Collect. Czech. Chem. Commun. 2000, 65, 23-34

Synthesis and Characterization of Heterodinuclear Complexes Pentacarbonyl[(dimethylaminomethyl)ferrocene]molybdenum and Pentacarbonyl[(dimethylaminomethyl)ferrocene]tungsten

Ivan Pavlíka,*, Martin Pavlištaa, Klaus Jacobb, Claus Pietzschc, Tomáš Lébla and Jaromír Vinkláreka

a Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, CZ-532 10 Pardubice, Czech Republic
b Department of Inorganic Chemistry, Martin-Luther-University Halle-Wittenberg, D-06099 Halle, Germany
c Department of Applied Physics, Mining Academy Technical University, D-09596 Freiberg, Germany


(Dimethylaminomethyl)ferrocene (HFcR, R = CH2NMe2) reacts with Mo(CO)6 and W(CO)6 under substitution of one CO group and formation of the donor-acceptor complexes of the formula HFcR·M(CO)5 (M = Mo, W). These yellow microcrystalline derivatives were characterized by mass, UV-VIS, IR, NMR and Mössbauer spectroscopy.

Keywords: (Dimethylaminomethyl)ferrocene; Donor-acceptor complexes; Molybdenum; Tungsten; NMR spectroscopy; UV-VIS spectroscopy; IR spectroscopy; Mössbauer spectroscopy; Metallocenes; Ferrocenes; Carbonyl complexes.

References: 28 live references.