Collect. Czech. Chem. Commun. 1994, 59, 1616-1619

Intercalation of Anhydrous Vanadyl Phosphate with Aliphatic Alcohol Mixtures

Ludvík Beneša, Vítězslav Zimaa, Jaroslava Kalousováb and Jiří Votinskýb

a Joint Laboratory of Solid State Chemistry, Academy of Sciences of the Czech Republic and University of Pardubice, 530 09 Pardubice, Czech Republic
b Department of General and Inorganic Chemistry, University of Pardubice, 532 10 Pardubice, Czech Republic


The intercalation of VOPO4 with the mixtures of alcohols (ethanol and 1-butanol, methanol and ethanol, methanol and 1-propanol, methanol and 1-butanol) have been studied. The dependence of alcohols content and interlayer distance of the intercalates formed on composition of the starting mixtures of alcohols has been found. The ability of VOPO4 to form mixed intercalates with alcohols is discussed.