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Collect. Czech. Chem. Commun. 2002, 67, 991-1006
https://doi.org/10.1135/cccc20020991

13-Vertex Carbacobaltaboranes: Synthesis and Molecular Structures of the 4,1,6-, 4,1,8- and 4,1,12-Isomers of Cp*CoC2B10H12

Anthony Burke, Ruaraidh McIntosh, David Ellis, Georgina M. Rosair and Alan J. Welch*

Department of Chemistry, Heriot-Watt University, Edinburgh EH14 4AS, U.K.

Crossref Cited-by Linking

  • Chan Antony P.Y., Parkinson John A., Rosair Georgina M., Welch Alan J.: Bis(phosphine)hydridorhodacarborane Derivatives of 1,1′-Bis(ortho-carborane) and Their Catalysis of Alkene Isomerization and the Hydrosilylation of Acetophenone. Inorg. Chem. 2020, 59, 2011. <https://doi.org/10.1021/acs.inorgchem.9b03351>
  • Loginov Dmitry A., Shul'pina Lidia S., Muratov Dmitry V., Shul'pin Georgiy B.: Cyclopentadienyl cobalt(III) complexes: Synthetic and catalytic chemistry. Coordination Chemistry Reviews 2019, 387, 1. <https://doi.org/10.1016/j.ccr.2019.01.022>
  • Maier Thomas M., Coburger Peter, van Leest Nicolaas P., Hey-Hawkins Evamarie, Wolf Robert: Direct synthesis of an anionic 13-vertex closo-cobaltacarborane cluster. Dalton Trans. 2019, 48, 15772. <https://doi.org/10.1039/C9DT03111A>
  • Kuvshinova Sofya S., Nelyubina Yulia V., Smol'yakov Alexander F., Kosenko Irina D., Barakovskaya Irina G., Loginov Dmitry A.: Usage of (C5R5)Co(CO)I2 (R = H, Me) for the synthesis of 12-vertex closo-cobaltacarboranes. Unexpected formation of 10-{CpCo(C5H4)}-7,8-Me2-7,8-nido-C2B9H9. Journal of Organometallic Chemistry 2018, 865, 109. <https://doi.org/10.1016/j.jorganchem.2018.01.045>
  • Welch Alan: What Can We Learn from the Crystal Structures of Metallacarboranes?. Crystals 2017, 7, 234. <https://doi.org/10.3390/cryst7080234>
  • Thiripuranathar Gobika, Man Wing Y., Palmero Cesar, Chan Antony P. Y., Leube Bernhard T., Ellis David, McKay David, Macgregor Stuart A., Jourdan Laure, Rosair Georgina M., Welch Alan J.: Icosahedral metallacarborane/carborane species derived from 1,1′-bis(o-carborane). Dalton Trans. 2015, 44, 5628. <https://doi.org/10.1039/C5DT00081E>
  • McAnaw Amelia, Lopez Maria Elena, Ellis David, Rosair Georgina M., Welch Alan J.: Asymmetric 1,8/13,2,x-M2C2B10 14-vertex metallacarboranes by direct electrophilic insertion reactions; the VCD and BHD methods in critical analysis of cage C atom positions. Dalton Trans. 2014, 43, 5095. <https://doi.org/10.1039/C3DT52101J>
  • Loginov Dmitry A., Starikova Zoya A., Corsini Maddalena, Zanello Piero, Kudinov Alexander R.: (Cyclopentadienyl)metalladicarbollides 3-(η-C5R5)-3,1,2-MC2B9H11 (M = Co, Rh, Ir): Synthesis, electrochemistry, and bonding. Journal of Organometallic Chemistry 2013, 747, 69. <https://doi.org/10.1016/j.jorganchem.2012.12.021>
  • McAnaw Amelia, Scott Greig, Elrick Lisa, Rosair Georgina M., Welch Alan J.: The VCD method – a simple and reliable way to distinguish cage C and B atoms in (hetero)carborane structures determined crystallographically. Dalton Trans. 2013, 42, 645. <https://doi.org/10.1039/C2DT31515G>
  • Qiu Zaozao, Wong Kit-Hung, Xie Zuowei: Synthesis, structure and properties of mixed-sandwich cobalta- and ferra-carboranes with ‘carbon-atoms-adjacent’ C2B9 and C2B10 systems. Journal of Organometallic Chemistry 2012, 721-722, 97. <https://doi.org/10.1016/j.jorganchem.2012.06.021>
  • Ward Jas S., Tricas Hugo, Scott Greig, Ellis David, Rosair Georgina M., Welch Alan J.: Facile Isomerization and Unprecedented Decarbonation of Metallacarboranes with Fluorinated Aryl Substituents. Organometallics 2012, 31, 2523. <https://doi.org/10.1021/om200691z>
  • McAnaw Amelia, Elena Lopez Maria, Scott Greig, Ellis David, McKay David, Rosair Georgina M., Welch Alan J.: Untethered 4,1,2-MC2B10 supraicosahedral metallacarboranes, their C,C′-dimethyl 4,1,6-, 4,1,8- and 4,1,12-MC2B10 analogues, and DFT study of the (4,)1,2- to (4,)1,6-isomerisations of C2B11 carboranes and MC2B10 metallacarboranes. Dalton Trans. 2012, 41, 10957. <https://doi.org/10.1039/c2dt31283b>
  • Scott Greig, McAnaw Amelia, McKay David, Boyd Alan S. F., Ellis David, Rosair Georgina M., Macgregor Stuart A., Welch Alan J., Laschi Franco, Rossi Fulvio: Supraicosahedral indenyl cobaltacarboranes. Dalton Trans 2010, 39, 5286. <https://doi.org/10.1039/c003067h>
  • Abram Peter D., Ellis David, Rosair Georgina M., Welch Alan J.: Exopolyhedral ligand flipping on isomerisation of novel supraicosahedral stannacarboranes. Chem. Commun. 2009, 5403. <https://doi.org/10.1039/b911350a>
  • Deng Liang, Chan Hoi-Shan, Xie Zuowei: Synthesis, Structure, Reactivity, and Thermal Isomerization of Boron-Substituted 13-Vertex Cobaltacarboranes (η5-Cp)Co(η6-R2C2B10Me8H2) (R = H, Et). Inorg. Chem. 2007, 46, 2716. <https://doi.org/10.1021/ic062423t>
  • Dalby Kelly J., Ellis David, Erhardt Stefan, McIntosh Ruaraidh D., Macgregor Stuart A., Rae Karen, Rosair Georgina M., Settels Volker, Welch Alan J., Hodson Bruce E., McGrath Thomas D., Stone F. Gordon A.: The Conformations of 13-Vertex ML2C2B10 Metallacarboranes:  Experimental and Computational Studies. J. Am. Chem. Soc. 2007, 129, 3302. <https://doi.org/10.1021/ja067698m>
  • Zlatogorsky Sergey, Ellis David, Rosair Georgina M., Welch Alan J.: Unexpectedly facile isomerisation of [7,10-Ph2-7,10-nido-C2B10H10]2− to [7,9-Ph2-7,9-nido-C2B10H10]2− . Chem. Commun. 2007, 2178. <https://doi.org/10.1039/B618556H>
  • McIntosh Ruaraidh D., Ellis David, Rosair Georgina M., Welch Alan J.: A 15-Vertex Heteroborane. Angew. Chem. 2006, 118, 4419. <https://doi.org/10.1002/ange.200601266>
  • McIntosh Ruaraidh D., Ellis David, Rosair Georgina M., Welch Alan J.: A 15-Vertex Heteroborane. Angew. Chem. Int. Ed. 2006, 45, 4313. <https://doi.org/10.1002/anie.200601266>
  • Corsini Maddalena, de Biani Fabrizia Fabrizi, Zanello Piero: Mononuclear metallacarboranes of groups 6–10 metals: Analogues of metallocenes. Coord Chem Rev - 2006, 250, 1351. <https://doi.org/10.1016/j.ccr.2005.12.009>
  • Franken Andreas, Lei Peng, McGrath Thomas D., Stone F. Gordon A.: Carbonyl–metal fragment insertion into eight-vertex [closo-1-CB7H8]−. Facile synthesis of ten-vertex metalladicarbollide complexes [2,2,2-(CO)3-1-OH-closo-2,1,10-MC2B7H8]n− {M = Fe, Ru (n = 0), Mn, Re (n = 1)}. Chem. Commun. 2006, 3423. <https://doi.org/10.1039/B607768D>
  • Hodson Bruce E., McGrath Thomas D., Stone F. Gordon A.: Synthesis and Reactivity of the 13-Vertex Metallacarborane Anions [4,4,4-(CO)3-closo-4,1,6-MC2B10H12]- (M = Re, Mn). Organometallics 2005, 24, 3386. <https://doi.org/10.1021/om050226g>
  • Ellis David, Lopez Maria Elena, McIntosh Ruaraidh, Rosair Georgina M., Welch Alan J., Quenardelle Romain: The first 4,1,10-MC2B10 supraicosahedral metallacarboranes and a route to previously inaccessible 4,1,12-ruthenium arene species. Chem. Commun. 2005, 1348. <https://doi.org/10.1039/b416646a>
  • Burke Anthony, Ellis David, Ferrer Daniel, Ormsby Daniel L., Rosair Georgina M., Welch Alan J.: Synthetic, spectroscopic, computational and structural studies of some 13-vertex ruthenacarboranes. Dalton Trans. 2005, 1716. <https://doi.org/10.1039/b500944h>
  • McIntosh Ruaraidh, Ellis David, Gil-Lostes Javier, Dalby Kelly J., Rosair Georgina M., Welch Alan J.: The synthesis and characterisation of 4,1,2-MC2B10 metallacarboranes. Dalton Trans. 2005, 1842. <https://doi.org/10.1039/b503214h>
  • Laguna Miguel A, Ellis David, Rosair Georgina M, Welch Alan J: New supraicosahedral metallacarboranes. The synthesis and molecular structures of 4-dppe-4,1,6-closo-NiC2B10H12 and [4-(η-C3H5)-4-(CO)2-4,1,6-closo-MoC2B10H12]−. Inorg Chim Ada 2003, 347, 161. <https://doi.org/10.1016/S0020-1693(02)01454-8>