Collect. Czech. Chem. Commun. 2002, 67, 1609-1615

Transition Metal-Organic Polycarboxylate Coordination Polymer Chemistry. Hydrothermal Synthesis and Structural Characterization of a One-Dimensional Coordination Polymer [Fe(bzta)2(ox)]n (bzta = benzotriazole, ox = oxalato)

Hong-Bin Jiaa,b, Jie-Hui Yua, Ji-Qing Xua,*, Hong Dinga, Wei-Jie Jinga, Yong-Jiang Liuc, Yi-Zhi Lic, Yan Xuc, Ling Yed, Tie-Gang Wanga, Jia-Ning Xua and Zeng-Chun Lia,b

a College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, P.R. China
b Department of Chemistry, Inner Mongolia University for Nationalities, Tongliao 028000, P.R. China
c State Key Laboratory of Coordination Chemistry Nanjing University, Nanjing 210093, P.R. China
d Key Laboratory of Supramolecular Structure and Materials of Ministry of Education, Jilin University, Changchun 130023, P.R. China


Complex [Fe(bzta)2(ox)]n (1) was synthesized from K3[Fe(ox)3]ยท3H2O and benzotriazole. Single-crystal X-ray diffraction study of complex 1 has established a novel structure containing several kinds of secondary bonding interactions. All these interactions make it display a three-dimensional supramolecular network.

Keywords: Crystal structure; Benzotriazole; Ferrous complexes; Coordination polymers; Oxalates; X-Ray diffraction.

References: 11 live references.