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Collect. Czech. Chem. Commun. 2001, 66, 363-381
https://doi.org/10.1135/cccc20010363

Unusual cis/trans Isomerism in Octahedral Nickel(II) Complexes with 1,4,8,11-Tetraazacyclotetradecane-1,8-bis(methylphosphonic Acid) as a Ligand

Jan Kotek, Pavel Vojtíšek, Ivana Císařová, Petr Hermann* and Ivan Lukeš

Department of Inorganic Chemistry, Faculty of Science, Charles University, Hlavova 2030, 128 40 Prague 2, Czech Republic

Crossref Cited-by Linking

  • Koucký Filip, Kotek Jan, Císařová Ivana, Havlíčková Jana, Kubíček Vojtěch, Hermann Petr: Transition metal complexes of cyclam with two 2,2,2-trifluoroethylphosphinate pendant arms as probes for 19F magnetic resonance imaging. Dalton Trans. 2023, 52, 12208. <https://doi.org/10.1039/D3DT01420G>
  • Blahut Jan, Benda Ladislav, Kotek Jan, Pintacuda Guido, Hermann Petr: Paramagnetic Cobalt(II) Complexes with Cyclam Derivatives: Toward 19F MRI Contrast Agents. Inorg. Chem. 2020, 59, 10071. <https://doi.org/10.1021/acs.inorgchem.0c01216>
  • Blahut Jan, Hermann Petr, Gálisová Andrea, Herynek Vít, Císařová Ivana, Tošner Zdeněk, Kotek Jan: Nickel(ii) complexes of N-CH2CF3 cyclam derivatives as contrast agents for 19F magnetic resonance imaging. Dalton Trans. 2016, 45, 474. <https://doi.org/10.1039/C5DT04138D>
  • Ševčík R., Vaněk J., Michalicová R., Lubal P., Hermann P., Santos I. C., Santos I., Campello M. P. C.: Formation and decomplexation kinetics of copper(ii) complexes with cyclen derivatives having mixed carboxylate and phosphonate pendant arms. Dalton Trans. 2016, 45, 12723. <https://doi.org/10.1039/C6DT01127F>
  • Svobodová Ivona, Havlíčková Jana, Plutnar Jan, Lubal Přemysl, Kotek Jan, Hermann Petr: Metal Complexes of 4,11‐Dimethyl‐1,4,8,11‐tetraazacyclotetradecane‐1,8‐bis(methylphosphonic acid) – Thermodynamic and Formation/Decomplexation Kinetic Studies. Eur J Inorg Chem 2009, 2009, 3577. <https://doi.org/10.1002/ejic.200900358>
  • Havlíčková Jana, Medová Hana, Vitha Tomáš, Kotek Jan, Císařová Ivana, Hermann Petr: Coordination properties of cyclam (1,4,8,11-tetraazacyclotetradecane) endowed with two methylphosphonic acid pendant arms in the 1,4-positions. Dalton Trans. 2008, 5378. <https://doi.org/10.1039/b803235a>
  • Piskula Z., Svobodová I., Lubal P., Lis S., Hnatejko Z., Hermann P.: Kinetic study of dissociation of Eu(III) complex with H8dotp (H8dotp = 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetrakis(methylphosphonic acid)). Inorganica Chimica Acta 2007, 360, 3748. <https://doi.org/10.1016/j.ica.2007.05.009>
  • Försterová Michaela, Svobodová Ivona, Lubal Přemysl, Táborský Petr, Kotek Jan, Hermann Petr, Lukeš Ivan: Thermodynamic study of lanthanide(iii) complexes with bifunctional monophosphinic acid analogues of H4dota and comparative kinetic study of yttrium(iii) complexes. Dalton Trans. 2007, 535. <https://doi.org/10.1039/B613404A>
  • Lubal P., Maleček J., Hermann P., Kotek J., Havel J.: Capillary electrophoretic separation and kinetic study of inert copper(II) complexes of 1,8-bis(methylphosphonate) derivative of cyclam. J Polyhedron 2006, 25, 1884. <https://doi.org/10.1016/j.poly.2005.12.004>
  • Svobodová Ivona, Lubal Přemysl, Plutnar Jan, Havlíčková Jana, Kotek Jan, Hermann Petr, Lukeš Ivan: Thermodynamic, kinetic and solid-state study of divalent metal complexes of 1,4,8,11-tetraazacyclotetradecane (cyclam) bearing two trans (1,8-)methylphosphonic acid pendant arms. Dalton Trans. 2006, 5184. <https://doi.org/10.1039/B603251F>
  • Vitha Tomáš, Kotek Jan, Rudovský Jakub, Kubíček Vojtěch, Císařová Ivana, Hermann Petr, Lukeš Ivan: Selective Protection of 1,4,8,11-Tetraazacyclotetradecane (Cyclam) in Position 1,4 with the Phosphonothioyl Group and Synthesis of a Cyclam-1,4-bis(methylphosphonic Acid). Crystal Structures of Several Cyclic Phosphonothioamides. Collect. Czech. Chem. Commun. 2006, 71, 337. <https://doi.org/10.1135/cccc20060337>
  • Kong Deyuan, Clearfield Abraham: Supramolecular Hydrogen-Bonded Frameworks from 6-Phosphonopyridine-2-carboxylic Acid and Transition Metal Ions. Crystal Growth & Design 2005, 5, 1263. <https://doi.org/10.1021/cg050015e>
  • Füzerová Silvia, Kotek Jan, Císařová Ivana, Hermann Petr, Binnemans Koen, Lukeš Ivan: Cyclam (1,4,8,11-tetraazacyclotetradecane) with one methylphosphonate pendant arm: a new ligand for selective copper(ii) binding. Dalton Trans. 2005, 2908. <https://doi.org/10.1039/b507062g>
  • Táborský Petr, Lubal Přemysl, Havel Josef, Kotek Jan, Hermann Petr, Lukeš Ivan: Thermodynamic and Kinetic Studies of Lanthanide(III) Complexes with H5do3ap (1,4,7,10-Tetraazacyclododecane-1,4,7-triacetic-10-(methylphosphonic Acid)), a Monophosphonate Analogue of H4dota. Collect. Czech. Chem. Commun. 2005, 70, 1909. <https://doi.org/10.1135/cccc20051909>
  • Kong, Medvedev Dmitri G., Clearfield Abraham: DOTP−Manganese and −Nickel Complexes:  from a Tetrahedral Network with 12-Membered Rings to an Ionic Phosphonate. Inorg. Chem. 2004, 43, 7308. <https://doi.org/10.1021/ic040076m>
  • Kotek Jan, Lubal Přemysl, Hermann Petr, Císařová Ivana, Lukeš Ivan, Godula Tomáš, Svobodová Ivona, Táborský Petr, Havel Josef: High Thermodynamic Stability and Extraordinary Kinetic Inertness of Copper(II) Complexes with 1,4,8,11‐Tetraazacyclotetradecane‐1,8‐bis(methylphosphonic acid): Example of a Rare Isomerism between Kinetically Inert Penta‐ and Hexacoordinated Copper(II) Complexes. Chemistry A European J 2003, 9, 233. <https://doi.org/10.1002/chem.200390017>
  • Fallis Ian A.: 19  Coordination chemistry of macrocyclic ligands. Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem. 2002, 98, 321. <https://doi.org/10.1039/B109662C>