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Collect. Czech. Chem. Commun. 1993, 58, 2090-2120

Eleven-Vertex Polyhedral Dicarbaplatinaborane Chemistry. Aspects of the Chemistry of Some closo-Structured {1,2,3-PtC2B8} Species and Some Related Compounds

John D. Kennedya, Bohumil Štíbrb, Tomáš Jelínekb, Xavier L. R. Fontainea and Mark Thornton-Petta

a School Of Chemistry, University of Leeds, Leeds LS2 9JT, England
b Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, 25068 Řež near Prague, Czech Republic

Crossref Cited-by Linking

  • Kennedy Robert D., Kennedy John D.: The contrarotational fluxionality of [3,3-(PMe2Ph)2-closo-3,1,2-PtC2B9H11] and related species. Dalton Trans. 2015, 44, 9620. <>
  • Dolgushin Fedor M., Kostukovich Alexandr Yu, Pisareva Irina V., Konoplev Vitalii E., Chizhevsky Igor T.: Cluster rearrangement of isonido-ruthenacarboranes [1-(η6-1,4-Me2C6H4)-3(6)-Cl-isonido-1,2,4-RuC2B8H9] under thermal conditions. Journal of Organometallic Chemistry 2014, 751, 493. <>
  • Bould Jonathan, Harrington Ross W., Clegg William, Kennedy John D.: Nine-vertex metallaborane chemistry. Preparation and characterisation of [1,1,1-(PMe3)2H-isocloso-IrB8H7-8-X], where X = H or Cl. Journal of Organometallic Chemistry 2012, 721-722, 155. <>
  • Bould Jonathan, Laromaine Anna, Bullen Neil J., Viñas Clara, Thornton-Pett Mark, Sillanpää Reijo, Kivekäs Raikko, Kennedy John D., Teixidor Francesc: Borane reaction chemistry. Alkyne insertion reactions into boron-containing clusters. Products from the thermolysis of [6,9-(2-HCC–C5H4N)2-arachno-B10H12]. Dalton Trans. 2008, 1552. <>
  • Macías Ramón, Bould Jonathan, Holub Josef, Kennedy John D., Štíbr Bohumil, Thornton-Pett Mark: Polyhedral metallaheteroborane chemistry. Synthesis, spectroscopy, structure and dynamics of eleven-vertex {RhNB9} and {PtCB9} metallaheteroboranes. Dalton Trans. 2007, 2885. <>
  • Dou Jianmin, Guo Qingliang, Wu Libin, Li Dacheng, Wang Daqi, Wang Huaisheng, Li Yantuan: Synthesis, crystal structure and electrochemical properties of threeisocloso eleven-vertex ferrocenecarboxylate ruthenaborane clusters. Appl. Organometal. Chem. 2006, 20, 193. <>
  • Guo Qingliang, Dou Jianmin, Wu Libin, Li Dacheng, Wang Daqi, Wang Huaisheng: Synthesis and Crystal Structures of Twoexo-Cyclic 11-Vertexisocloso Ruthenaborane Clusters [(PPh3)(p-ClPhCO2)2RuB10H8] and [(PPh3)2Ru(PPh3)(p-ClPhCO2)RuB10H9]·0.5C5H12·H2O. Z. anorg. allg. Chem. 2006, 632, 1591. <>
  • Bould Jonathan, Kilner Colin A., Kennedy John D.: The capture of dioxygen, carbon monoxide and sulfur dioxide by [(PMe2Ph)4Pt2B10H10]. Dalton Trans. 2005, 1574. <>
  • Franken Andreas, Kilner Colin A, Thornton-Pett Mark, Kennedy John D: Polyhedral monocarbaborane chemistry. Journal of Organometallic Chemistry 2002, 657, 180. <>
  • Ormsby Daniel L, Greatrex Robert, Štı́br Bohumil, Kennedy John D: Bond rotamers and calculated 11B-NMR chemical shifts in boron-containing cluster chemistry. Some effects in the {nido-7,8,10-PC2B8} system. Journal of Organometallic Chemistry 2000, 614-615, 61. <>
  • Bown Mark, Grüner Bohumı́r, Štı́br Bohumil, Fontaine Xavier L.R., Thornton-Pett Mark, Kennedy John D.: Eleven-vertex polyhedral metalladicarbaborane chemistry. Reactions of neutral nido-5,6-C2B8H12 and the [nido-6,9-C2B8H10]2− anion to give formally closo isomeric 1-(arene) and 1-(cyclopentadiene)-1,2,4- and 1,2,3-metalladicarbaundecaboranes, and some substituent chemistry. Chiral separations, and crystal and molecular structures of [5-Br-1-(η6-C6Me6)-1,2,4-RuC2B8H9] and [2-Me-1-(η5-C5Me5)-1,2,3-RhC2B8H9]. Journal of Organometallic Chemistry 2000, 614-615, 269. <>
  • Holub Josef, Ormsby Daniel L, Kennedy John D, Greatrex Robert, Štı́br Bohumil: Phosphacarborane chemistry. New cluster isomers in the eleven-vertex nido-phosphadicarbaborane series: synthesis of the nido phosphadicarbaboranes 7,8,11-PC2B8H11, [7,8,11-PC2B8H10]− and 7-Ph-7,8,10-PC2B8H10. Inorganic Chemistry Communications 2000, 3, 178. <>
  • Bould Jonathan, Cooke Paul A., Dörfler Udo, Kennedy John D., Barton Lawrence, Rath Nigam P., Thornton-Pett Mark: B-frame-supported bimetallics. Isoelectronic arachno-structured [(PMe2Ph)4Pd2B8H10] and closo-structured [(PMe3)4(CO)2Ir2B8H8]. Inorganica Chimica Acta 1999, 285, 290. <>
  • Bould Jonathan, Clegg William, Teat Simon J., Barton Lawrence, Rath Nigam P., Thornton-Pett Mark, Kennedy John D.: An approach to megalo-boranes. Mixed and multiple cluster fusions involving iridaborane and platinaborane cluster compounds. Crystal structure determinations by conventional and synchrotron methods. Inorganica Chimica Acta 1999, 289, 95. <>
  • Kim Young-hee, Cooke Paul A, Greatrex Robert, Kennedy John D, Thornton-Pett Mark: B-frame supported bimetallics. [(PMe2ph)2PtB9H11Ru(η6-isoPrC6H4Me)] and [(PMe2ph)2PtB9H9Ru(η6-isoPrC6H4Me)]; an interesting pair of electron-deficient nido and closo geometries1We are pleased to be able to dedicate this paper to Ken Wade, whose Rules have been instrumental and inspirational in the development of boron-containing cluster chemistry over the quarter century since their original formulation.1. Journal of Organometallic Chemistry 1998, 550, 341. <>
  • Jelínek Tomáŝ, Kennedy John D., Štíbr Bohumil, Thornton-Pett Mark: Macropolyhedral boron-containing cluster chemistry. An interesting angular change in relative subcluster orientation in the oxidative protonation of [S2B17H18]− to [S2B17H17]. Inorganic Chemistry Communications 1998, 1, 179. <>
  • O'Connell Donnacha, Patterson Jennifer C., Spalding Trevor R., Ferguson George, Gallagher John F., Li Yiwei, Kennedy John D., Macías Ramón, Thornton-Pett Mark, Holub Josef: Conformational polymorphism and fluxional behaviour of M(PR3)2units in closo-twelve-atom metallaheteroboranes with MX2B9(X = C or As) and MZB10cages (Z = S, Se or Te). J. Chem. Soc., Dalton Trans. 1996, 3323. <>
  • Jelínek Tomáš, Kennedy John D., Štíbr Bohumil, Thornton-Pett Mark: Macropolyhedral boron-containing cluster chemistry. The eighteen-vertex monocarbaborane [(Me3CNH2)CB17H18(CN)]. J. Chem. Soc., Chem. Commun. 1995, 2407. <>
  • Holub Josef, Štíbr Bohumil, Janoušek Zbyněk, Kennedy John D., Thornton-Pett Mark: Ten-vertex polyhedral dicarbaborane chemistry: new positional isomers of cluster constituents in the ten-vertex arachnodicarbaborane family: the patent [arachno-5,10-C2B8H13]− anion and the isomeric ligand derivatives exo-9-L-arachno-5,6-C2B8H12 and exo-6-L-arachno-5 ,10-C2B8H12. Inorganica Chimica Acta 1994, 221, 5. <>
  • Štíbr Bohumil, Kennedy John D., Drdáková Eva, Thornton-Pett Mark: Nine-vertex polyhedral iridamonocarbaborane chemistry. Products of thermolysis of [(CO)(PPh3)2IrCB7H8] and emerging alternative cluster-geometry patterns. J. Chem. Soc., Dalton Trans. 1994, 229. <>
  • Holub Josef, Kennedy John D., Jelínek Tomáš, Štíbr Bohumil: Polyhedral carbathiaborane chemistry. Ten-vertex nido and arachno, eleven-vertex nido, and eight-vertex hypho families of carbathiaboranes. J. Chem. Soc., Dalton Trans. 1994, 1317. <>