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Collect. Czech. Chem. Commun. 1993, 58, 2936-2943

Asymmetric Cobaltacarboranes [6,6'-μ-R-S(1,7-C2B9H10)2-2-Co] with a Monosulfur Bridge between Ligands and HPLC Resolution of the Enantiomers

Jaromír Plešeka, Bohumír Grünera, Jiří Fuseka and Hana Votavováb

a Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, 25068 Řež near Prague, Czech Republic
b Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 166 10 Prague 6, Czech Republic

Crossref Cited-by Linking

  • Horáková Hana, Grüner Bohumír, Vespalec Radim: Emerging subject for chiral separation science: Cluster boron compounds. Chirality 2011, 23, 307. <>
  • Krasnov V. P., Demin A. M., Levit G. L., Grishakov A. N., Sadretdinova L. Sh., Ol’shevskaya V. A., Glukhov I. V., Kalinin V. N., Charushin V. N.: Determination of enantiomeric purity of 1-substituted 3-amino-1,2-dicarba-closo-dodecaboranes by HPLC on chiral stationary phases. Russ Chem Bull 2008, 57, 2535. <>
  • Horáková Hana, Vespalec Radim: Chiral separability of hydrophobic boron cluster anions with native cyclodextrins in water–methanol background electrolytes. Electrophoresis 2007, 28, 3639. <>
  • Slavı́c̆ek Viktor, Grüner Bohumı́r, Vespalec Radim: Exploration of the electrophoretic behaviour of borane cluster anions and of the capability of capillary electrophoresis to separate them chirally. Journal of Chromatography A 2003, 984, 121. <>
  • Plešek Jaromı́r, Grüner Bohumı́r, Cı́sařová Ivana, Báča Jiřı́, Selucký Pavel, Rais Jiřı́: Functionalized cobalt bis(dicarbollide) ions as selective extraction reagents for removal of M2+ and M3+ cations from nuclear waste, crystal and molecular structures of the [8,8′-μ-CIP(O)(O)2(1,2-C2B9H10)2-3,3′-Co]HN(C2H5)3 and [8,8′-μ-Et2NP(O)(O)2(1,2-C2B9H10)2-3,3′-Co](HN(CH3)3). Journal of Organometallic Chemistry 2002, 657, 59. <>
  • Plešek Jaromír, Císařová Ivana, Bačkovský Jaroslav: Cobalt Bis(1,2-dicarbollide) Ion with a Disulfur Bridge Between B(8) and B(8'). X-Ray Structure, Absolute Configuration of One Enantiomer, and Implications. Collect. Czech. Chem. Commun. 2002, 67, 569. <>
  • Bown Mark, Grüner Bohumı́r, Štı́br Bohumil, Fontaine Xavier L.R., Thornton-Pett Mark, Kennedy John D.: Eleven-vertex polyhedral metalladicarbaborane chemistry. Reactions of neutral nido-5,6-C2B8H12 and the [nido-6,9-C2B8H10]2− anion to give formally closo isomeric 1-(arene) and 1-(cyclopentadiene)-1,2,4- and 1,2,3-metalladicarbaundecaboranes, and some substituent chemistry. Chiral separations, and crystal and molecular structures of [5-Br-1-(η6-C6Me6)-1,2,4-RuC2B8H9] and [2-Me-1-(η5-C5Me5)-1,2,3-RhC2B8H9]. Journal of Organometallic Chemistry 2000, 614-615, 269. <>
  • Plešek Jaromı́r: The age of chiral deltahedral borane derivatives. Inorganica Chimica Acta 1999, 289, 45. <>
  • Grüner Bohumı́r, Holub Josef, Plešek Jaromı́r, Vaněk Tomáš, Votavová Hana: High-performance liquid chromatographic enantiomeric resolution in the ten-vertex carborane series. Journal of Chromatography A 1998, 793, 249. <>
  • Grüner Bohumir, Cisařová Ivana, Franken Andreas, Plešek Jaromı́r: Resolution of the [6,6′-μ-(CH3)2P-(1,7-(C2B9H10)2)-2-Co] bridged cobaltacarborane to enantiomers pure by chiral HPLC, circular dichroism spectra and absolute configurations by X-ray diffraction. Tetrahedron: Asymmetry 1998, 9, 79. <>
  • Grüner Bohumir, Plzák Zbyněk: High-performance liquid chromatographic separations of boron-cluster compounds. Journal of Chromatography A 1997, 789, 497. <>