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Collect. Czech. Chem. Commun. 1991, 56, 1618-1635
https://doi.org/10.1135/cccc19911618

Selective dismantling of closo-1,2-C2B10H12 to lower-cage dicarbaborane systems

Jaromír Plešeka, Bohumil Štíbrb, Xavier L. R. Fontaineb, John D. Kennedyb, Stanislav Heřmáneka and Tomáš Jelíneka

a Institute of Inorganic Chemistry, Czechoslovak Academy of Sciences, 250 68 Řež near Prague, Czechoslovakia
b School Of Chemistry, University of Leeds, Leeds LS2 9JT, England

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  • Štíbr Bohumil: Ten-vertex dicarbaboranes from nido -5,6-C 2 B 8 H 12. Journal of Organometallic Chemistry 2015, 798, 30. <https://doi.org/10.1016/j.jorganchem.2015.04.005>
  • Bakardjiev Mario, Štíbr Bohumil, Holub Josef, Růžička Aleš, Padělková Zdeňka: Half-pseudoferrocene cations from nucleophilic addition of o-carboranyl anions to the [(η6-mesitylene)2Fe]2+ dication. Dalton Trans. 2012, 41, 7151. <https://doi.org/10.1039/c2dt30181d>
  • Štíbr Bohumil, Holub Josef, Bakardjiev Mario, Janoušek Zbyněk: Unusual interaction of alkynes with nine-vertex arachno-monocarbaboranes 4-CB8H14and [4-CB8H13]−. Dalton Trans. 2007, 581. <https://doi.org/10.1039/B613237E>
  • Grüner Bohumír, Holub Josef, Plešek Jaromír, Štíbr Bohumil, Thornton-Pett Mark, Kennedy John D.: Dimethylsulfide-dicarbaborane chemistry. Isolation and characterisation of isomers [9-(SMe2)-nido-7,8-C2B9H10-X-Me] (where X = 1, 2, 3 and 4) and some related compounds. An unusual skeletal rearrangement. Dalton Trans. 2007, 4859. <https://doi.org/10.1039/b709526k>
  • Bould Jonathan, Clegg William, Kennedy John D.: Polyhedral iridaborane chemistry: Elements of the 10-vertex closo–isonido–isocloso continuum. Inorganica Chimica Acta 2006, 359, 3723. <https://doi.org/10.1016/j.ica.2006.01.038>
  • Farràs Pau, Teixidor Francesc, Branchadell Vicenç: Prediction of pKa Values of nido-Carboranes by Density Functional Theory Methods. Inorg. Chem. 2006, 45, 7947. <https://doi.org/10.1021/ic060908b>
  • Macháček Jan, Plešek Jaromír, Holub Josef, Hnyk Drahomír, Všetečka Václav, Císařová Ivana, Kaupp Martin, Štíbr Bohumil: New route to 1-thia-closo-dodecaborane(11), closo-1-SB11H11, and its halogenation reactions. The effect of the halogen on the dipole moments and the NMR spectra and the importance of spin–orbit coupling for the11B chemical shifts. Dalton Trans. 2006, 1024. <https://doi.org/10.1039/B512345C>
  • Janoušek Zbyněk, Dostál Radim, Macháček Jan, Hnyk Drahomír, Štíbr Bohumil: The first member of the eleven-vertex azadicarbaborane series, 1,6,9-NC2B8H13, and its N-alkyl derivatives. Dalton Trans. 2006, 4664. <https://doi.org/10.1039/B608857K>
  • Holub Josef, Bakardjiev Mario, Štíbr Bohumil: Electrophilic Halogenation of nido-5,6-C2B8H12. Collect. Czech. Chem. Commun. 2006, 71, 1549. <https://doi.org/10.1135/cccc20061549>
  • Holub Josef, Grüner Bohumír, Perekalin Dmitry S., Golovanov Denis G., Lyssenko Konstantin A., Petrovskii Pavel V., Kudinov Alexander R., Štíbr Bohumil: Synthesis and Rearrangements of Aminosubstituted Ferra- and Ruthenatricarbaboranes. Inorg. Chem. 2005, 44, 1655. <https://doi.org/10.1021/ic0483702>
  • Perekalin Dmitry S., Holub Josef, Golovanov Denis G., Lyssenko Konstantin A., Petrovskii Pavel V., Štíbr Bohumil, Kudinov Alexander R.: Ferra- and Ruthenatricarbollides CpFeC3B8H11 and Cp*RuC3B8H11. Organometallics 2005, 24, 4387. <https://doi.org/10.1021/om050139o>
  • Bakardjiev Mario, Holub Josef, Carr Michael J., Kennedy John D., Štíbr Bohumil: Diphosphacarborane analogues of ferrocene: The synthesis of two isomeric twelve-vertex closo-[(η5-C5H5)FeP2CB8H9] complexes. Dalton Trans. 2005, 909. <https://doi.org/10.1039/B418370C>
  • Grüner Bohumír, Bačkovský Jaroslav, Sillanpää Reijo, Kivekäs Raikko, Císařová Ivana, Teixidor Francesc, Viñas Clara, Štíbr Bohumil: Amino‐Substituted Ferra‐bis(tricarbollides) − Metallatricarbaboranes Designed for Linear Molecular Constructions. Eur J Inorg Chem 2004, 2004, 1402. <https://doi.org/10.1002/ejic.200300686>
  • Bould Jonathan, Laromaine Anna, Viñas Clara, Teixidor Francesc, Barton Lawrence, Rath Nigam P., Winter Rudolph E. K., Kivekäs Raikko, Sillanpää Reijo: New Derivatives of [NHMe3][7-Me-μ-(9,10-HMeC)-nido-7-CB10H10]. Organometallics 2004, 23, 3335. <https://doi.org/10.1021/om030487v>
  • Franken Andreas, Bullen Neil J., Jelínek Tomáš, Thornton-Pett Mark, Teat Simon J., Clegg William, Kennedy John D., Hardie Michaele J.: Structural chemistry of halogenated monocarbaboranes: the extended structures of Cs[1-HCB9H4Br5], Cs[1-HCB11H5Cl6] and Cs[1-HCB11H5Br6]. New J. Chem. 2004, 28, 1499. <https://doi.org/10.1039/B410929E>
  • Štíbr Bohumil, Holub Josef, Bakardjiev Mario, Pavlík Ivan, Tok Oleg L., Císařová Ivana, Wrackmeyer Bernd, Herberhold Max: Formation of Two Isomeric closo‐[(η5‐C5H5)FePC2B8H10] Phosphadicarbaborane Analogues of Ferrocene via Isolable η1‐Bonded Complexes of the [7‐{(η5‐C5H5)Fe(CO)2}‐(η1‐nido‐PC2B8H10)] Type. Chemistry A European J 2003, 9, 2239. <https://doi.org/10.1002/chem.200204704>
  • Štíbr Bohumil, Holub Josef, Bakardjiev Mario, Pavlík Ivan, Tok Oleg L., Wrackmeyer Bernd: Phosphadicarbaborane Analogues of Ferrocene: New Isomers of [closo‐(η5‐C5H5)FePC2B8H10]. Eur J Inorg Chem 2003, 2003, 2524. <https://doi.org/10.1002/ejic.200300002>
  • Grüner Bohumír, Štíbr Bohumil, Holub Josef, Císařová Ivana: Metal‐Promoted Cage Rearrangements in the Tricarbollide Series: Conversion of Ligand Derivatives 7‐L‐nido‐7,8,9‐C3B8H10 (L = H3N, tBuH2N, Me2HN) into Neutral 8‐R‐nido‐7,8,9‐C3B8H11 (R = H2N, tBuHN, Me2N) Compounds. Eur J Inorg Chem 2003, 2003, 1533. <https://doi.org/10.1002/ejic.200390200>
  • Jelínek Tomáš, Štíbr Bohumil, Kennedy John D., Hnyk Drahomír, Bühl Michael, Hofmann Matthias: Azacarbaborane chemistry. Butyl nitrite synthesis of the new eight-, nine- and ten-vertex azacarbaboranes exo- and endo-7-CH3-hypho-7,8-NCB6H11, nido-6,8,9-NC2B7H10, arachno-6,5,9-NC2B7H12 and arachno-6,5,10-C2NB7H12. Dalton Trans. 2003, 1326. <https://doi.org/10.1039/b300088e>
  • Štíbr Bohumil, Holub Josef, Bakardjiev Mario, Hnyk Drahomír, Tok Oleg L., Milius Wolfgang, Wrackmeyer Bernd: Phosphacarborane Chemistry: The Synthesis of the Parent Phosphadicarbaboranesnido-7,8,9-PC2B8H11 and [nido-7,8,9-PC2B8H10]−, and Their 10-Cl Derivatives − Analogs of the Cyclopentadienide Anion. Eur J Inorg Chem 2002, 2002, 2320. <https://doi.org/10.1002/1099-0682(200209)2002:9<2320::AID-EJIC2320>3.0.CO;2-E>
  • Štíbr Bohumil, Holub Josef, Bakardjiev Mario, Hnyk Drahomír, Tok Oleg L., Milius Wolfgang, Wrackmeyer Bernd: Phosphacarborane Chemistry: The Synthesis of the Parent Phosphadicarbaboranesnido-7,8,9-PC2B8H11 and [nido-7,8,9-PC2B8H10]−, and Their 10-Cl Derivatives − Analogs of the Cyclopentadienide Anion. Eur. J. Inorg. Chem. 2002, 2002, 2320. <https://doi.org/10.1002/1099-0682(200209)2002:9<2320::AID-EJIC2320>3.0.CO;2-E>
  • Plešek Jaromı́r, Grüner Bohumı́r, Cı́sařová Ivana, Báča Jiřı́, Selucký Pavel, Rais Jiřı́: Functionalized cobalt bis(dicarbollide) ions as selective extraction reagents for removal of M2+ and M3+ cations from nuclear waste, crystal and molecular structures of the [8,8′-μ-CIP(O)(O)2(1,2-C2B9H10)2-3,3′-Co]HN(C2H5)3 and [8,8′-μ-Et2NP(O)(O)2(1,2-C2B9H10)2-3,3′-Co](HN(CH3)3). Journal of Organometallic Chemistry 2002, 657, 59. <https://doi.org/10.1016/S0022-328X(02)01325-6>
  • Štı́br Bohumil, Wrackmeyer Bernd: Recent developments in the chemistry of the nine-vertex monocarbaboranes. Journal of Organometallic Chemistry 2002, 657, 3. <https://doi.org/10.1016/S0022-328X(02)01328-1>
  • Plešek Jaromı́r, Grüner Bohumı́r, Heřmánek Stanislav, Báča Jiřı́, Mareček Vladimı́r, Jänchenová Jana, Lhotský Alexandr, Holub Karel, Selucký Pavel, Rais Jiřı́, Cı́sařová Ivana, Čáslavský Josef: Synthesis of functionalized cobaltacarboranes based on the closo-[(1,2-C2B9H11)2-3,3′-Co]− ion bearing polydentate ligands for separation of M3+ cations from nuclear waste solutions. Electrochemical and liquid–liquid extraction study of selective transfer of M3+ metal cations to an organic phase. Molecular structure of the closo-[(8-(2-CH3OC6H4O)-(CH2CH2O)2-1,2-C2B9H10)-(1′,2′-C2B9H11)-3,3′-Co]Na determined by X-ray diffraction analysis. Polyhedron 2002, 21, 975. <https://doi.org/10.1016/S0277-5387(02)00865-3>
  • Fox Mark A., Goeta Andrés E., Hughes Andrew K., Johnson Andrew L.: Crystal and molecular structures of the nido-carborane anions, 7,9- and 2,9-C2B9H12−. J. Chem. Soc., Dalton Trans. 2002, 2132. <https://doi.org/10.1039/b108937d>
  • Fox Mark A., Hughes Andrew K., Johnson Andrew L., Paterson Michael A. J.: Do the discrete dianions C2B9H112− exist? Characterisation of alkali metal salts of the 11-vertex nido dicarboranes, C2B9H112−, in solution. J. Chem. Soc., Dalton Trans. 2002, 2009. <https://doi.org/10.1039/b109804g>
  • Grüner Bohumír, Plešek Jaromír, Báča Jiří, Císařová Ivana, Dozol Jean François, Rouquette Heléne, Viňas Clara, Selucký Pavel, Rais Jiří: Cobalt bis(dicarbollide) ions with covalently bonded CMPO groups as selective extraction agents for lanthanide and actinide cations from highly acidic nuclear waste solutions. New J. Chem. 2002, 26, 1519. <https://doi.org/10.1039/B202374C>
  • Holub Josef, Bakardjiev Mario, Štíbr Bohumil: Some Halogenation Reactions of nido-7,8,9,11-P2C2B7H9. Collect. Czech. Chem. Commun. 2002, 67, 783. <https://doi.org/10.1135/cccc20020783>
  • Hnyk Drahomír, Holub Josef: Two Forgotten Ten-Vertex arachno Triheteroboranes: arachno-5,6,9-C2SB7H11 and arachno-5,6,9-C3B7H13, Their Molecular Structure Determination by ab initio/NMR Approach and Synthesis of the Thiacarbaborane. Collect. Czech. Chem. Commun. 2002, 67, 813. <https://doi.org/10.1135/cccc20020813>
  • Janoušek Zbyněk, Hilton Cameron L., Schreiber Peter J., Michl Josef: C-Halogenation of the closo-[CB11H12]- Anion. Collect. Czech. Chem. Commun. 2002, 67, 1025. <https://doi.org/10.1135/cccc20021025>
  • Holub Josef, Jelínek Tomáš, Hnyk Drahomír, Plzák Zbyněk, Císařová Ivana, Bakardjiev Mario, Štíbr Bohumil: Phosphacarborane Chemistry: The 7,8,9,11-, 7,9,8,10- and 7,8,9,10-Isomers ofnido-P2C2B7H9—Diphosphadicarbaborane Analogues of 7,8,9,10-C4B7H11. Chem Eur J 2001, 7, 1546. <https://doi.org/10.1002/1521-3765(20010401)7:7<1546::AID-CHEM1546>3.0.CO;2-K>
  • Holub Josef, Jelínek Tomáš, Hnyk Drahomír, Plzák Zbyněk, Císařová Ivana, Bakardjiev Mario, Štíbr Bohumil: Phosphacarborane Chemistry: The 7,8,9,11-, 7,9,8,10- and 7,8,9,10-Isomers ofnido-P2C2B7H9—Diphosphadicarbaborane Analogues of 7,8,9,10-C4B7H11. Chem. Eur. J. 2001, 7, 1546. <https://doi.org/10.1002/1521-3765(20010401)7:7<1546::AID-CHEM1546>3.0.CO;2-K>
  • Bown Mark, Grüner Bohumı́r, Štı́br Bohumil, Fontaine Xavier L.R., Thornton-Pett Mark, Kennedy John D.: Eleven-vertex polyhedral metalladicarbaborane chemistry. Reactions of neutral nido-5,6-C2B8H12 and the [nido-6,9-C2B8H10]2− anion to give formally closo isomeric 1-(arene) and 1-(cyclopentadiene)-1,2,4- and 1,2,3-metalladicarbaundecaboranes, and some substituent chemistry. Chiral separations, and crystal and molecular structures of [5-Br-1-(η6-C6Me6)-1,2,4-RuC2B8H9] and [2-Me-1-(η5-C5Me5)-1,2,3-RhC2B8H9]. Journal of Organometallic Chemistry 2000, 614-615, 269. <https://doi.org/10.1016/S0022-328X(00)00615-X>
  • Grüner Bohumír, Lehtonen Ari, Kivekäs Raikko, Sillanpää Reijo, Holub Josef, Teixidor Francesc, Viñas Clara, Štíbr Bohumil: Unusual 9 → 10 Rearrangement of the Substituted Cage Carbon in the Ferratricarbollide Series. Synthesis of the Isomeric Complexes [2-η5-(C5H5)-10-X-closo-2,1,7,10-FeC3B8H10] (Where X = H2N, MeHN, Me2N, and ButHN). Inorg. Chem. 2000, 39, 2577. <https://doi.org/10.1021/ic991375s>
  • Lee Hans, Onak Thomas, Jaballas Jojo, Tran Uyen, Truong Thien U, To Huyen T: Conversion of site-specific deuterated closo-1,2- and 1,7-C2B10H12 to deuterated nido-7,8- and 7,9-[C2B9H12]− ions, respectively; mechanistic inferences. Comparisons of GIAO-NMR generated [C2B9H12]− chemical shifts with experimental values, and consideration of two principal isomers of the 7,8-[C2B9H12]− ion by comparison of geometry optimization data, NMR chemical shift data, and NMR coupling data to respective experimental data. Inorganica Chimica Acta 1999, 289, 11. <https://doi.org/10.1016/S0020-1693(99)00054-7>
  • Holub Josef, Grüner Bohumír, Císařová Ivana, Fusek Jiří, Plzák Zbyněk, Teixidor Francesc, Viñas Clara, Štíbr Bohumil: A Series of the Twelve-Vertex Ferratricarbollides [2-(η5-C5H5)-9-X-closo-2,1,7,9-FeC3B8H10] (Where X = H2N, MeHN, Me2N, ButHN, But(Me)N). A Highly Stable Metallatricarbaborane System with Amine Functions in the Para Position to the Metal Center. Inorg. Chem. 1999, 38, 2775. <https://doi.org/10.1021/ic981400e>
  • Hermansson Kersti, Wójcik Mark, Sjöberg Stefan: o-, m-, and p-Carboranes and Their Anions:  Ab Initio Calculations of Structures, Electron Affinities, and Acidities. Inorg. Chem. 1999, 38, 6039. <https://doi.org/10.1021/ic990381l>
  • Štı́br Bohumil, Teixidor Francesc, Viñas Clara, Fusek Jiřı́: A convenient route to carbon-substituted derivatives of nido-5,6-C2B8H121Dedicated to Professor K. Wade on the occasion of his 65th birthday for his essential contributions to the area of cluster boron chemistry. All cluster chemists know Wade's electron-counting rules and use them for the benefit of chemistry.1. Journal of Organometallic Chemistry 1998, 550, 125. <https://doi.org/10.1016/S0022-328X(97)00535-4>
  • Plešek Jaromír, Štíbr Bohumil, Hnyk Drahomír, Jelínek Tomáš, Heřmánek Stanislav, Kennedy John D., Hofmann Matthias, Schleyer Paul v. R.: Dicarbaheteroborane Chemistry. Representatives of Two Eleven-Vertex Dicarbaazaundecaborane Families:  nido-10,7,8-NC2B8H11, Its N-Substituted Derivatives, and arachno-1,8,11-NC2B8H13. Inorg. Chem. 1998, 37, 3902. <https://doi.org/10.1021/ic971526w>
  • Holub J., Štíbr B., Hnyk D., Fusek J., Císařová I., Teixidor F., Viñas C., Plzák Z., Schleyer P. v. R.: Parent Tricarbollides [nido-7,8,9-C3B8H11]-, nido-7,8,9-C3B8H12, [nido-7,8,10-C3B8H11]-, and Their Derivatives. J. Am. Chem. Soc. 1997, 119, 7750. <https://doi.org/10.1021/ja971194u>
  • Štíbr Bohumil, Holub Josef, Císařová Ivana, Teixidor Francesc, Viñas Clara, Fusek Jiří, Plzák Zbyněk: The Derivatives of the 7,8,9- Series of Tricarbollides. Preparation and Structural Characterization of the 11-Vertex Tricarbaboranes 7-L-nido-7,8,9-C3B8H10 (L = Amines). Inorg. Chem. 1996, 35, 3635. <https://doi.org/10.1021/ic951437o>
  • Wille Andrew E., Plešek Jaromir, Holub Josef, Štíbr Bohumil, Carroll Patrick J., Sneddon Larry G.: An Improved Synthesis of arachno-4-CB8H14 and Crystallographic and ab Initio/IGLO/NMR Investigations of the Solid State and Solution Structures of the arachno-4-CB8H13- Anion. Inorg. Chem. 1996, 35, 5342. <https://doi.org/10.1021/ic9602409>
  • Štíbr Bohumil, Holub Josef, Jelínek Tomáš, Fontaine Xavier L. R., Fusek Jiři, Kennedy John D., Thornton-Pett Mark: Ten-vertex polyhedral monoheteroborane chemistry: syntheses, molecular structures, and nuclear magnetic resonance characterization of some 9-substituted 6-aza- and 6-thia-arachno-decaboranes. J. Chem. Soc., Dalton Trans. 1996, 1741. <https://doi.org/10.1039/DT9960001741>
  • Holub Josef, Kennedy John D., Jelínek Tomáš, Štíbr Bohumil: Polyhedral carbathiaborane chemistry. Ten-vertex nido and arachno, eleven-vertex nido, and eight-vertex hypho families of carbathiaboranes. J. Chem. Soc., Dalton Trans. 1994, 1317. <https://doi.org/10.1039/DT9940001317>
  • Plešek Jaromír, Grüner Bohumír, Maloň Petr: Liquid chromatographic resolution of enantiomers of deltahedral carborane and metallaborane derivatives. Journal of Chromatography A 1992, 626, 197. <https://doi.org/10.1016/0021-9673(92)85410-U>