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Collect. Czech. Chem. Commun. 2002, 67, 769-782
https://doi.org/10.1135/cccc20020769

Chemistry on the Rhodacarborane Cluster [9,9-(PPh3)-nido-9,7,8-RhC2B8H11]: Formation of Bidentate Phosphine and Bimetallic Derivatives

Oleg Volkov, Nigam P. Rath and Lawrence Barton*

Department of Chemistry, University of Missouri-St. Louis, St. Louis, MO 63121, U.S.A.

Crossref Cited-by Linking

  • Dolgushin Fedor M., Kostukovich Alexandr Yu, Pisareva Irina V., Konoplev Vitalii E., Chizhevsky Igor T.: Cluster rearrangement of isonido-ruthenacarboranes [1-(η6-1,4-Me2C6H4)-3(6)-Cl-isonido-1,2,4-RuC2B8H9] under thermal conditions. Journal of Organometallic Chemistry 2014, 751, 493. <https://doi.org/10.1016/j.jorganchem.2013.10.024>
  • Dolgushin F. M., Balagurova E. V., Pisareva I. V., Godovikov I. A., Barakovskaya I. G., Chizhevsky I. T.: First cupracarborane commo-clusters based on the medium-cage nido-5,6-C2B8H12-carborane and molecular structure of [Ph3PEt][commo-9,9′-Cu(nido-7,8-C2B8H11)2]. Russ Chem Bull 2013, 62, 1919. <https://doi.org/10.1007/s11172-013-0276-x>
  • Volkov Oleg, Macías Ramón, Rath Nigam P., Barton Lawrence: Organometallic chemistry on rhodaheteroborane clusters: reactions with bidentate phosphines and organotransition metal reagents. Applied Organom Chemis 2003, 17, 409. <https://doi.org/10.1002/aoc.448>
  • Volkov Oleg, Macías Ramón, Rath Nigam P., Barton Lawrence: Phosphine−Boranes as Bidentate Ligands:  Formation of [8,8-η2-{η2-(BH3)·dppm}-nido-8,7-RhSB9H10] and [9,9-η2-{η2-(BH3)·dppm}-nido-9,7,8-RhC2B8H11] from [8,8-(η2-dppm)-8-(η1-dppm)-nido-8,7-RhSB9H10] and [9,9-(η2-dppm)-9-(η1-dppm)-nido-9,7,8-RhC2B8H11], Respectively. Inorg. Chem. 2002, 41, 5837. <https://doi.org/10.1021/ic0258375>
  • Volkov Oleg, Rath Nigam P., Barton Lawrence: Chemistry of a Metallathiaborane Cluster. 5. Reaction of [8,8-(η2-dppm)-8-(η1-dppm)-nido-8,7-RhSB9H10] and Its Derivatives with Organotransition-Metal Reagents. Organometallics 2002, 21, 5505. <https://doi.org/10.1021/om020480y>