Collect. Czech. Chem. Commun.
1994, 59, 453-456
https://doi.org/10.1135/cccc19940453
Diels-Alder Self-Addition and Retroaddition of (Cyclopentadienylmethyl)triethoxysilane and Synthesis of its Permethylated Analogue
Jan Čermák, Magdalena Kvíčalová, Jan Schraml and Martin Čapka
Institute of Chemical Process Fundamentals, Academy of Sciences of the Czech Republic, 165 02 Prague 6-Suchdol, Czech Republic
Abstract
Reversible Diels-Alder self-addition of (cyclopentadienylmethyl)triethoxysilane hampering its use as functionalizing agent and the synthesis of a new silica functionalizing agent, (tetramethylcyclopentadienylmethyl)triethoxysilane, are described.
