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Collect. Czech. Chem. Commun. 1998, 63, 599-613

Michael Additions of Benzotriazole-Stabilized Carbanions. A Review

Alan R. Katritzky and Ming Qi

Center for Heterocyclic Compounds, Department of Chemistry, University of Florida, Gainesville, FL 32611-7200, U.S.A.

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  • Katritzky Alan R., Rachwal Stanislaw: Synthesis of Heterocycles Mediated by Benzotriazole. 1. Monocyclic Systems. Chem. Rev. 2010, 110, 1564. <>
  • Uhde Moritz, Ziegler Thomas: Reaction of N-Nitro-benzotriazole with Nucleophiles. Synthetic Communications 2010, 40, 3046. <>
  • Wang Xiaoxia, Li Zhifang, Zhu Xiangming, Mao Hui, Zou Xuefei, Kong Lichun, Li Xinsheng: Features and applications of reactions of α,β-unsaturated N-acylbenzotriazoles with amino compounds. Tetrahedron 2008, 64, 6510. <>
  • Uhde Moritz, Anwar Muhammad Usman, Ziegler Thomas: Reaction of N‐Nonaflyl and N‐Cyano‐Benzotriazoles with Enamines. Synthetic Communications 2008, 38, 881. <>
  • Kirschning Andreas, Kujat Christof, Luiken Silke, Schaumann Ernst: Small and Versatile – Formyl Anion and Dianion Equivalents. Eur J Org Chem 2007, 2007, 2387. <>
  • Dib Hicham H., Al‐Awadi Nouria A., Ibrahim Yehia A., El‐Dusouqui Osman M. E.: Gas‐phase thermolysis of benzotriazole derivatives: part 1—synthesis of α‐N(1)‐ and N(2)‐benzotriazolyl ketones and kinetics and mechanism of their gas‐phase pyrolysis. J of Physical Organic Chem 2004, 17, 267. <>
  • Katritzky Alan R., Rogovoy Boris V.: Benzotriazole: An Ideal Synthetic Auxiliary. Chemistry A European J 2003, 9, 4586. <>
  • Katritzky Alan R., Jain Ritu, Xu Yong-Jiang, Steel Peter J.: Novel Routes to 1,2,3,4-Tetrahydropyrrolo[1,2-a]pyrazines and 5,6,9,10,11,11a-Hexahydro-8H-pyrido[1,2-a]pyrrolo[2,1-c]pyrazines. J. Org. Chem. 2002, 67, 8220. <>
  • Katritzky Alan R.: The continuing magic of benzotriazole: An overview of some recent advances in synthetic methodology. Journal of Heterocyclic Chem 1999, 36, 1501. <>
  • KATRITZKY A. R., QI M.: ChemInform Abstract: Michael Additions of Benzotriazole‐Stabilized Carbanions. ChemInform 1998, 29. <>
  • Katritzky Alan R., Voronkov Michael V., Toader Dorin: Novel and Efficient Entry to γ-Aryl-Substituted γ,δ-Unsaturated Ketones, Amides, Nitriles, and Sulfones by Conjugate Additions of 2-Benzotriazolylethylsilanes. J. Org. Chem. 1998, 63, 9987. <>