Collect. Czech. Chem. Commun.
1994, 59, 2501-2510
https://doi.org/10.1135/cccc19942501
Radical Addition of Triethylamine and 1-Methylpiperidine to Tetrafluoroethene
František Hampl and František Liška
Department of Organic Chemistry, Prague Institute of Chemical Technology, 166 28 Prague 6, Czech Republic
Abstract
The radical addition of triethylamine (I) and 1-methylpiperidine (II) to tetrafluoroethene (III) initiated by UV and γ-60Co radiation produces tertiary amines containing 1,1,2,2-tetrafluoroethyl group at α-position (1 : 1 adducts) and/or at α,α'-positions (1 : 2 adducts). 1 : 2 Telomers, 1 : 3 adducts, and products formed by recombination of 1 : 1 adduct radicals represent minor products.
