Collect. Czech. Chem. Commun.
2002, 67, 1247-1261
https://doi.org/10.1135/cccc20021247
The Stereoselective Preparation of Fluorinated Dienes via Stille-Liebeskind Cross-Coupling Reactions
Xin Zhang, Long Lu and Donald J. Burton*
Department of Chemistry, University of Iowa, Iowa City, Iowa 52242, U.S.A.
Abstract
Readily prepared fluorinated vinylstannane reagents stereoselectively undergo Stille-Liebeskind cross-coupling reactions with vinyl halides (including fluorine-containing vinyl halides) with Pd(PPh3)4/CuI catalysis.
Keywords: Cross-coupling reactions; Fluorinated dienes; Stille-Liebeskind; Fluorinated vinylstannanes; Pd(0) catalysis; Alkenes; Stannanes.
References: 25 live references.
