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Collect. Czech. Chem. Commun. 2002, 67, 813-821
https://doi.org/10.1135/cccc20020813

Two Forgotten Ten-Vertex arachno Triheteroboranes: arachno-5,6,9-C2SB7H11 and arachno-5,6,9-C3B7H13, Their Molecular Structure Determination by ab initio/NMR Approach and Synthesis of the Thiacarbaborane

Drahomír Hnyk* and Josef Holub

Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, 250 68 Řež, Czech Republic

Crossref Cited-by Linking

  • Hnyk Drahomír, Rankin David W. H.: Stereochemistry of free boranes and heteroboranes from electron scattering and model chemistries. Dalton Trans. 2009, 585. <https://doi.org/10.1039/B806774K>
  • Hnyk Drahomír, Bühl Michael, Holub Josef, Hayes Stuart A., Wann Derek A., Mackie Iain D., Borisenko Konstantin B., Robertson Heather E., Rankin David W. H.: Molecular Structures of arachno-Decaborane Derivatives 6,9-X2B8H10 (X = CH2, NH, Se) Including a Gas-Phase Electron-Diffraction Study of 6,9-C2B8H14. Inorg. Chem. 2006, 45, 6014. <https://doi.org/10.1021/ic060296v>
  • Hnyk Drahomír, Holub Josef, Hayes Stuart A., Robinson Mark F., Wann Derek A., Robertson Heather E., Rankin David W. H.: Molecular Structures of Arachno-Heteroboranes with Decaborane Frameworks:  Two Cs-symmetrical Azacarba- and Carbathiaboranes. Inorg. Chem. 2006, 45, 8442. <https://doi.org/10.1021/ic061253h>
  • Janoušek Zbyněk, Holub Josef, Hnyk Drahomı́r, Londesborough Michael G.S., Shoemaker Richard K.: Synthesis of the first 11-vertex arachno-dicarbathiaborane anion, [1,6,7-C2SB8H11]−. Polyhedron 2003, 22, 3541. <https://doi.org/10.1016/j.poly.2003.10.001>
  • Jelínek Tomáš, Štíbr Bohumil, Kennedy John D., Hnyk Drahomír, Bühl Michael, Hofmann Matthias: Azacarbaborane chemistry. Butyl nitrite synthesis of the new eight-, nine- and ten-vertex azacarbaboranes exo- and endo-7-CH3-hypho-7,8-NCB6H11, nido-6,8,9-NC2B7H10, arachno-6,5,9-NC2B7H12 and arachno-6,5,10-C2NB7H12. Dalton Trans. 2003, 1326. <https://doi.org/10.1039/b300088e>