Collect. Czech. Chem. Commun. 2000, 65, 963-970

Theory of Second- and Third-Order Reciprocal Derivative Chronopotentiometry for a Reversible Reaction

Shuping Bi*, Jian Chen, Xiaolan Xing and Jiong Yu

Chemistry Department, Nanjing University, Nanjing 210093, People Republic of China


Equations describing the second- and third-order reciprocal derivative chronopotentiometric curves, dt/dE vs E are deduced for a reversible reaction. Theoretical calculated values are verified experimentally.

Keywords: Reciprocal derivative chronopotentiometry; Reversible reaction; Polarography; Hanging mercury drop electrode; Electrochemistry.

References: 14 live references.