Collect. Czech. Chem. Commun. 1992, 57, 1899-1904

Preparation and Structural Characterization of Cyanatocopper(II) Complexes with Substituted Piperidines

Anna Mašlejová, Mária Hvastijová and Jiří Kohout

Department of Inorganic Chemistry, Slovak Technical University, 812 37 Bratislava


Coordination geometry of the newly prepared complex compounds of [Cu(NCO)2L2] type (L is piperidine, 2-methylpiperidine, 4-methylpiperidine and 2,6-dimethylpiperidine) was investigated at room temperature utilizing the results of infrared, electronic and ESR spectra and magnetic moments. All complexes show a tetragonal arrangement with small axial interaction depending on steric properties of the piperidine ligand given.