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Collect. Czech. Chem. Commun. 1999, 64, 2044-2060
https://doi.org/10.1135/cccc19992044

In situ Mössbauer Study of the Passive Layer Formed on the Iron Anode in Alkaline Electrolyte

Karel Bouzeka,* and Martin Nejezchlebab,c

a Department of Inorganic Technology, Prague Institute of Chemical Technology, Technická 5, 166 28 Prague 6, Czech Republic
b Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, Peléova 26, 160 00 Prague 6, Czech Republic
c Joint Laboratory of Mössbauer Spectroscopy, Faculty of Mathematics and Physics, Charles University, V Holešovičká ch 2, 180 00 Prague 8, Czech Republic

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  • Kerekeš Kamil, Hrnčiariková Lucia, Híveš Ján, Gál Miroslav: On the Mechanism of Electrochemical Transpassive Dissolution of Fe-Based Anodes in Binary Hydroxide Media. J. Electrochem. Soc. 2014, 161, C62. <https://doi.org/10.1149/2.075401jes>
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  • Híveš J., Mácová Z., Benová M., Bouzek K.: Comparison of Ferrate(VI) Synthesis in Eutectic NaOH–KOH Melts and in Aqueous Solutions. J. Electrochem. Soc. 2008, 155, E113. <https://doi.org/10.1149/1.2946716>
  • De Koninck Mathieu, Brousse Thierry, Bélanger Daniel: The electrochemical generation of ferrate at pressed iron powder electrodes: effect of various operating parameters. Electrochimica Acta 2003, 48, 1425. <https://doi.org/10.1016/S0013-4686(03)00020-3>
  • Jiang Jia-Qian, Lloyd Barry: Progress in the development and use of ferrate(VI) salt as an oxidant and coagulant for water and wastewater treatment. Water Research 2002, 36, 1397. <https://doi.org/10.1016/S0043-1354(01)00358-X>