. <https://doi.org/10.3390/molecules24203779>
  • Konieczka Szymon Z., Schlüter Florian, Sindorf Christoph, Kerpen Christoph, Bernhardt Eduard, Finze Maik: Stepwise Introduction of Cyano Groups into nido - and closo -Undecaborate Clusters. Chem. Eur. J. 2018, 24, 3528. <https://doi.org/10.1002/chem.201704860>
  • Douvris Christos, Michl Josef: Update 1 of: Chemistry of the Carba-closo-dodecaborate(−) Anion, CB11H12–. Chem. Rev. 2013, 113, PR179. <https://doi.org/10.1021/cr400059k>
  • Lepšík Martin, Srnec Martin, Plešek Jaromír, Buděšínský Miloš, Klepetářová Blanka, Hnyk Drahomír, Grüner Bohumír, Rulíšek Lubomír: Thiocyanation of closo-Dodecaborate B12H122−. A Novel Synthetic Route and Theoretical Elucidation of the Reaction Mechanism. Inorg. Chem. 2010, 49, 5040. <https://doi.org/10.1021/ic100206y>
  • Körbe Stefanie, Schreiber Peter J., Michl Josef: Chemistry of the Carba-closo-dodecaborate(−) Anion, CB11H12-. Chem. Rev. 2006, 106, 5208. <https://doi.org/10.1021/cr050548u>
  • Körbe Stefanie, Sowers Damian B., Franken Andreas, Michl Josef: Preparation of 1-p-Halophenyl and 1-p-Biphenylyl Substituted Monocarbadodecaborate Anions [closo-1-Ar−CB11H11]- by Insertion of Arylhalocarbenes into [nido-B11H14]-. Inorg. Chem. 2004, 43, 8158. <https://doi.org/10.1021/ic049255u>
  • Vyakaranam Kamesh, Körbe Stefanie, Divišová Hana, Michl Josef: A New Type of Intermediate, C+(BCH3)11- ↔ C(BCH3)11, in a Grob Fragmentation Coupled with Intramolecular Hydride Transfer. A Nonclassical Carbocation Ylide or a Carbenoid?. J. Am. Chem. Soc. 2004, 126, 15795. <https://doi.org/10.1021/ja0466558>