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Collect. Czech. Chem. Commun. 2002, 67, 808-812
https://doi.org/10.1135/cccc20020808

The Reaction of Cp*ReH6, Cp* = C5Me5, with Monoborane to Yield a Novel Rhenaborane. Synthesis and Characterization of arachno-Cp*ReH3B3H8

Sundargopal Ghosh, Alicia M. Beatty and Thomas P. Fehlner*

Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556-5670, U.S.A.

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  • Nanda Pradhan Alaka, Jaiswal Shippy, Ghosh Sundargopal: Metal‐Rich Metallaboranes: Synthesis, Structure, and Bonding of Heteronuclear Trimetallic Clusters containing (μ3‐BH) Ligand. Eur J Inorg Chem 2023, 26. <https://doi.org/10.1002/ejic.202300254>
  • Nandi Chandan, Bag Ranjit, Giri Soumen, Roy Arindam, Cordier Marie, Ghosh Sundargopal: Triple-decker complexes comprising heterocyclic middle-deck with coinage metals. Journal of Organometallic Chemistry 2023, 990, 122667. <https://doi.org/10.1016/j.jorganchem.2023.122667>
  • Pathak Kriti, Mishra Shivankan, Nandi Chandan, Saha Suvam, Ghosh Sundargopal: Synthesis and Chemistry of Dihydridoborate Group 7 Metal Complexes with Varied N,E-Chelated Ligands (E = O, NH, or S). Inorg. Chem. 2023, 62, 160. <https://doi.org/10.1021/acs.inorgchem.2c03095>
  • Pradhan Alaka Nanda, Bairagi Subhash, Ghosh Sundargopal: Diborane and Triborane Species in the Coordination Sphere of Group-8 Transition Metals. Inorg. Chem. 2023, 62, 14790. <https://doi.org/10.1021/acs.inorgchem.3c02286>
  • Mohapatra Stutee, Gayen Sourav, Bag Ranjit, Das Arpita, Ramalakshmi Rongala, Cordier Marie, Ghosh Sundargopal: Structures and Bonding of Early Transition Metallaborane Clusters. Organometallics 2023, 42, 1077. <https://doi.org/10.1021/acs.organomet.2c00363>
  • Haridas Anagha, Chatterjee Debipada, Giri Soumen, De Aishee, Ghosh Sundargopal: Degradation Chemistry of Dimetallaboranes, [(Cp*M)2B5H9+x] with [Ph2Se2] (x = 2 or 0, M = V or Cr). Organometallics 2023, 42, 3199. <https://doi.org/10.1021/acs.organomet.3c00341>
  • Mohapatra Stutee, Gayen Sourav, Shyamal Sampad, Halet Jean-François, Ghosh Sundargopal: Synthesis, Structure and Bonding of the Tungstaboranes [Cp*W(CO)2B3H8] and [(Cp*W)3(CO)2B4H7]. Inorganics 2023, 11, 248. <https://doi.org/10.3390/inorganics11060248>
  • Diaw-Ndiaye Fatou, Sanz Miguel Pablo J., Rodríguez Ricardo, Macías Ramón: The Synthesis, Characterization, and Fluxional Behavior of a Hydridorhodatetraborane. Molecules 2023, 28, 6462. <https://doi.org/10.3390/molecules28186462>
  • Nanda Pradhan Alaka, Keshari Rout Bikram, Halet Jean-François, Ghosh Sundargopal: Metal-rich clusters: synthesis, structure and bonding of metallaboranes featuring µ5-boride and triply bridging borylene units. Inorganica Chimica Acta 2022, 540, 121045. <https://doi.org/10.1016/j.ica.2022.121045>
  • Kar Sourav, Nanda Pradhan Alaka, Ghosh Sundargopal: Metal-rich metallaboranes: Clusters containing triply and tetra bridging borylene and boride units. Coordination Chemistry Reviews 2021, 436, 213796. <https://doi.org/10.1016/j.ccr.2021.213796>
  • Bag Ranjit, Gomosta Suman, Pradhan Alaka Nanda, Roisnel Thierry, Ghosh Sundargopal: Synthesis and characterization of group 6-9 metal-rich homo- and hetero-metallaboranes. Journal of the Indian Chemical Society 2021, 98, 100040. <https://doi.org/10.1016/j.jics.2021.100040>
  • Prakash Rini, Nanda Pradhan Alaka, Ghosh Sundargopal: Chemistry of bimetallic hexaborane(10) analogues: A combined experimental and theoretical study. Inorganica Chimica Acta 2020, 512, 119898. <https://doi.org/10.1016/j.ica.2020.119898>
  • Nandi Chandan, Kar Sourav, Zafar Mohammad, Kar Ketaki, Roisnel Thierry, Dorcet Vincent, Ghosh Sundargopal: Chemistry of Dimetallaoctaborane(12) with Chalcogen-Based Borate Ligands: Obedient versus Disobedient Clusters. Inorg. Chem. 2020, 59, 3537. <https://doi.org/10.1021/acs.inorgchem.0c00122>
  • Prakash Rini, Pradhan Alaka Nanda, Jash Madhuri, Kahlal Samia, Cordier Marie, Roisnel Thierry, Halet Jean-François, Ghosh Sundargopal: Diborane(6) and Its Analogues Stabilized by Mono-, Bi-, and Trinuclear Group 7 Templates: Combined Experimental and Theoretical Studies. Inorg. Chem. 2020, 59, 1917. <https://doi.org/10.1021/acs.inorgchem.9b03217>
  • Golub Igor E., Filippov Oleg A., Kulikova Vasilisa A., Belkova Natalia V., Epstein Lina M., Shubina Elena S.: Thermodynamic Hydricity of Small Borane Clusters and Polyhedral closo-Boranes. Molecules 2020, 25, 2920. <https://doi.org/10.3390/molecules25122920>
  • Gomosta Suman, Ramalakshmi Rongala, Arivazhagan Chinnappa, Haridas Anagha, Raghavendra Beesam, Maheswari Kuppaiyandi, Roisnel Thierry, Ghosh Sundargopal: Synthesis, Structural Characterization, and Theoretical Studies of Silver(I) Complexes of Dihydrobis(2‐mercapto‐benzothiazolyl) Borate. Zeitschrift anorg allge chemie 2019, 645, 588. <https://doi.org/10.1002/zaac.201800492>
  • Eleazer Bennett J., Smith Mark D., Peryshkov Dmitry V.: Reaction of a ruthenium B-carboranyl hydride complex and BH3(SMe2): Selective formation of a pincer-supported metallaborane LRu(B3H8). Tetrahedron 2019, 75, 1471. <https://doi.org/10.1016/j.tet.2019.02.010>
  • Zafar Mohammad, Kar Sourav, Nandi Chandan, Ramalakshmi Rongala, Ghosh Sundargopal: Cluster Fusion: Face-Fused Macropolyhedral Tetracobaltaboranes. Inorg. Chem. 2019, 58, 47. <https://doi.org/10.1021/acs.inorgchem.8b02740>
  • Saha Koushik, Kaur Urminder, Kar Sourav, Mondal Bijan, Joseph Benson, Antharjanam P. K. Sudhadevi, Ghosh Sundargopal: Trithia-diborinane and Bis(bridging-boryl) Complexes of Ruthenium Derived from a [BH3(SCHS)]− Ion. Inorg. Chem. 2019, 58, 2346. <https://doi.org/10.1021/acs.inorgchem.8b02759>
  • Saha Koushik, Kaur Urminder, Borthakur Rosmita, Ghosh Sundargopal: Synthesis of Trithia-Borinane Complexes Stabilized in Diruthenium Core: [(Cp*Ru)2(η1-S)(η1-CS){(CH2)2S3BR}] (R = H or SMe). Inorganics 2019, 7, 21. <https://doi.org/10.3390/inorganics7020021>
  • Joseph Benson, Saha Koushik, Prakash Rini, Nandi Chandan, Roisnel Thierry, Ghosh Sundargopal: Chalcogenolato-bridged dinuclear half sandwich complexes of ruthenium and iridium. Inorganica Chimica Acta 2018, 483, 106. <https://doi.org/10.1016/j.ica.2018.08.005>
  • Bhattacharyya Moulika, Prakash Rini, Jagan R., Ghosh Sundargopal: Synthesis and ligand substitution of tri-metallic triply bridging borylene complexes. Journal of Organometallic Chemistry 2018, 866, 79. <https://doi.org/10.1016/j.jorganchem.2018.04.006>
  • Prakash Rini, De Anangsha, Kirubakaran Bakthavachalam, Ghosh Sundargopal: Metal-Rich Oxametallaboranes of Group 5 Metals: Synthesis and Structure of a Face-Fused μ7-Boride Cluster. Inorg. Chem. 2018, 57, 14748. <https://doi.org/10.1021/acs.inorgchem.8b02512>
  • Bag Ranjit, Mondal Bijan, Bakthavachalam K., Roisnel Thierry, Ghosh Sundargopal: Heterometallic boride clusters: synthesis and characterization of butterfly and square pyramidal boride clusters*. Pure and Applied Chemistry 2018, 90, 665. <https://doi.org/10.1515/pac-2017-1001>
  • Saha Koushik, Ramalakshmi Rongala, Borthakur Rosmita, Gomosta Suman, Pathak Kriti, Dorcet Vincent, Roisnel Thierry, Halet Jean‐François, Ghosh Sundargopal: An Efficient Method for the Synthesis of Boratrane Complexes of Late Transition Metals. Chemistry A European J 2017, 23, 18264. <https://doi.org/10.1002/chem.201704332>
  • Roy Dipak Kumar, De Anangsha, Prakash Rini, Barik Subrat Kumar, Ghosh Sundargopal: Heterodimetallaboranes of Group 4 and 9 Metals: Analogues of Pentaborane(11) and Hexaborane(12). Eur J Inorg Chem 2017, 2017, 4452. <https://doi.org/10.1002/ejic.201700330>
  • Ramalakshmi Rongala, Roisnel Thierry, Dorcet Vincent, Halet Jean-François, Ghosh Sundargopal: Synthesis and structural characterization of trithiocarbonate complexes of molybdenum and ruthenium derived from CS2 ligand. Journal of Organometallic Chemistry 2017, 849-850, 256. <https://doi.org/10.1016/j.jorganchem.2017.03.027>
  • Prakash Rini, Bakthavachalam K., Varghese Babu, Ghosh Sundargopal: Chlorination of the terminal hydrogen atoms in the hydrogen-rich group 5 dimetallaboranes (Cp*M) 2 (B 2 H 6 ) 2 (M = Nb, Ta). Journal of Organometallic Chemistry 2017, 846, 372. <https://doi.org/10.1016/j.jorganchem.2017.07.008>
  • Saha Koushik, Joseph Benson, Borthakur Rosmita, Ramalakshmi Rongala, Roisnel Thierry, Ghosh Sundargopal: Chemistry of ruthenium σ-borane complex, [Cp∗RuCO(μ-H)BH2L] (Cp∗= η5-C5Me5; L = C7H4NS2) with terminal and internal alkynes: Structural characterization of vinyl hydroborate and vinyl complexes of ruthenium. Polyhedron 2017, 125, 246. <https://doi.org/10.1016/j.poly.2017.01.003>
  • Saha Koushik, Joseph Benson, Ramalakshmi Rongala, Anju R. S., Varghese Babu, Ghosh Sundargopal: η4‐HBCC‐σ,π‐Borataallyl Complexes of Ruthenium Comprising an Agostic Interaction. Chemistry A European J 2016, 22, 7871. <https://doi.org/10.1002/chem.201600181>
  • Yuvaraj K., Bhattacharyya Moulika, Prakash Rini, Ramkumar V., Ghosh Sundargopal: New Trinuclear Complexes of Group 6, 8, and 9 Metals with a Triply Bridging Borylene Ligand. Chemistry A European J 2016, 22, 8889. <https://doi.org/10.1002/chem.201600637>
  • Rao Chokkapu Eswara, Barik Subrat Kumar, Yuvaraj K., Bakthavachalam K., Roisnel Thierry, Dorcet Vincent, Halet Jean‐François, Ghosh Sundargopal: Reactivity of CS2 – Syntheses and Structures of Transition‐Metal Species with Dithioformate and Methanedithiolate Ligands. Eur J Inorg Chem 2016, 2016, 4913. <https://doi.org/10.1002/ejic.201600823>
  • Barik Subrat Kumar, Chowdhury Monojit Ghosal, De Susmita, Parameswaran Pattiyil, Ghosh Sundargopal: Extended Sandwich Molecules Displaying Direct Metal–Metal Bonds. Eur J Inorg Chem 2016, 2016, 4546. <https://doi.org/10.1002/ejic.201600888>
  • RAMALAKSHMI RONGALA, SAHA KOUSHIK, PAUL ANAMIKA, GHOSH SUNDARGOPAL: Reactivity of [Cp*Mo(CO)3Me] with chalcogenated borohydrides Li[BH2E3] and Li[BH3EFc] (Cp*= (η 5-C5Me5); E = S, Se or Te; Fc = (C5H5-Fe-C5H4)). J Chem Sci 2016, 128, 1025. <https://doi.org/10.1007/s12039-016-1102-4>
  • Saha Koushik, Gomosta Suman, Ramalakshmi Rongala, Varghese Babu, Ghosh Sundargopal: Synthesis and Structural Characterization of Group 7 and 8 Metal-Thiolate Complexes. Proc. Natl. Acad. Sci., India, Sect. A Phys. Sci. 2016, 86, 521. <https://doi.org/10.1007/s40010-016-0305-x>
  • Roy Dipak Kumar, Yuvaraj K., Jagan R., Ghosh Sundargopal: Chemistry of Rh-N,S heterocyclic carbene complexes. Journal of Organometallic Chemistry 2016, 811, 8. <https://doi.org/10.1016/j.jorganchem.2016.03.012>
  • Mondal Bijan, Bhattacharya Somnath, Ghosh Sundargopal: Heterometallic boride clusters of group 6 and 9 transition metals. Journal of Organometallic Chemistry 2016, 819, 147. <https://doi.org/10.1016/j.jorganchem.2016.06.027>
  • Borthakur Rosmita, Prakash Rini, Nandi Purbasha, Ghosh Sundargopal: Metal rich metallaboranes of group 9 transition metals. Journal of Organometallic Chemistry 2016, 825-826, 1. <https://doi.org/10.1016/j.jorganchem.2016.10.008>
  • Roy Dipak Kumar, Borthakur Rosmita, Prakash Rini, Bhattacharya Somnath, Jagan Rajamony, Ghosh Sundargopal: Hypoelectronic 8–11-Vertex Irida- and Rhodaboranes. Inorg. Chem. 2016, 55, 4764. <https://doi.org/10.1021/acs.inorgchem.6b00076>
  • Ramalakshmi Rongala, Maheswari K., Sharmila Dudekula, Paul Anamika, Roisnel Thierry, Halet Jean-François, Ghosh Sundargopal: Reactivity of cyclopentadienyl transition metal(ii) complexes with borate ligands: structural characterization of the toluene-activated molybdenum complex [Cp*Mo(CO)2(η3-CH2C6H5)]. Dalton Trans. 2016, 45, 16317. <https://doi.org/10.1039/C6DT02641A>
  • Ramalakshmi Rongala, Bhattacharyya Moulika, Rao Chokkapu Eswara, Ghosh Sundargopal: Synthesis, structure and chemistry of low-boron containing molybdaborane: Arachno -[Cp*Mo(CO) 2 B 3 H 8 ]. Journal of Organometallic Chemistry 2015, 792, 31. <https://doi.org/10.1016/j.jorganchem.2014.12.031>
  • Anju V. P., Barik Subrat Kumar, Mondal Bijnaneswar, Ramkumar V., Ghosh Sundargopal: Metallaboranes from Metal Carbonyl Compounds and Their Utilization as Catalysts for Alkyne Cyclotrimerization. ChemPlusChem 2014, 79, 546. <https://doi.org/10.1002/cplu.201400013>
  • Sharmila Dudekula, Yuvaraj K., Barik Subrat Kumar, Roy Dipak Kumar, Chakrahari Kiran Kumarvarma, Ramalakshmi Rongala, Mondal Bijan, Varghese Babu, Ghosh Sundargopal: New Heteronuclear Bridged Borylene Complexes That Were Derived from [{Cp*CoCl}2] and Mono‐MetalCarbonyl Fragments. Chemistry A European J 2013, 19, 15219. <https://doi.org/10.1002/chem.201302427>
  • Anju R.S., Geetharani K., Roy Dipak Kumar, Ghosh Sundargopal: Synthesis and structural characterization of diruthenium cluster containing germylene ligand. Journal of Organometallic Chemistry 2013, 731, 18. <https://doi.org/10.1016/j.jorganchem.2013.02.004>
  • Anju R. S., Roy Dipak Kumar, Mondal Bijan, Ramkumar V., Ghosh Sundargopal: An Early–Late Transition Metal Hybrid Analogue of Hexaborane(12). Organometallics 2013, 32, 4618. <https://doi.org/10.1021/om400594d>
  • Geetharani K., Bose Shubhankar Kumar, Basak Debajyoti, Suresh Venkata M., Ghosh Sundargopal: A new entry into ferraborane chemistry: Synthesis and characterization of heteroferraborane complexes. Inorganica Chimica Acta 2011, 372, 42. <https://doi.org/10.1016/j.ica.2010.12.033>
  • Geetharani K., Kumar Bose Shubhankar, Pramanik Goutam, Kumar Saha Tanmoy, Ramkumar V., Ghosh Sundargopal: An Efficient Route to Group 6 and 8 Metallaborane Compounds: Synthesis of arachno‐[Cp*Fe(CO)B3H8] and closo‐[(Cp*M)2B5H9] (M = Mo, W). Eur J Inorg Chem 2009, 2009, 1483. <https://doi.org/10.1002/ejic.200801137>
  • Girolami Gregory S., Kim Do Young, You Yujian: Synthesis and crystal structures of two (cyclopentadienyl)titanium(III) hydroborate complexes, [Cp∗TiCl(BH4)]2 and Cp2Ti(B3H8). J Organomet Chem 2008, 693, 981. <https://doi.org/10.1016/j.jorganchem.2007.12.017>
  • Green Malcolm L.H., Leach John B., Kelland Malcolm A.: Formation of ferraboranes from pentaborane(9) or BH3·thf and an electron-rich cyclopentadienyl iron phosphine hydride. J Organomet Chem 2007, 692, 4147. <https://doi.org/10.1016/j.jorganchem.2007.06.024>
  • Green Malcolm L. H., Leach John B., Kelland Malcolm A.: Synthesis and Interconversion of Some Small Ruthenaboranes: Reaction of a Ruthenium Borohydride with Pentaborane(9) to Form Larger Ruthenaboranes. Organometallics 2007, 26, 4031. <https://doi.org/10.1021/om700323g>
  • Green Malcolm L.H., Leach John B., Kelland Malcolm A.: Reactions of small boranes with ruthenium phosphine hydrides: Oligomerisation of monoborane-tetrahydrofuran to a nido-hexaruthenaborane. J Organomet Chem 2006, 691, 2063. <https://doi.org/10.1016/j.jorganchem.2006.01.027>
  • Goedde Dean M., Girolami Gregory S.: A New Class of CVD Precursors to Metal Borides:  Cr(B3H8)2 and Related Octahydrotriborate Complexes. J. Am. Chem. Soc. 2004, 126, 12230. <https://doi.org/10.1021/ja046906c>
  • Beckett Michael A, Brassington David S, Coles Simon J, Gelbrich Thomas, Hursthouse Michael B: Synthesis and characterisation of a series of Group 7 metal 2,2,2,2-dicarbonylbis(triorganophosphine)-arachno-2-metallatetraboranes, [M(CO)2L2(B3H8)] (M=Re, Mn); crystal and molecular structures of [Re(CO)2(dppf)(B3H8)] and [Mn(CO)2(dppe)(B3H8)]. J Polyhedron 2003, 22, 1627. <https://doi.org/10.1016/S0277-5387(03)00289-4>
  • Peldo Melanie A., Beatty Alicia M., Fehlner Thomas P.: Reaction of the Transition Metal Hydrides [Cp*MH2]2 (Cp* = η5-C5Me5; M = Fe, Ru) with BH3·THF to Yield Metallaboranes. Improved Kinetic Control Leads to Novel Ferraboranes. Organometallics 2003, 22, 3698. <https://doi.org/10.1021/om0340084>