Collect. Czech. Chem. Commun.
2002, 67, 1629-1634
https://doi.org/10.1135/cccc20021629
Synthesis and Structural Characterization of Polymeric Silver(I) Butyl Xanthate
Jiang Xuhonga,b, Zhang Weiguanga,*, Zhong Yunb and Wang Sueleinc
a Department of Chemistry, South China Normal University, Guangzhou 510631, China
b Department of Foundation, Zhongkai Agrotechnical College, Guangzhou 510230, China
c Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 300, China
Abstract
Polymeric silver(I) butyl xanthate, [Ag(Bu-XA)]n, was synthesized and crystallographically characterized. The polymer shows chair conformation of eight-membered ring units and a novel mode of coordination, with a structural arrangement different from that in silver dialkyldithiocarbamate and dialkyldithiophosphates. The polymeric structure of the new complex is formed by corrugated planes.
Keywords: Silver(I) complexes; Butyl xanthate; Xanthates; Two-dimensional polymers; Crystal structure; X-Ray diffraction.
References: 13 live references.
