Collect. Czech. Chem. Commun. 1992, 57, 1291-1298
https://doi.org/10.1135/cccc19921291

Relative Reactivities of 1,1,1-Trichloroethane and 1,1,1-Trichlorotrifluoroethane in Competitive Addition Reactions

František Adámek, Milan Hájek and Zbyněk Janoušek

Institute of Chemical Process Fundamentals, Czechoslovak Academy of Sciences, 165 02 Prague 6-Suchdol

Individual author index pages


Other CCCC articles of these authors

  • Ivan Šnajdr, Zbyněk Janoušek and Martin Kotora
    Synthesis of novel C-(o-carboranyl)-2-deoxy-D-ribose conjugates
    Symposium Series 2011, Vol. 12, pp. 465–466 [Abstract]
    Published online 2015-08-20 10:24:38
  • Radim Dostál*, Michael G. S. Londesborough*, Magdalena Kvíčalová, Jan Macháček, Ivana Císařová and Zbyněk Janoušek
    Incremental iodination of the eight-vertex closo monocarborane anion [closo-1-CB7H8]: Preparation and characterization of [closo-1-CB7H5-6,7,8-I3] and [closo-1-CB7H2-2,3,4,6,7,8-I6], and the synthesis of the first eight-vertex C-methylated carborane anion [1-CH3-closo-1-CB7H4-6,7,8-I3]
    2010, Vol. 75, Issue 9, pp. 931–947 [Abstract]
  • Bryan Ringstrand*, Devon Bateman, Richard K. Shoemaker and Zbyněk Janoušek*
    Improved synthesis of [closo-1-CB9H10] anion and new C-substituted derivatives
    2009, Vol. 74, Issue 3, pp. 419–431 [Abstract]
  • Zbyněk Janoušek, Cameron L. Hilton, Peter J. Schreiber and Josef Michl*
    C-Halogenation of the closo-[CB11H12]- Anion
    2002, Vol. 67, Issue 7, pp. 1025–1034 [Abstract]
  • Josef Holub, Tomáš Jelínek and Zbyněk Janoušek*
    New Multigram-Scale Preparation of 1,10-Dicarba-closo-decaborane
    2002, Vol. 67, Issue 7, pp. 949–952 [Abstract]
  • Zbyněk Janoušek*, Piotr Kaszynski, John D. Kennedy and Bohumil Štíbr
    NMR Assignments of [6-R-nido-5,6-C2B8H10]- Anions (where R = H, Me, and n-C6H13). An Irreversible 5 → 6 Alkyl Migration via a B9 Vertex-Swing Mechanism
    1999, Vol. 64, Issue 6, pp. 986–992 [Abstract]
  • Bohumil Štíbr*, Zbyněk Janoušek, Matthew Trammell, Bohumír Grüner and Zbyněk Plzák
    Oxidation of the [nido-6,9-C2B8H10]2- Anion - An Alternative Source of the 1,6- and 1,10-Dicarba-closo-decaboranes(10)
    1999, Vol. 64, Issue 6, pp. 971–976 [Abstract]
  • Milan Hájek
    Microwave Activation of Homogeneous and Heterogeneous Catalytic Reactions
    1997, Vol. 62, Issue 2, pp. 347–354 [Abstract]
  • Milan Hájek, Martin Kotora, František Adámek, Reg Davis, Cecile Fischer and Warren A. C. Joshu
    Catalyst Effects on the Stereoselectivity of Addition of Tetrachloromethane to 1,3-Cyclohexadiene
    1996, Vol. 61, Issue 5, pp. 774–777 [Abstract]
  • Martin Kotora, Milan Hájek and Christian Döbler
    Addition of Tetrachloromethane to Styrene Catalyzed by Copper-Chiral Amine Complexes
    1992, Vol. 57, Issue 12, pp. 2622–2628 [Abstract]
  • Martin Kotora and Milan Hájek
    Addition of Tetrachloromethane to 1,5-Hexadiene
    1992, Vol. 57, Issue 2, pp. 393–396 [Abstract]
  • Milan Hájek, Přemysl Šilhavý and Božena Špirková
    Reactivity of substituted styrenes in the catalytic addition reaction with the trichloromethyl radical
    1990, Vol. 55, Issue 12, pp. 2949–2955 [Abstract]
  • Robert Ponec and Milan Hájek
    Influence of the solvent on the transmission of polar effects in free radical reactions. A theoretical study
    1988, Vol. 53, Issue 11, pp. 2714–2721 [Abstract]
  • Milan Hájek, Alena Horská, Petr Trška, Luděk Vodička, Douglas J. Raber, Brent L. Podlogar and Joop A. Peters
    Halogen substituted adamantanones. Structural studies with lanthanide shift reagents
    1988, Vol. 53, Issue 1, pp. 97–109 [Abstract]
  • Zdeněk Vít and Milan Hájek
    Addition of esters of chloroacetic acids to 1,3-butadiene catalysed by copper complexes
    1987, Vol. 52, Issue 5, pp. 1280–1284 [Abstract]
  • Robert Ponec, Štěpán Krupička and Milan Hájek
    MO analysis of chemically interacting systems. Reaction of hydrogen abstraction by free radicals
    1987, Vol. 52, Issue 3, pp. 547–554 [Abstract]
  • Bohumil Štíbr, Zbyněk Janoušek, Jaromír Plešek, Tomáš Jelínek and Stanislav Heřmánek
    Arachno-6,9-C2B8H14 dicarbaborane and its 1- and 5-monohalogenated derivatives
    1987, Vol. 52, Issue 1, pp. 103–112 [Abstract]
  • Bohumil Štíbr, Zbyněk Janoušek, Karel Baše, Stanislav Heřmánek, Jaromír Plešek and Inessa A. Zakharova
    Synthesis and structure of μ-6,9-metalla-bis(ligand)-6,9-dicarba-nido-decarboranes(10) from the [6,9-C2B8H10]2- anion
    1984, Vol. 49, Issue 8, pp. 1891–1894 [Abstract]
  • Jan Tříska, Luděk Vodička, Eugenijus P. Butkus and Milan Hájek
    Beckmann rearrangement of adamantanone oxime as a route to ditopic and tritopic secondarily substituted adamantane derivatives
    1984, Vol. 49, Issue 8, pp. 1774–1779 [Abstract]
  • Bohumil Štíbr, Zbyněk Janoušek, Karel Baše, Jaromír Plešek, Konstantin A. Solntsev, Lev A. Butman, Igor I. Kuznetsov and Nikolai T. Kuznetsov
    Synthesis of ten-vertex closo-metallacarbaboranes from 4-CB8H14
    1984, Vol. 49, Issue 7, pp. 1660–1664 [Abstract]
  • Robert Ponec, Milan Hájek and Jaroslav Málek
    PMO treatment of structure-reactivity relationships. Polar effects in the free radical addition reactions
    1983, Vol. 48, Issue 9, pp. 2469–2472 [Abstract]
  • Milan Hájek and Přemysl Šilhavý
    Redox chain addition of chloroform to 1-alkenes catalysed by copper complexes
    1983, Vol. 48, Issue 6, pp. 1710–1717 [Abstract]
  • Zdeněk Kafka, Luděk Vodička and Milan Hájek
    Oxidation of triamantane by sulphuric acid
    1983, Vol. 48, Issue 4, pp. 1074–1076 [Abstract]
  • Zbyněk Janoušek, Jaromír Plešek, Bohumil Štíbr and Stanislav Heřmánek
    Synthesis and structure of iso-C4B18H22
    1983, Vol. 48, Issue 1, pp. 228–231 [Abstract]
  • Zbyněk Janoušek, Jaromír Plešek, Stanislav Heřmánek, Karel Baše, Lee J. Todd and W. F. Wright
    Synthesis and characteristics of sulfur interligand bridge-derivatives and of some S-substituted compounds in the (C2B9H11)2Co- series. Conformations of (C2B9H11)2Mx- metallocarboranes
    1981, Vol. 46, Issue 11, pp. 2818–2833 [Abstract]
  • Robert Ponec, Milan Hájek and Jaroslav Málek
    PMO-treatment of the structure-reactivity relationships in free radical addition reactions of cycloalkenes
    1981, Vol. 46, Issue 10, pp. 2524–2530 [Abstract]
  • Gustav Šebor, Salvador Reynoso, Milan Hájek, Otto Weisser and Jiří Mostecký
    Study of hydrogenation of petroleum asphaltenes
    1981, Vol. 46, Issue 2, pp. 409–418 [Abstract]
  • Milan Hájek, Přemysl Šilhavý and Jaroslav Málek
    Catalytic activity of copper oxides and chlorides in the redox chain addition of tetrachloromethane to styrene
    1980, Vol. 45, Issue 12, pp. 3502–3509 [Abstract]
  • Milan Hájek, Přemysl Šilhavý and Jaroslav Málek
    Metal-oxide induced redox chain addition of tetrachloromethane to a carbon-carbon double bond
    1980, Vol. 45, Issue 12, pp. 3488–3501 [Abstract]
  • Luděk Vodička, Jan Tříska and Milan Hájek
    Synthesis, separation, and identification of 4-bromoadamantan-2-one stereoisomers
    1980, Vol. 45, Issue 10, pp. 2670–2674 [Abstract]
  • Milan Hájek and Jaroslav Málek
    Reactivity of cycloalkenes in the radical addition reaction with ethyl cyanoacetate
    1980, Vol. 45, Issue 7, pp. 1940–1949 [Abstract]
  • Jaromír Plešek, Zbyněk Janoušek and Stanislav Heřmánek
    Synthesis and properties of some icosahedral carborane B,B'-dithiols
    1980, Vol. 45, Issue 6, pp. 1775–1779 [Abstract]
  • Milan Hájek and Jaroslav Málek
    Catalytic activity of cupric oxide in addition reactions of alkyl cyanoacetates with 1-alkenes
    1979, Vol. 44, Issue 12, pp. 3695–3704 [Abstract]
  • Milan Hájek, Přemysl Šilhavý and Jaroslav Málek
    Radical cyclisation reactions of ketones with alkenes initiated by silver(II) and lead(IV) oxides
    1979, Vol. 44, Issue 8, pp. 2393–2400 [Abstract]
  • Milan Hájek, Božena Špirková and Jaroslav Málek
    Radical addition of lactones to 1-alkenes initiated by cupric oxide
    1979, Vol. 44, Issue 5, pp. 1608–1612 [Abstract]
  • František Skácel, Milan Hájek, František Liška, Petr Trška and Zbyněk Ksandr
    Application of shift reagents in 1H and 19F NMR spectroscopy. Interactions with chlorofluoroalkanols C3, C4
    1979, Vol. 44, Issue 5, pp. 1440–1447 [Abstract]
  • Milan Hájek, Gustav Šebor, Ivo Lang, Zenon Starčuk, Otto Weisser and Luděk Vodička
    Characterization of heavy crude oil fractions by means of the 13C NMR technique
    1979, Vol. 44, Issue 4, pp. 1160–1166 [Abstract]
  • Jiří Karhan, Milan Hájek, Zbyněk Ksandr and Luděk Vodička
    Application of the relaxation reagent Gd(FOD)3 (1,1,1,2,2,3,3-heptafluoro-7,7-dimethyl-4,6-octanedionate)gadolinium(III) in 1H NMR spectroscopy of adamantoid compounds
    1979, Vol. 44, Issue 2, pp. 533–541 [Abstract]
  • Jaromír Plešek, Zbyněk Janoušek and Stanislav Heřmánek
    Four new (CH3)2S·C2B9H11 isomers
    1978, Vol. 43, Issue 11, pp. 2862–2868 [Abstract]
  • Jaromír Plešek, Zbyněk Janoušek and Stanislav Heřmánek
    Chemistry of 9-mercapto-1,7-dicarba-closo-dodecaborane
    1978, Vol. 43, Issue 5, pp. 1332–1338 [Abstract]
  • Jaroslava Podehradská, Milan Hájek and Slavoj Hála
    1H-NMR spectra of high-boiling adamantylaromatic compounds
    1978, Vol. 43, Issue 1, pp. 250–256 [Abstract]