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Collect. Czech. Chem. Commun. 1996, 61, 1285-1294
https://doi.org/10.1135/cccc19961285

The Dimeric Structure of Bis(1,3-Dimethylcyclopentadienyl)titanium(III) Chloride

Karel Macha, Vojtech Vargaa, Günter Schmidb, Jörg Hillerb and Ulf Thewaltb

a J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, 182 23 Prague 8, Czech Republic
b Universität Ulm, Sektion für Röntgen- und Elektronenbeugung, D-89069 Ulm, Germany

Crossref Cited-by Linking

  • Horno Estefanía del, Jiménez-Aparicio Reyes, Mena Miguel, Pérez-Redondo Adrián, Priego José Luis, Yélamos Carlos: Preparation of Dimeric Monopentamethylcyclopentadienyltitanium(III) Dihalides and Related Derivatives. Inorg. Chem. 2020, 59, 3740. <https://doi.org/10.1021/acs.inorgchem.9b03399>
  • Pinkas Jiří, Kubišta Jiří, Horáček Michal, Mach Karel, Varga Vojtech, Gyepes Róbert: Low-valent ansa-dimethylsilylene-, dimethylmethylene-bis(cyclopentadienyl) titanium compounds and ansa-titanium–magnesium complexes. Journal of Organometallic Chemistry 2019, 889, 15. <https://doi.org/10.1016/j.jorganchem.2019.03.003>
  • García-Castro María, García-Iriepa Cristina, del Horno Estefanía, Martín Avelino, Mena Miguel, Pérez-Redondo Adrián, Temprado Manuel, Yélamos Carlos: The Puzzling Monopentamethylcyclopentadienyltitanium(III) Dichloride Reagent: Structure and Properties. Inorg. Chem. 2019, 58, 5314. <https://doi.org/10.1021/acs.inorgchem.9b00437>
  • Křižan Martin, Honzíček Jan, Vinklárek Jaromír, Růžičková Zdeňka, Erben Milan: Titanocene(iii) pseudohalides: an ESR and structural study. New J. Chem. 2015, 39, 576. <https://doi.org/10.1039/C4NJ01404A>
  • Pinkas Jiří, Císařová Ivana, Gyepes Róbert, Kubišta Jiří, Horáček Michal, Mach Karel: Synthesis and Structure of Titanium(III) Bis(decamethyltitanocene) Oxide. Organometallics 2013, 32, 6306. <https://doi.org/10.1021/om400624y>
  • Semproni Scott P., Milsmann Carsten, Chirik Paul J.: Side-on Dinitrogen Complexes of Titanocenes with Disubstituted Cyclopentadienyl Ligands: Synthesis, Structure, and Spectroscopic Characterization. Organometallics 2012, 31, 3672. <https://doi.org/10.1021/om300156z>
  • Horáček Michal, Gyepes Róbert, Císařová Ivana, Kubišta Jiří, Pinkas Jiří, Mach Karel: Synthesis and structure of dinuclear dimethylene- or 1,4-phenylene-linked bis(decamethyltitanoceneoxide) (TiIII) complexes. Journal of Organometallic Chemistry 2010, 695, 2338. <https://doi.org/10.1016/j.jorganchem.2010.06.025>
  • Lukešová Lenka, Horáček Michal, Gyepes Róbert, Císařová Ivana, Štěpnička Petr, Kubišta Jiří, Mach Karel: Low-Valent Titanocene Products from Attempted Syntheses of Titanocene Bearing Dimethyl(3,3,3-trifluoropropyl)silyl Groups. Collect. Czech. Chem. Commun. 2005, 70, 11. <https://doi.org/10.1135/cccc20050011>
  • Lukešová Lenka, Gyepes Róbert, Pinkas Jiří, Horáček Michal, Kubišta Jiří, Čejka Jiří, Mach Karel: Preparation and Crystal Structure of Bis(tert-butyltetramethylcyclopentadienyl)dichlorotitanium. Collect. Czech. Chem. Commun. 2005, 70, 1589. <https://doi.org/10.1135/cccc20051589>
  • Kotov Vasily V, Fröhlich Roland, Kehr Gerald, Erker Gerhard: Synthesis and structural features of [(C5H4CMe2NMe2)2TiCl], a bis(cyclopentadienyl)Ti(III) complex with internal dimethylamino coordination. Journal of Organometallic Chemistry 2003, 676, 1. <https://doi.org/10.1016/S0022-328X(03)00221-3>
  • Mach Karel, Gyepes Róbert, Horáček Michal, Petrusová Lidmila, Kubišta Jiří: Linear Dimerization of Terminal Alkynes by Bis(tetramethylphenylcyclopentadienyl)titanium-Magnesium Hydride and Acetylide Complexes. Collect. Czech. Chem. Commun. 2003, 68, 1877. <https://doi.org/10.1135/cccc20031877>
  • Horáček Michal, Štěpnička Petr, Gentil Sébastien, Fejfarová Karla, Kubišta Jiřı́, Pirio Nadine, Meunier Philippe, Gallou Fabrice, Paquette Leo A, Mach Karel: Syntheses and properties of some exo,exo-bis(isodicyclopentadienyl)titanium low-valent complexes. Journal of Organometallic Chemistry 2002, 656, 81. <https://doi.org/10.1016/S0022-328X(02)01562-0>
  • Horáček Michal, Kupfer Volkmar, Thewalt Ulf, Polášek Miroslav, Mach Karel: Synthesis and structures of paramagnetic binuclear (η8-1,4-bis(trimethylsilyl)cyclooctatetraenide)titanium(III) chlorides. Journal of Organometallic Chemistry 1999, 579, 126. <https://doi.org/10.1016/S0022-328X(98)01213-3>
  • Langmaier Jan, Samec Zdeněk, Varga Vojtěch, Horáček Michal, Mach Karel: Substituent effects in cyclic voltammetry of titanocene dichlorides. Journal of Organometallic Chemistry 1999, 579, 348. <https://doi.org/10.1016/S0022-328X(99)00025-X>
  • Horáček Michal, Kupfer Volkmar, Müller Bernhard, Thewalt Ulf, Mach Karel: Reactions of (trimethylsilyl)tetramethylcyclopentadiene with (benzene)titanium(II) bis(tetrachloroaluminate). Crystal structures of [C5Me4(SiMe3)]Ti(AlCl4)2 and {[C5Me4(SiMe3)]Ti(AlCl4)(μ-Cl)}2. Journal of Organometallic Chemistry 1998, 552, 75. <https://doi.org/10.1016/S0022-328X(97)00581-0>
  • Varga Vojtech, Hiller Jörg, Gyepes Róbert, Polášek Miroslav, Sedmera Petr, Thewalt Ulf, Mach Karel: Synthesis, crystal structures and some properties of dimethylsilylene-bridged ansa-permethyltitanocene [Ti(IV), (III) and (II)] complexes. Journal of Organometallic Chemistry 1997, 538, 63. <https://doi.org/10.1016/S0022-328X(96)06917-3>