Collect. Czech. Chem. Commun. 1994, 59, 1311-1318
https://doi.org/10.1135/cccc19941311

Sorption of Cadmium and Lead by Chelating Ion Exchangers Ostsorb OXIN, Ostsorb DETA, and Ostsorb DTTA

Ladislav Svoboda and Petr Vořechovský

Department of Inorganic Technology, University of Pardubice, 532 10 Pardubice, Czech Republic

Abstract

The properties of cellulose chelating ion exchangers Ostsorb have been studied in the sorption of cadmium and lead from aqueous solutions. The Cd(II) and Pb(II) ions are trapped by the Ostsorb OXIN and Ostsorb DETA ion exchangers most effectively in neutral and alkaline media but at these conditions formation of stable hydrolytic products of both metals competes with the exchange equilibria. From this point of view, Ostsorb DTTA appears to be a more suitable sorbent since it traps the Pb(II) and Cd(II) ions in acidic media already. Chloride ions interfere with the sorption of the two metals by Ostsorb DTTA whereas the ionic strength adjusted by the addition of sodium perchlorate does not affect the exchange capacity of this ion exchanger.