Collect. Czech. Chem. Commun. 1999, 64, 1953-1965

Electrochemical Studies of the Complex (OC-6-22)-W(CO)3(dppm)2 at a Glassy Carbon Electrode in CH2Cl2

Ibrahim Shibl El-Hallag* and Amira Mahmoud Hassanien

Chemistry Department, Faculty of Science, Tanta University, Tanta, Egypt


Electrochemical behaviour of tricarbonylbis[methylenebis(diphenylphosphine)] tungsten has been studied by convolution-deconvolution voltammetry and chronopotentiometry with glassy carbon electrode in dichloromethane solution. Electrochemical parameters of the investigated system have been determined and confirmed by theoretical treatment and by the proposed electrode mechanism.

Keywords: Convolution-deconvolution voltammetry; Chronopotentiometry; Tungsten complexes; Phosphines; Electrochemistry.