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Collect. Czech. Chem. Commun. 2001, 66, 1359-1374

Synthesis of Trichloro(η5-alkenyltetramethylcyclopentadienyl)titanium(IV) Complexes and Their Activity in Styrene Polymerization

Jaroslav Zemáneka, Lenka Fröhlichováb, Pavel Šindelářb, Petr Štěpničkac, Ivana Císařovác, Vojtech Vargad, Michal Horáčeka and Karel Macha,*

a J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, 182 23 Prague 8, Czech Republic
b Polymer Institute Brno, 656 49 Brno, Czech Republic
c Department of Inorganic Chemistry, Charles University, 128 40 Prague 2, Czech Republic
d Research Institute of Inorganic Chemistry, 400 01 Ústí nad Labem, Czech Republic

Crossref Cited-by Linking

  • Schellenberg Jürgen: Recent transition metal catalysts for syndiotactic polystyrene. Prog Polym Sci 2009, 34, 688. <>
  • Varga Vojtech, Pinkas Jiří, Císařová Ivana, Gyepes Róbert, Mach Karel, Kubišta Jiří, Horáček Michal: Synthesis and Structure of Permethylcyclopentadienyltitanium Diisopropoxide Zwitterionic Complex. Collect. Czech. Chem. Commun. 2008, 73, 1161. <>
  • Wang Chen, Huang Jiling: Styrene polymerization with half-sandwich titanium complexes bearing pendent cyclo-alkenyl groups. Euro Poly J 2006, 42, 3032. <>
  • Wang Chen, Liu Rucheng, Huang Jiling, Xiao Wei: Styrene polymerization with half-sandwich titanium complexes bearing pendent alkenyl groups: From atactic to syndiotactic. Journal of Molecular Catalysis A 2006, 258, 139. <>
  • Pinkas Jiří, Lyčka Antonín, Šindelář Pavel, Gyepes Róbert, Varga Vojtech, Kubišta Jiří, Horáček Michal, Mach Karel: Effects of substituents in cyclopentadienyltitanium trichlorides on electronic absorption and 47,49Ti NMR spectra and styrene polymerization activated by methylalumoxane. Journal of Molecular Catalysis A 2006, 257, 14. <>
  • Lukešová Lenka, Gyepes Róbert, Varga Vojtech, Pinkas Jiří, Horáček Michal, Kubišta Jiří, Mach Karel: Synthesis and Crystal Structures of Dinuclear Trichloro(tetramethylcyclopentadienyl)titanium Complexes. Collect. Czech. Chem. Commun. 2006, 71, 164. <>
  • Lukešová Lenka, Gyepes Róbert, Pinkas Jiří, Horáček Michal, Kubišta Jiří, Čejka Jiří, Mach Karel: Preparation and Crystal Structure of Bis(tert-butyltetramethylcyclopentadienyl)dichlorotitanium. Collect. Czech. Chem. Commun. 2005, 70, 1589. <>
  • Kubišta Jiřı́, Mach Karel, Lukešová Lenka, Horáček Michal, Štěpnička Petr, Gyepes Róbert, Cı́sařová Ivana: Irregular cyclization reactions in titanocenes bearing pendant double bonds. J Organomet Chem 2004, 689, 1919. <>
  • Qian Xianmiao, Huang Jiling, Qian Yanlong, Wang Chen: Syndiotactic polymerization of styrene catalyzed by alkenyl-substituted cyclopentadienyltitanium trichlorides. Appl. Organometal. Chem. 2003, 17, 277. <>
  • Horáček Michal, Štěpnička Petr, Kubišta Jiřı́, Cı́sařová Ivana, Petrusová Lidmila, Mach Karel: Reduction-induced double bond coordination and multiple CH activation in fully-substituted titanocenes bearing a pendant double bond or an eight-membered hydrocarbyl ansa-chain. J Organomet Chem 2003, 667, 154. <>
  • Arnold Polly L.: 20  Organometallic chemistry of monometallic species. Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem. 2002, 98, 369. <>