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Collect. Czech. Chem. Commun. 2002, 67, 569-576
https://doi.org/10.1135/cccc20020569

Cobalt Bis(1,2-dicarbollide) Ion with a Disulfur Bridge Between B(8) and B(8'). X-Ray Structure, Absolute Configuration of One Enantiomer, and Implications

Jaromír Plešeka,*, Ivana Císařováb and Jaroslav Bačkovskýa

a Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, 250 68 Řež, Czech Republic
b Department of Inorganic Chemistry, Charles University, 128 40 Prague 2, Czech Republic

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  • Sardo Carla, Janczak Sławomir, Leśnikowski Zbigniew J.: Unusual resistance of cobalt bis dicarbollide phosphate and phosphorothioate bridged esters towards alkaline hydrolysis: The “metallacarborane effect”. Journal of Organometallic Chemistry 2019, 896, 70. <https://doi.org/10.1016/j.jorganchem.2019.06.001>
  • Corsini Maddalena, de Biani Fabrizia Fabrizi, Zanello Piero: Mononuclear metallacarboranes of groups 6–10 metals: Analogues of metallocenes. Coord Chem Rev - 2006, 250, 1351. <https://doi.org/10.1016/j.ccr.2005.12.009>
  • Franken Andreas, Kennedy John D.: Polyhedral dicarbaborane chemistry: a convenient synthesis of the [nido-7,8-C2B9H12]− ‘dicarbollide’ anion via the Brellochs reaction. J Inorg Chem Commun 2005, 8, 52. <https://doi.org/10.1016/j.inoche.2004.10.022>