Collect. Czech. Chem. Commun.
1991, 56, 736-744
https://doi.org/10.1135/cccc19910736
Excess molar volumes of binary mixtures of acetic acid and propionic acid with some members of homologous series of alkanes
Ondřej Drábek and Ivan Cibulka
Department of Physical Chemistry, Prague Institute of Chemical Technology, 166 28 Prague 6
Abstract
Excess molar volumes of binary liquid mixtures of (acetic or propionic acid = hexane) at 25 and 35°C, and (acetic or propionic acid + heptane or octane) and (acetic acid + dodecane) at 25°C, measured with a tilting dilution dilatometer, are reported. The excess volumes are positive over the entire concentration range for all mixtures and increase with increasing length of an alkane molecule, decrease with increasing of the alkyl chain in a molecule of carboxylic acid, and increase with increasing temperature.
