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Collect. Czech. Chem. Commun. 1996, 61, 1285-1294
https://doi.org/10.1135/cccc19961285

The Dimeric Structure of Bis(1,3-Dimethylcyclopentadienyl)titanium(III) Chloride

Karel Macha, Vojtech Vargaa, Günter Schmidb, Jörg Hillerb and Ulf Thewaltb

a J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, 182 23 Prague 8, Czech Republic
b Universität Ulm, Sektion für Röntgen- und Elektronenbeugung, D-89069 Ulm, Germany

Crossref Cited-by Linking

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  • Horno Estefanía del, Jiménez-Aparicio Reyes, Mena Miguel, Pérez-Redondo Adrián, Priego José Luis, Yélamos Carlos: Preparation of Dimeric Monopentamethylcyclopentadienyltitanium(III) Dihalides and Related Derivatives. Inorg. Chem. 2020, 59, 3740. <https://doi.org/10.1021/acs.inorgchem.9b03399>
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  • García-Castro María, García-Iriepa Cristina, del Horno Estefanía, Martín Avelino, Mena Miguel, Pérez-Redondo Adrián, Temprado Manuel, Yélamos Carlos: The Puzzling Monopentamethylcyclopentadienyltitanium(III) Dichloride Reagent: Structure and Properties. Inorg. Chem. 2019, 58, 5314. <https://doi.org/10.1021/acs.inorgchem.9b00437>
  • Křižan Martin, Honzíček Jan, Vinklárek Jaromír, Růžičková Zdeňka, Erben Milan: Titanocene(iii) pseudohalides: an ESR and structural study. New J. Chem. 2015, 39, 576. <https://doi.org/10.1039/C4NJ01404A>
  • Pinkas Jiří, Císařová Ivana, Gyepes Róbert, Kubišta Jiří, Horáček Michal, Mach Karel: Synthesis and Structure of Titanium(III) Bis(decamethyltitanocene) Oxide. Organometallics 2013, 32, 6306. <https://doi.org/10.1021/om400624y>
  • Semproni Scott P., Milsmann Carsten, Chirik Paul J.: Side-on Dinitrogen Complexes of Titanocenes with Disubstituted Cyclopentadienyl Ligands: Synthesis, Structure, and Spectroscopic Characterization. Organometallics 2012, 31, 3672. <https://doi.org/10.1021/om300156z>
  • Horáček Michal, Gyepes Róbert, Císařová Ivana, Kubišta Jiří, Pinkas Jiří, Mach Karel: Synthesis and structure of dinuclear dimethylene- or 1,4-phenylene-linked bis(decamethyltitanoceneoxide) (TiIII) complexes. Journal of Organometallic Chemistry 2010, 695, 2338. <https://doi.org/10.1016/j.jorganchem.2010.06.025>
  • Klahn Marcus, Arndt Perdita, Spannenberg Anke, Gansäuer Andreas, Rosenthal Uwe: Menthyl-Substituted Group 4 Metallocene Dihalides. Organometallics 2008, 27, 5846. <https://doi.org/10.1021/om800605x>
  • Gansäuer Andreas, Barchuk Andriy, Keller Florian, Schmitt Martin, Grimme Stefan, Gerenkamp Mareike, Mück-Lichtenfeld Christian, Daasbjerg Kim, Svith Heidi: Mechanism of Titanocene-Mediated Epoxide Opening through Homolytic Substitution. J. Am. Chem. Soc. 2007, 129, 1359. <https://doi.org/10.1021/ja067054e>
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  • Kotov Vasily V, Fröhlich Roland, Kehr Gerald, Erker Gerhard: Synthesis and structural features of [(C5H4CMe2NMe2)2TiCl], a bis(cyclopentadienyl)Ti(III) complex with internal dimethylamino coordination. Journal of Organometallic Chemistry 2003, 676, 1. <https://doi.org/10.1016/S0022-328X(03)00221-3>
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